公开(公告)号：US08974863B2

公开(公告)日：2015-03-10

申请号：US13499800

申请日：2010-10-01

申请人： Teppei Miura ,  Manabu Kaneko

发明人： Teppei Miura ,  Manabu Kaneko

IPC分类号： B05D3/02 ,  C08J5/24 ,  C08G59/32 ,  C08G59/50 ,  C08L63/00

CPC分类号： C08J5/24 ,  C08G59/3218 ,  C08G59/3227 ,  C08G59/504 ,  C08J2363/00 ,  C08L63/00 ,  Y10T442/2631 ,  C08L2666/22

摘要： A method for producing a fiber-reinforced composite material having high mechanical properties and high heat resistance, and allowing the use of a gypsum die in primary curing, wherein a fiber-reinforced prepreg, obtained by impregnating reinforcing fibers with an epoxy resin composition comprising a triphenylmethane-type epoxy resin, N,N,N′,N′-tetraglycidyldiaminodiphenylmethane (B) and diaminodiphenylsulfone (C), is subjected to primary curing at 110-130° C., and then to secondary curing at a temperature which is at least as high as the primary curing temperature.

摘要翻译： 一种生产具有高机械性能和高耐热性的纤维增强复合材料的方法，并且允许在一次固化中使用石膏模头，其中通过用包含以下组分的环氧树脂组合物浸渍增强纤维获得的纤维增强预浸料 三苯甲烷型环氧树脂，N，N，N'，N'-四缩水甘油基二氨基二苯基甲烷（B）和二氨基二苯基砜（C）在110-130℃下进行一次固化，然后在温度为 至少与主要固化温度一样高。

公开(公告)号：US20130295811A1

公开(公告)日：2013-11-07

申请号：US13879278

申请日：2011-10-13

申请人： Yuusuke Shinmen ,  Norifumi Hirota ,  Atsushi Nakajima ,  Naoki Aoyama ,  Naomasa Matsuyama ,  Takeshi Nii ,  Akiyoshi Kogame ,  Yasuyuki Fujii ,  Yoshiko Irie ,  Harumi Matsuda ,  Takayuki Kiriyama ,  Teppei Miura ,  Takuya Teranishi ,  Shouhei Mori ,  Manabu Kaneko ,  Kiharu Numata ,  Masahiro Ichino ,  Shigekazu Takeda ,  Takayuki Kobayashi ,  Toshiyuki Itou ,  Masahiro Hata ,  Hiroyuki Nakao ,  Kenichi Watanabe

发明人： Yuusuke Shinmen ,  Norifumi Hirota ,  Atsushi Nakajima ,  Naoki Aoyama ,  Naomasa Matsuyama ,  Takeshi Nii ,  Akiyoshi Kogame ,  Yasuyuki Fujii ,  Yoshiko Irie ,  Harumi Matsuda ,  Takayuki Kiriyama ,  Teppei Miura ,  Takuya Teranishi ,  Shouhei Mori ,  Manabu Kaneko ,  Kiharu Numata ,  Masahiro Ichino ,  Shigekazu Takeda ,  Takayuki Kobayashi ,  Toshiyuki Itou ,  Masahiro Hata ,  Hiroyuki Nakao ,  Kenichi Watanabe

IPC分类号： D01F9/12 ,  B32B37/14 ,  F27D7/00

CPC分类号： D01F9/12 ,  B29C70/44 ,  B32B37/14 ,  C08J5/042 ,  C08J5/24 ,  C08J2363/00 ,  D01D5/096 ,  D01D5/253 ,  D01F6/38 ,  D01F9/225 ,  F27D7/00 ,  Y10T428/26 ,  Y10T428/298 ,  Y10T442/3089

摘要： Provided are: a carbon fiber bundle which has a large value of single-fiber fineness and excellent productivity and which, despite this, contains few interlaced single fibers therein and has excellent spreadability; and precursor fibers which are suitable for use in producing the carbon fiber bundle. The precursor fibers are a carbon-fiber-precursor acrylic fiber bundle which comprises a polyacrylonitrile copolymer comprising 95-99 mol % acrylonitrile units and 1-5 mol % hydroxyalkyl (meth)acrylate units and which has a single-fiber fineness of 1.5-5.0 dtex. In the acrylic fiber bundle, the cross-section of each single fiber which is perpendicular to the fiber axis has a shape that has a roundness of 0.9 or less. The roundness is a value determined using equation (1) where S and L are the cross-sectional area and the circumferential length, respectively, of a single fiber which are obtained by examining, with an SEM, the cross-section of the single fiber which is perpendicular to the fiber axis and analyzing the obtained image. Roundness=4pS/L2  (1)

摘要翻译： 提供：具有大的单纤维细度值和优异的生产率的碳纤维束，尽管如此，它在其中包含很少的交错单纤维并且具有优异的铺展性; 和适用于生产碳纤维束的前体纤维。 前体纤维是碳纤维前体丙烯酸纤维束，其包含包含95-99mol％丙烯腈单元和1-5mol％（甲基）丙烯酸羟烷基酯单元的聚丙烯腈共聚物，其单纤维细度为1.5-5.0 dtex 在丙烯酸​​系纤维束中，与纤维轴垂直的各单纤维的截面为圆度为0.9以下的形状。 圆度是使用公式（1）确定的值，其中S和L分别是通过用SEM检查单根纤维的横截面而获得的单根纤维的横截面面积和圆周长度 其垂直于纤维轴并分析所获得的图像。 圆度= 4pS / L2（1）

公开(公告)号：US20120231687A1

公开(公告)日：2012-09-13

申请号：US13499800

申请日：2010-10-01

申请人： Teppei Miura ,  Manabu Kaneko

发明人： Teppei Miura ,  Manabu Kaneko

IPC分类号： B05D3/02 ,  B32B27/12 ,  B05D7/00

CPC分类号： C08J5/24 ,  C08G59/3218 ,  C08G59/3227 ,  C08G59/504 ,  C08J2363/00 ,  C08L63/00 ,  Y10T442/2631 ,  C08L2666/22

摘要： A method for producing a fiber-reinforced composite material having high mechanical properties and high heat resistance, and allowing the use of a gypsum die in primary curing, wherein a fiber-reinforced prepreg, obtained by impregnating reinforcing fibers with an epoxy resin composition comprising a triphenylmethane-type epoxy resin, N,N,N′,N′-tetraglycidyldiaminodiphenylmethane (B) and diaminodiphenylsulfone (C), is subjected to primary curing at 110-130° C., and then to secondary curing at a temperature which is at least as high as the primary curing temperature.

摘要翻译： 一种生产具有高机械性能和高耐热性的纤维增强复合材料的方法，并且允许在一次固化中使用石膏模头，其中通过用包含以下组分的环氧树脂组合物浸渍增强纤维获得的纤维增强预浸料 三苯甲烷型环氧树脂，N，N，N'，N'-四缩水甘油基二氨基二苯基甲烷（B）和二氨基二苯基砜（C）在110-130℃下进行一次固化，然后在温度为 至少与主要固化温度一样高。

公开(公告)号：US09481789B2

公开(公告)日：2016-11-01

申请号：US14001391

申请日：2012-03-02

申请人： Masahiro Ichino ,  Manabu Kaneko ,  Kazuki Koga ,  Teppei Miura ,  Takuya Teranishi ,  Kiharu Numata ,  Kazutami Mitani ,  Tadao Samejima

发明人： Masahiro Ichino ,  Manabu Kaneko ,  Kazuki Koga ,  Teppei Miura ,  Takuya Teranishi ,  Kiharu Numata ,  Kazutami Mitani ,  Tadao Samejima

IPC分类号： C08J5/24 ,  C08L63/10 ,  C08G59/17 ,  C08G59/40 ,  C08K5/00

CPC分类号： C08L63/10 ,  B32B2305/076 ,  C08G59/1466 ,  C08G59/4021 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/10 ,  C08K5/0025 ,  Y10T428/27

摘要： The present invention relates to a method for producing a prepreg which contains reinforcing fibers and a matrix resin composition with the weight per square meter of the reinforcing fibers being 250-2,000 g/m2. The production method comprises the following steps (1)-(3): (1) a matrix resin composition blending step for obtaining a matrix resin composition by mixing an epoxy resin, a radically polymerizable unsaturated compound, an epoxy resin curing agent and a polymerization initiator that generates radicals, in said step the content of the radically polymerizable unsaturated compound relative to 100% by mass of the total of the epoxy resin and the radically polymerizable unsaturated compound being 10-25% by mass; (2) a matrix resin composition impregnating step; and (3) a surface viscosity increasing step.

摘要翻译： 本发明涉及含有增强纤维的预浸料坯的制造方法和每平方米加强纤维的重量为250〜2000g / m 2的基质树脂组合物。 制造方法包括以下步骤（1） - （3）：（1）通过混合环氧树脂，可自由基聚合的不饱和化合物，环氧树脂固化剂和聚合物来获得基质树脂组合物的基质树脂组合物混合步骤 在所述步骤中，自由基聚合性不饱和化合物的含量相对于环氧树脂和自由基聚合性不饱和化合物的总量的100质量％为10〜25质量％，生成自由基的引发剂; （2）基质树脂组合物浸渍步骤; 和（3）表面粘度增加步骤。

公开(公告)号：US20130327479A1

公开(公告)日：2013-12-12

申请号：US14001391

申请日：2012-03-02

申请人： Masahiro Ichino ,  Manabu Kaneko ,  Kazuki Koga ,  Teppei Miura ,  Takuya Teranishi ,  Kiharu Numata ,  Kazutami Mitani ,  Tadao Samejima

发明人： Masahiro Ichino ,  Manabu Kaneko ,  Kazuki Koga ,  Teppei Miura ,  Takuya Teranishi ,  Kiharu Numata ,  Kazutami Mitani ,  Tadao Samejima

IPC分类号： C08L63/10

CPC分类号： C08L63/10 ,  B32B2305/076 ,  C08G59/1466 ,  C08G59/4021 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/10 ,  C08K5/0025 ,  Y10T428/27

摘要： The present invention relates to a method for producing a prepreg which contains reinforcing fibers and a matrix resin composition with the weight per square meter of the reinforcing fibers being 250-2,000 g/m2. The production method comprises the following steps (1)-(3): (1) a matrix resin composition blending step for obtaining a matrix resin composition by mixing an epoxy resin, a radically polymerizable unsaturated compound, an epoxy resin curing agent and a polymerization initiator that generates radicals, in said step the content of the radically polymerizable unsaturated compound relative to 100% by mass of the total of the epoxy resin and the radically polymerizable unsaturated compound being 10-25% by mass; (2) a matrix resin composition impregnating step; and (3) a surface viscosity increasing step.

摘要翻译： 本发明涉及含有增强纤维的预浸料坯的制造方法和每平方米加强纤维的重量为250〜2000g / m 2的基质树脂组合物。 制造方法包括以下步骤（1） - （3）：（1）通过混合环氧树脂，可自由基聚合的不饱和化合物，环氧树脂固化剂和聚合物来获得基质树脂组合物的基质树脂组合物混合步骤 在所述步骤中，自由基聚合性不饱和化合物的含量相对于环氧树脂和自由基聚合性不饱和化合物的总量的100质量％为10〜25质量％，生成自由基的引发剂; （2）基质树脂组合物浸渍步骤; 和（3）表面粘度增加步骤。

公开(公告)号：US10364347B2

公开(公告)日：2019-07-30

申请号：US14006168

申请日：2012-03-22

申请人： Masao Tomioka ,  Manabu Kaneko ,  Miyuki Hagiwara

发明人： Masao Tomioka ,  Manabu Kaneko ,  Miyuki Hagiwara

IPC分类号： C08L63/04 ,  H05K5/00 ,  C08J5/24 ,  C08G59/32 ,  C08K5/21 ,  C08L63/00

摘要： To provide an epoxy-resin composition and prepreg for producing a fiber-reinforced composite material which exhibits excellent curability and has excellent flame retardance and heat resistance, as well as to provide fiber-reinforced composite materials produced using the prepreg and to provide housing for electronic/electrical devices. The epoxy resin composition contains component (A): a phosphorus compound; component (B): an epoxy resin which has at least three epoxy groups in the molecule, and which does not correspond to component (A) nor include component (A); component (C): an epoxy resin curing agent which does not have a urea structure in the molecule; and component (D): a dimethylurea compound represented by formula (a) (in formula (a), “R” is a hydrogen atom or an alkyl group having any number of 1 to 10 carbons).

公开(公告)号：US20100265309A1

公开(公告)日：2010-10-21

申请号：US12742104

申请日：2008-03-05

申请人： Manabu Kaneko ,  Hisato Kato

发明人： Manabu Kaneko ,  Hisato Kato

IPC分类号： B41J2/01 ,  C09D11/10

CPC分类号： C09D11/38 ,  B41M5/0023 ,  C09D11/322 ,  C09D11/36

摘要： A non-aqueous ink-jet ink which has printability on non-absorbing recording media such as polyvinyl chloride (abrasion resistance and water resistance), is excellent in ejection stability and safety, is free from problems concerning odor, does not cause operational abnormality in an ink-jet head even in long-term use, and can be stably used even after long-term storage. Also provided is a method of ink-jet recording with the ink. This non-aqueous ink-jet ink comprises a pigment, a binder resin, and an organic solvent. It is characterized in that at least 60 mass % of the organic solvent is accounted for by a water-soluble organic solvent and that the content in the ink of a metal salt which is the highest in content among the salts of metals selected among sodium, potassium, magnesium, and calcium is 3-50 ppm in terms of metal-ion concentration.

摘要翻译： 在聚氯乙烯等非吸收性记录介质（耐磨损性和耐水性）上具有可印刷性的非水性喷墨油墨，喷射稳定性和安全性优异，无异味问题，不会引起操作异常 喷墨头即使长期使用也可以稳定使用。 还提供了一种利用墨水进行喷墨记录的方法。 该非水性喷墨油墨包括颜料，粘合剂树脂和有机溶剂。 其特征在于，通过水溶性有机溶剂考虑至少60质量％的有机溶剂，并且金属盐中的含量最高的金属盐的含量选自钠， 钾，镁和钙的金属离子浓度为3-50ppm。

公开(公告)号：US20060182904A1

公开(公告)日：2006-08-17

申请号：US11352065

申请日：2006-02-10

申请人： Masayuki Ushiku ,  Manabu Kaneko ,  Shinsaku Kashiwamura

发明人： Masayuki Ushiku ,  Manabu Kaneko ,  Shinsaku Kashiwamura

IPC分类号： B41M5/00

CPC分类号： B41M5/506 ,  B41M5/5209 ,  B41M5/5218 ,  B41M2205/12

摘要： An ink-jet recording sheet containing a support having thereon at least two porous ink absorptive layers containing microparticles and a hydrophilic resin, wherein an uppermost ink absorptive layer has a smaller average void diameter than an ink absorptive layer adjacent to the uppermost ink absorptive layer, and the hydrophilic resin in the uppermost ink absorptive layer is cross-linked by irradiation with ionization radiation.

摘要翻译： 一种含有载体的喷墨记录纸，其上具有至少两个含有微粒和亲水性树脂的多孔油墨吸收层，其中最上面的吸墨层的平均空隙直径小于与最上层的吸墨层相邻的吸墨层， 并且通过用电离辐射照射将最上面的吸墨层中的亲水性树脂交联。

公开(公告)号：US20060134408A1

公开(公告)日：2006-06-22

申请号：US11015023

申请日：2004-12-20

申请人： Manabu Kaneko

发明人： Manabu Kaneko

IPC分类号： B32B15/04 ,  E04B1/16 ,  B32B7/12

CPC分类号： B32B27/36 ,  B32B3/12 ,  B32B5/022 ,  B32B5/10 ,  B32B15/06 ,  B32B15/20 ,  B32B25/045 ,  B32B25/08 ,  B32B25/20 ,  B32B27/08 ,  B32B27/12 ,  B32B37/12 ,  B32B2250/05 ,  B32B2250/40 ,  B32B2262/106 ,  B32B2266/06 ,  B32B2305/024 ,  B32B2307/54 ,  B32B2307/546 ,  B32B2307/718 ,  B32B2307/7242 ,  B32B2307/7265 ,  B32B2605/00 ,  Y10T428/28 ,  Y10T428/2826 ,  Y10T428/2852 ,  Y10T428/287 ,  Y10T428/2878 ,  Y10T428/2891 ,  Y10T428/31511 ,  Y10T428/31786 ,  Y10T442/2738 ,  Y10T442/674 ,  Y10T442/675

摘要： A process for producing a sandwich structure, includes laminating a reinforced fiber material which is substantially free from a matrix resin; a glycol modified copolymerized polyester resin film; a thermosetting resin composition film which is hardened at room temperature; a core material selected from an open cell foam and a honeycomb; a thermosetting resin composition film which is hardened at room temperature; a glycol modified copolymerized polyester resin film; and a reinforced fiber material which is substantially free from a matrix resin, in this order in a molding tool to form a sandwich, hardening the thermosetting resin composition film which is hardened at room temperature under a condition that the molding tool is closed, infusing a matrix resin into the molding tool, and adjusting a temperature in the molding tool at room temperature or a hardening temperature of the matrix resin to harden the matrix resin.

摘要翻译： 一种夹层结构体的制造方法，其特征在于，层叠基本上不含基质树脂的增强纤维材料， 二醇改性共聚聚酯树脂膜; 在室温下硬化的热固性树脂组合物膜; 选自开孔泡沫体和蜂窝体的核心材料; 在室温下硬化的热固性树脂组合物膜; 二醇改性共聚聚酯树脂膜; 以及基本上不含基质树脂的增强纤维材料，依次形成模制工具以形成夹层，硬化热固性树脂组合物膜，其在室温下在模制工具关闭的条件下硬化，注入 将基质树脂加入到成形工具中，并调节模具中的室温或基体树脂的硬化温度，使基体树脂硬化。

公开(公告)号：US09051485B2

公开(公告)日：2015-06-09

申请号：US13641532

申请日：2011-04-08

申请人： Manabu Kaneko ,  Hidenobu Ohya ,  Naoko Nakajima

发明人： Manabu Kaneko ,  Hidenobu Ohya ,  Naoko Nakajima

IPC分类号： C09D11/322 ,  B41M5/00 ,  B41M7/00 ,  C09D11/106

CPC分类号： C09D11/322 ,  B41M5/0011 ,  B41M5/0023 ,  B41M7/009 ,  C09D11/106

摘要： Provided is an inkjet ink which can form high-quality images with high abrasion resistance and adhesiveness on a non-absorptive recording medium and which exhibits high ejection properties and excellent storage stability. Also provided is an inkjet recording method. An inkjet ink which comprises water, a pigment, a water-soluble resin, a water-soluble or Panic solvent and a surfactant, characterized in that: the water-soluble resin comprises a water-soluble resin consisting of a copolymer resin which has an acid value of 50 to 130 mgKOH/g, a glass transition temperature (Tg) of 30 to 100° C., and a weight-average molecular weight (Mw) of 20,000 to 80,000, said copolymer resin being a resin which is synthesized from a monomer component that comprises methyl methacrylate, an alkyl acrylate or methacrylate, and an acid monomer and in which the total mass of methyl methacrylate and the alkyl acrylate or methacrylate is 80 to 95% relative to the total mass of all of the monomers constituting the copolymer resin; and the surfactant comprises a fluorochemical surfactant and a polyoxyethylene alkyl ether.

摘要翻译： 本发明提供一种喷墨油墨，其能够在非吸收性记录介质上形成具有高耐磨性和粘合性的高质量图像，并且具有高喷射性能和优异的储存稳定性。 还提供了一种喷墨记录方法。 一种喷墨油墨，其包含水，颜料，水溶性树脂，水溶性或恐慌溶剂和表面活性剂，其特征在于：所述水溶性树脂包含由共聚物树脂组成的水溶性树脂，所述共聚物树脂具有 酸值为50〜130mgKOH / g，玻璃化转变温度（Tg）为30〜100℃，重均分子量（Mw）为20,000〜80,000，所述共聚树脂为由 包含甲基丙烯酸甲酯，丙烯酸烷基酯或甲基丙烯酸烷基酯和酸性单体的单体组分，其中甲基丙烯酸甲酯和丙烯酸烷基酯或甲基丙烯酸烷基酯的总质量相对于构成所述单体的所有单体的总质量为80-95％ 共聚树脂; 表面活性剂包括含氟表面活性剂和聚氧乙烯烷基醚。