摘要:
Disclosed are polymeric foam structures suitable for absorbing and storing body fluids such as urine, menses and the like. These liquid storage structures are high suction collapsible polymeric foam materials. The collapsed foams, upon contact with aqueous fluids, can absorb and expand these fluids even when opposed by significant hydrostatic pressures. These absorbent polymeric foams comprise interconnected open-cells. In one aspect, the foams can absorb at least about 25 g/g against a hydrostatic head pressure of 50 cm. In another aspect, the foams of the present invention will have a vertical hang sorption height at 90% of at least about 60 cm.
摘要:
The present invention relates to a HIPE-derived heterogeneous polymeric foam structure of interconnected open-cells, wherein the foam structure has at least two distinct regions. Such heterogeneous foams have various applications, such as energy and fluid absorption, insulation, and filtration.The invention further relates to a heterogeneous absorbent polymeric foam that, upon contact with aqueous fluids (in particular body fluids such as urine and blood), can acquire, distribute, and store these fluids.The foams of the invention have at least two distinct regions having different density, polymer composition, surface properties, and/or microcellular morphology.The invention further relates to a process for obtaining the heterogeneous foams by polymerizing a high internal phase water-in-oil emulsion, or HIPE. In one aspect, the process utilizes at least two distinct HIPEs, with each emulsion having a relatively small amount of an oil phase and a relatively greater amount of a water phase.
摘要:
This application relates to flexible, microporous, open-celled polymeric foam materials with physical characteristics that make them suitble for a variety of uses. This application particularly relates to degassing the components of the high internal phase emulsions which are subsequently cured to form such foams.
摘要:
Described are absorbent members useful in the containment of body liquids such as urine. The storage members have a high capillary suction capacity. For purposes of the present disclosure, capillary suction capacity is measured in terms of the member's ability to uptake liquid at relatively high capillary pressures, which are generally encountered when the member is positioned in an absorbent article. In particular, capillary suction capacity is measured in terms of a member's capillary sorption absorbent capacity, which is measured in accordance with the Capillary Sorption method described in the Test Methods section of the disclosure. The absorbent members may include an osmotic absorbent (preferably a hydrogel-forming absorbent polymer) or a high surface area material, or a combination thereof.
摘要:
The present invention relates to compressable polymeric foam materials useful as insulation. These polymeric foams are prepared by polymerization of certain water-in-oil emulsions having a relatively high ratio of water phase to oil phase, commonly known as "HIPEs." The polymeric foam materials comprise a generally hydrophobic, flexible or semi-flexible, nonionic polymeric foam structure of interconnected open-cells. The foam structures have: (a) a specific surface area per foam volume of at least about 0.01 m.sup.2 /cc; (b) an expanded density of less than about 0.05 g/cc; and (c) a ratio of expanded to compressed thickness of at least about 3:1; wherein when the foam is compressed to 33% of its original expanded thickness and is thereafter maintained without artificial restraint on its surface, said foam will reexpand by no more than 50% after 21 days at ambient temperature (22.degree. C.). In a preferred embodiment, the foams of the present invention, when heated to their Tg or higher, will reexpand to 90% of their original thickness within about 1 day or less. The invention also relates to a process for making the compressible polymeric foam material comprising polymerizing a water-in-oil emulsion having a volume to weight ratio of water phase to oil phase in the range of from about 20:1 to about 250:1.
摘要:
The invention relates to the use of polymeric foam materials for insulation. These polymeric foams are prepared by polymerization of certain water-in-oil emulsions having a relatively high ratio of water phase to oil phase, commonly known in the art as high internal phase emulstions, or "HIPEs." The HIPE-derived foam materials used in the present invention comprise a generally hydrophobic, flexible, semi-flexible, or rigid nonionic polymeric foam structure of interconnected open-cells. These foam structures have: A) a specific surface area per foam volume of at least about 0.01 m.sup.2 /cc; B) a density of less than about 0.05 g/cc; and C) a glass transition temperature (Tg) of between about -20.degree. and 90.degree. C. The foams can be used as thermal, acoustic, and/or mechanical insulation materials. In a preferred embodiment, the foams used can be prepared, packaged, and shipped in a compressed, high density state and will "spring back" upon activation (e.g. heat) to the original density of the foam.
摘要:
Absorbent foam materials that are capable of acquiring and distributing aqueous fluids, especially discharged body fluids such as urine. These absorbent foams combine relatively high capillary absorption pressures and capacity-per-weight properties that allow them to acquire fluid, with or without the aid of gravity. These absorbent foams also give up this fluid efficiently to higher absorption pressure storage materials, including foam-based absorbent fluid storage components, without collapsing. These absorbent foams are made by polymerizing high internal phase emulsions (HIPEs).
摘要:
Described is a method of forming and curing high internal phase emulsions (HIPEs) into shaped three dimensional foam implements. In general the method uses the steps of: providing a HIPE, depositing the HIPE into a mold cavity having a predetermined three dimensional shape, curing the HIPE in the mold cavity to form a HIPE foam, and stripping the HIPE foam from the mold cavity to form the three dimensional foam implement. The molded implements are widely useful as components in absorbent articles, toys, insulation, and other uses where a combination of low density and tridimensional shape are desired.
摘要:
A method of making high internal phase emulsions is described. The method forms high internal phase emulsion (HIPE) using a single pass through the static mixer. In alternative embodiments, the HIPE may be further processed to farther modify the size of dispersed phase droplets, to incorporate additional materials into the HIPE, to alter emulsion temperature, and the like.
摘要:
Disclosed are polymeric foam structures suitable for absorbing and storing body fluids such as urine, menses and the like. These liquid storage structures are high suction collapsible polymeric foam materials. The collapsed foams, upon contact with aqueous fluids, can absorb and expand these fluids even when opposed by significant hydrostatic pressures. These absorbent polymeric foams comprise interconnected open-cells. In one aspect, the foams can absorb at least about 25 g/g against a hydrostatic head pressure of 50 cm. In another aspect, the foams of the present invention will have a vertical hang sorption height at 90% of at least about 60 cm.