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公开(公告)号:US11492504B2
公开(公告)日:2022-11-08
申请号:US16143062
申请日:2018-09-26
Inventor: Lian Wang , Qiaoxi Li , Jianfeng Zhang , Xipeng Liu , Taoran Hui
IPC: B33Y70/00 , C09D11/101 , C09D11/102 , B33Y10/00 , B29C64/124 , B29C64/112 , B29C64/135
Abstract: The present disclosure relates generally to photocurable compositions and methods for continuously forming a three-dimensional body from these compositions. More particularly, the present disclosure relates to photocurable compositions comprising a mixture of polysiloxanes capable of being dually cured, i.e., first by UV radiation followed by thermal treatment, or being cured by UV radiation. In one aspect, the disclosure provides a photocurable composition, including: a first polysiloxane comprising at least two acrylate or methacrylate groups per molecule; a second polysiloxane containing at least one (e.g., at least two) Si—H group per molecule; a third polysiloxane containing at least one (e.g., at least two) reactive aliphatic ethylene group per molecule; a free radical photoinitiator in an amount of about 0.01 to about 10 weight % based on the total weight of (meth)acrylate-containing polysiloxane in the composition; and a hydrosilylation catalyst in an amount of about 0.001 to about 10 weight % hydride-containing polysiloxane and vinyl-containing polysiloxane in the composition.
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公开(公告)号:US20200332069A1
公开(公告)日:2020-10-22
申请号:US16849634
申请日:2020-04-15
Inventor: Qiaoxi Li , Jianfeng Zhang , Xipeng Liu , Lian Wang
IPC: C08G77/442 , G03F7/075 , G03F7/00 , C08G77/20 , C08G77/12
Abstract: This disclosure relates to polysiloxanes and polysiloxane compositions having dual-curable properties, to methods for forming articles from such compositions, and to articles formed thereby. In one embodiment, the polysiloxane comprises at least about two alkenyl groups and at least about two (meth)acryloyl groups.
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公开(公告)号:US11976172B2
公开(公告)日:2024-05-07
申请号:US16849634
申请日:2020-04-15
Inventor: Qiaoxi Li , Jianfeng Zhang , Xipeng Liu , Lian Wang
CPC classification number: C08G77/442 , C08G77/12 , C08G77/20 , G03F7/0037 , G03F7/0757 , B33Y10/00 , B33Y70/00
Abstract: This disclosure relates to polysiloxanes and polysiloxane compositions having dual-curable properties, to methods for forming articles from such compositions, and to articles formed thereby. In one embodiment, the polysiloxane comprises at least about two alkenyl groups and at least about two (meth)acryloyl groups.
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公开(公告)号:US20190202993A1
公开(公告)日:2019-07-04
申请号:US16236608
申请日:2018-12-30
Inventor: Jianfeng Zhang , Jian L. Ding , Ying Wang , Xipeng Liu
IPC: C08G77/14 , C09D183/06 , C09J183/06
CPC classification number: C08G77/14 , C09D183/06 , C09J183/06
Abstract: This disclosure relates to polymerizable silicone compositions, methods for polymerizing such compositions, and to polymerized silicone compositions formed thereby. In one embodiment, a polymerizable composition includes one or more first organosiloxanes or organosilanes, each comprising a plurality of silicon hydride functional groups, one or more second organosiloxanes or organosilanes, each comprising a plurality of reactive heterocycloalkyl functional groups; and one or more third organosiloxanes or organosilanes, each comprising at least about one silicon hydride functional group and at least about one reactive heterocycloalkyl functional group; one or more reactive organic compounds, each comprising at least about one reactive heterocycloalkyl functional group; and an effective amount of a borane catalyst, present, for example, in an amount within the range of 0.0005 wt % to about 10 wt %, wherein the ratio of reactive heterocycloalkyl functional groups to reactive silicon hydride functional groups in the composition is in the range of 1:5 to 5:1.
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公开(公告)号:US20190031932A1
公开(公告)日:2019-01-31
申请号:US16148766
申请日:2018-10-01
Inventor: Jianfeng Zhang , Michael J. Tzivanis , Xipeng Liu , Jian L. Ding
IPC: C09J183/06
Abstract: This disclosure relates to polymerizable silicone compositions, methods for polymerizing such compositions, and to polymerized silicone compositions formed thereby. In one embodiment, a polymerizable composition includes one or more first organosiloxanes or organosilanes, each comprising a plurality of silicon hydride functional groups, one or more second organosiloxanes or organosilanes, each comprising a plurality of reactive heterocycloalkyl functional groups; and one or more third organosiloxanes or organosilanes, each comprising at least about one silicon hydride functional group and at least about one reactive heterocycloalkyl functional group; and an effective amount of a borane catalyst, present, for example, in an amount within the range of 0.0005 wt % to about 10 wt %, wherein the ratio of reactive heterocycloalkyl functional groups to reactive silicon hydride functional groups in the composition is in the range of 1:5 to 5:1. The compositions and methods are useful, for example, in adhesive and sealing applications.
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公开(公告)号:US09982809B2
公开(公告)日:2018-05-29
申请号:US15395437
申请日:2016-12-30
Inventor: Adam P. Nadeau , Jianfeng Zhang
IPC: F16L11/04 , B29C35/08 , B29C47/06 , B32B1/08 , B32B7/12 , B32B27/28 , C09J119/00 , B29C47/00 , B29K83/00 , B29K101/12 , B29K105/00 , B29K105/24 , B29C35/10
CPC classification number: F16L11/04 , B29C35/0805 , B29C35/0866 , B29C35/10 , B29C47/0004 , B29C47/0023 , B29C47/065 , B29C2035/0822 , B29C2035/0827 , B29C2035/0833 , B29C2035/085 , B29C2035/0877 , B29K2083/00 , B29K2101/12 , B29K2105/0097 , B29K2105/24 , B32B1/08 , B32B7/12 , B32B25/042 , B32B25/08 , B32B25/20 , B32B27/06 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/20 , B32B27/281 , B32B27/283 , B32B27/285 , B32B27/302 , B32B27/306 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/40 , B32B2250/03 , B32B2270/00 , B32B2274/00 , B32B2307/4026 , B32B2307/50 , B32B2307/58 , B32B2307/70 , B32B2307/714 , B32B2307/724 , B32B2307/726 , B32B2307/732 , B32B2307/746 , B32B2535/00 , B32B2605/00 , C09J119/00
Abstract: A composite tube includes an inner layer including a silicone polymer, wherein the inner layer has a surface that defines a central lumen of the composite tube; an adhesive layer adjacent to the inner layer, wherein the adhesive layer includes an adhesive silicone material including a silicone polymer and an adhesion promoter, and an outer layer adjacent to the adhesive layer, wherein the outer layer includes a thermoplastic polymer having a functional group that forms a chemical bond with the adhesion promoter of the adhesive silicone material.
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公开(公告)号:US12049978B2
公开(公告)日:2024-07-30
申请号:US17130167
申请日:2020-12-22
Inventor: Jianfeng Zhang , Rachel Z. Pytel , Jian L. Ding
CPC classification number: F16L55/1003 , F16L11/12
Abstract: A profile includes: a sidewall, a lumen for a fluid path, and an end, the profile including a thermoset material, wherein the profile includes a sealed end without an external bonding material, wherein the sealed end withstands a seal integrity pressure test of at least 1 psi, such as at least 5 psi, such as at least 10 psi, such as at least 15 psi, or even at least 20 psi air pressure for about 30 minutes under dry and wet conditions.
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公开(公告)号:US11878476B2
公开(公告)日:2024-01-23
申请号:US17348387
申请日:2021-06-15
Inventor: Jianfeng Zhang , Scott R. Johnson , Heidi Lennon
IPC: B29C65/00 , B29C65/56 , B29K683/00 , B29K669/00
CPC classification number: B29C66/712 , B29C65/56 , B29C66/028 , B29K2669/00 , B29K2683/00
Abstract: The present disclosure relates to a composite article that may include a plastic component, and a silicone component bonded the plastic component. The plastic component and the silicone component may be bonded at an intersecting region between a first surface of the plastic component and a first surface of the silicone component. The intersecting region may include at least one of an acetone content of not greater than about 0.2 ppm, an MEK content of not greater than about 0.2 ppm, or a trimethylsilanol content of not greater than about 0.2 ppm.
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公开(公告)号:US11590333B2
公开(公告)日:2023-02-28
申请号:US16254369
申请日:2019-01-22
Inventor: Jianfeng Zhang , Xipeng Liu , Jian L. Ding
Abstract: A tubular coupling comprising a first connector comprising a body defining a first passageway portion and a valve area, the valve area comprising a first volume adjacent to an end of the first passageway portion; and a second volume in fluid communication with the first volume; and a first valve disposed in the first volume of the valve area; and a second connector adapted to receive at least a portion of the first connector, the second connector comprising: a body defining a second passageway portion and a valve area, the valve area comprising: a first volume adjacent to an end of the second passageway portion; and a second volume in fluid communication with the first volume; and a second valve disposed in the first volume of the valve area.
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公开(公告)号:US11267944B2
公开(公告)日:2022-03-08
申请号:US15395381
申请日:2016-12-30
Inventor: Xipeng Liu , Michael J. Tzivanis , Jianfeng Zhang
IPC: C08J7/12 , B29C64/124 , C08K5/56 , B33Y80/00 , A61L31/06 , B29C35/08 , C09J183/14 , C08G77/12 , C08G77/20 , B33Y10/00 , B33Y70/00 , B29K83/00 , B29K105/00
Abstract: A radiation curable article includes a silicone composition including a silicone oligomer and a photoactive catalyst, wherein the silicone oligomer comprises at least one alkenyl group and at least one hydride group, the radiation curable silicone oligomer having a viscosity of less than about 100,000 centipoise prior to cure. Further included is a method of forming a radiation curable article includes providing a silicone composition including a silicone oligomer and a photoactive catalyst, wherein the silicone oligomer includes at least one alkenyl group and at least one hydride group, the silicone oligomer having a viscosity of less than about 100,000 centipoise prior to cure; and irradiating the silicone composition with a radiation source.
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