公开(公告)号：US20230192692A1

公开(公告)日：2023-06-22

申请号：US17754924

申请日：2020-10-10

申请人： TIANJIN NORMAL UNIVERSITY

发明人： Chunju LI ,  Kaidi XU ,  ZhiYuan ZHANG

IPC分类号： C07D471/08 ,  C07C43/205 ,  C07D513/18 ,  C07C49/755 ,  C07D487/18 ,  C07C50/34 ,  C07D487/22 ,  C07C49/255 ,  C07F5/02 ,  C07C59/68 ,  C07C51/41 ,  C07C37/50

CPC分类号： C07D471/08 ,  C07C43/2055 ,  C07D513/18 ,  C07C49/755 ,  C07D487/18 ,  C07C50/34 ,  C07D487/22 ,  C07C49/255 ,  C07F5/027 ,  C07C59/68 ,  C07C51/41 ,  C07C37/50

摘要： A series of new macrocycles and cage-like molecules are obtained in a high yield from a bis-(2,4-dialkoxyphenyl)arene (naphthalene, anthracene, pyrene, porphyrin, etc.) or a tris-(2,4-dialkoxyphenyl)arene (benzene, sym-tribenzobenzene) and paraformaldehyde under the catalysis of a Lewis acid. In addition, perhydroxybiphenylarenes (tetrabiphenyl trimer, naphthalene dimer, etc.) can be obtained by means of demethylation, and a variety of water-soluble derivatives can be obtained by further modification, with same exhibiting a good bond ability for guest molecules (purpurine, etc.). Moreover, the functional group introduced into the backbone enables the macrocycle to have excellent adsorption and separation capabilities and a photophysical property. The macrocyclic and cage-like molecules have commercially available raw materials, are simple to synthesize, have a high yield, and are convenient to modify, such that same have wide application prospects in gas adsorption and separation, facilitate performance improvement of luminescent materials, perform adsorption of water-soluble toxic substances, etc.