摘要:
An organometallic compound, represented by Formula 1: M1(Ln1)n1(Ln2)n2 Formula 1 wherein, in Formula 1, M1 is a transition metal, Ln1 is a ligand represented by Formula 1A, Ln2 is a ligand represented by Formula 1B, n1 is 1 or 2, and n2 is 1 or 2: wherein, in Formulae 1A, 1B, CY1, CY2, CY4, X1, X2, Y1, R1, R2, R10, R20, R40, R31, R32, R33, R34, R40, b10, b20, and b40 are as provided herein, and wherein * and * each indicate a binding site to M1.
摘要:
An organometallic compound represented by Formula 1: M(L1)n1(L2)n2 Formula 1 wherein M is a transition metal, L1 is a ligand represented by Formula 2, L2 is a monodentate ligand, a bidentate ligand, a tridentate ligand, or a tetradentate ligand, n1 is 1, 2, or 3, n2 is 0, 1, 2, 3, or 4, and Formula 2 is as described herein.
摘要:
An organometallic compound represented by Formula 1:
M1(L1)n1(L2)n2 Formula 1
wherein, M1 is a transition metal, L1 is ligand represented by Formula 1A, L2 is a ligand represented by Formula 1B, and n1 and n2 are each independently 1 or 2:
wherein, X1 to X4 are each C or N, ring CY1 and ring CY2 are each independently a C5-C30 carbocyclic group or a C1-C30 heterocyclic group, ring CY3 is a 6-membered heterocyclic group, a 6-membered heterocyclic group condensed with a C5-C30 carbocyclic group, or a 6-membered heterocyclic group condensed with a C1-C30 heterocyclic group, ring CY41 is a 5-membered carbocyclic group or a 5-membered heterocyclic group, Y1 is O, S, Se, C(R6)(R7), or N(R8), * and *′ each indicate a binding site to M1, and the remaining description of Formulae 1A and 2B is as described herein.
摘要:
An organometallic compound represented by Formula 1:
M1(Ln1)n1(Ln2)n2 Formula 1
wherein M1 is a transition metal, Ln1 is a ligand represented by Formula 1A, Ln2 is a ligand represented by Formula 1B, n1 is 1 or 2, and n2 is 1 or 2,
wherein ring CY1 and ring CY2 are each independently a C5-C30 carbocyclic group or a C1-C30 heterocyclic group, ring CY41 is a phenyl group, ring CY42 is a 5-membered aromatic heterocyclic group, and the other substituents are as described herein.
摘要:
An organometallic compound, represented by Formula 1: M(L1)n1(L2)n2 Formula 1 wherein M is a transition metal, L1 is a ligand represented by Formula 2-1, L2 is a ligand represented by Formula 2-2, n1 is 0, 1, or 2, n2 is 1, 2, or 3, and L1 and L2 are different from each other, wherein R1 to R4, rings CY1 to CY3, rings CY41 and CY42, Y1 to Y3, X4, Z4, a1 to a3, b4, *, and *′ are each as defined herein.
摘要:
An organometallic compound represented by Formula 1: M(L1)n1(L2)n2 Formula 1 wherein M, L1, L2, n1, and n2 are the same as described in the specification.
摘要:
A genetically modified microorganism comprising a polynucleotide encoding α-ketoglutarate synthase or a mutant thereof, and a polynucleotide encoding pyruvate carboxylase or a mutant thereof; wherein the genetically modified microorganism has decreased malate quinone oxidoreductase activity and/or decreased phosphoenolpyruvate carboxykinase activity compared to an unmodified microorganism of the same type, and wherein the genetically modified microorganism produces 4-hydroxybutyrate.