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1.发明授权
公开(公告)号：US4564511A
公开(公告)日：1986-01-14
申请号：US672394
申请日：1984-11-16
IPC分类号： C01B33/20 , B01J29/04 , C01B35/10 , C01B39/06 , C07B61/00 , C07C1/20 , C07C5/27 , C07C15/073 , C07C15/08
CPC分类号： C01B35/1009 , B01J23/30 , B01J23/88 , B01J29/03 , C01B33/2876 , C01B33/2884
摘要： A method for preparing a molecular sieving metallosilicate is disclosed which comprises(A) providing a mixture comprising: water; an oxide of silicon source; a mineralizing agent and/or synthesis directing agent; and a heteropolymetallate of the formulaA.sub.a L.sub.l M.sub.m J.sub.z O.sub.y .dH.sub.2 O whereinA is an ion selected from the group consisting of hydrogen; one or more of the Group I-A to VI-A or Group I-B to VI-B metals; one or more of the rare earth metals; ammonium, alkyl ammonium, alkyl phosphonium or alkyl arsonium; or a mixture of two or more thereof;M is Zn, Ga, Ge, Ti, Cr, Mn, Fe, Co, B, Ni, Rh, Zr or a mixture of two or more thereof;L is P, As, Si, Al, H or a mixture of two or more thereof;J is Mo, W, V, Nb or a mixture of two or more thereof;a is a number which when multiplied by the charge of A will result in balancing the charge on the complex within the brackets;l is a number ranging from zero to about 20;m is a number ranging from zero to about 20;z is a number ranging from about 1 to about 50;y is a number ranging from about 7 to about 150;d is a number ranging from about zero to about 150; and(B) maintaining said mixture at a temperature of about 80.degree. C. to about 300.degree. C. for an effective period of to form said molecular sieving metallosilicate.
摘要翻译： 公开了一种制备分子筛金属硅酸盐的方法，其包括（A）提供包含水的混合物; 硅源的氧化物; 矿化剂和/或合成导向剂; 以及式AaL1MmJzOy·dH2O的杂多金属铝，其中A是选自氢的离子; I-A至VI-A族或I-B至VI-B族金属中的一种或多种; 一种或多种稀土金属; 铵，烷基铵，烷基鏻或烷基ium ium; 或其两种或更多种的混合物; M是Zn，Ga，Ge，Ti，Cr，Mn，Fe，Co，B，Ni，Rh，Zr或其两种或更多种的混合物; L是P，As，Si，Al，H或其两种或更多种的混合物; J为Mo，W，V，Nb或其两种以上的混合物; a是一个数字，当乘以A的费用将导致平衡在括号内的复合体的费用; l是从零到大约20的数字; m是从零到大约20的数字; z为约1至约50的数; y为约7至约150的数; d为约0至约150的数; 和（B）将所述混合物保持在约80℃至约300℃的温度下进行有效时间以形成所述分子筛金属硅酸盐。
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2.发明授权Synthesis of molecular sieving high silica mordenite using synthesis directing organic dyes 失效使用合成指导有机染料合成分子筛高硅石丝光沸石
公开(公告)号：US4585640A
公开(公告)日：1986-04-29
申请号：US672403
申请日：1984-11-16
CPC分类号： C01B39/06 , B01J29/18 , C01B39/265 , Y10S423/25
摘要： A method is disclosed for making molecular sieving high silica mordenite comprising the steps of:(A) providing a mixture comprising: water; an oxide of silicon source; an oxide of aluminum source; a mineralizing agent; and a synthesis directing nitrogen containing organic dye; and(B) maintaining said mixture at a temperature of about 80.degree. C. to about 300.degree. C. for an effective period of time to provide said mordenite.
摘要翻译： 公开了一种用于制备分子筛高二氧化硅丝光沸石的方法，包括以下步骤：（A）提供包含以下物质的混合物：水; 硅源的氧化物; 铝源氧化物; 矿化剂; 和含氮有机染料的合成方法; 和（B）将所述混合物在约80℃至约300℃的温度下保持一段有效的时间以提供所述丝光沸石。
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3.发明授权
公开(公告)号：US4582693A
公开(公告)日：1986-04-15
申请号：US672406
申请日：1984-11-16
IPC分类号： B01J29/035 , C01B33/18 , C01B33/28 , B01J21/08
CPC分类号： C01B33/18 , B01J29/035 , C01P2002/22 , C01P2002/72 , C01P2002/74 , C01P2006/80
摘要： A method is disclosed for making a silica molecular sieve comprising:(A) providing a mixture comprising: water; an oxide, hydroxide or alkoxide of silicon; a mineralizing agent; and a synthesis directing nitrogen containing organic dye; and(B) maintaining said mixture at a temperature of about 80.degree. C. to about 300.degree. C. for an effective period of time to provide said silica molecular sieve.
摘要翻译： 公开了制备二氧化硅分子筛的方法，其包括：（A）提供包含水的混合物; 硅的氧化物，氢氧化物或醇盐; 矿化剂; 和含氮有机染料的合成方法; 和（B）将所述混合物在约80℃至约300℃的温度下保持有效的时间以提供所述二氧化硅分子筛。
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4.发明授权Process for the preparation of metallosilicates of tetravalent lanthanide and actinide series metals using heterpoly metallates 失效使用杂多金属盐制备四价镧系元素和锕系金属的金属硅酸盐的方法
公开(公告)号：US4681747A
公开(公告)日：1987-07-21
申请号：US672594
申请日：1984-11-16
IPC分类号： B01J29/00 , B01J29/04 , B01J29/40 , C01B33/20 , C01B39/10 , C01B39/12 , C01B39/40 , C07B61/00 , C07C1/00 , C07C1/20 , C07C11/02 , C07C67/00 , C01B35/10
CPC分类号： C07C1/20 , B01J29/04 , C01B33/2876 , C01B35/1009 , C07C2529/04
摘要： A molecular sieving metallosilicate is disclosed which comprises a complex represented in terms of mole ratios of oxides by the formula: ##STR1## wherein A is an ammonium, alkyl ammonium, alkyl phosphonium or alkyl arsonium ion; D is an alkali or alkaline earth metal ion or a mixture of two or more thereof; E is selected from the group consisting of Al, B, Mo, W, Fe, or a mixture of two or more thereof; M is a tetravalent metal selected from the Lanthanide or Actinide series; a is a number ranging from zero to about 25; b is a number ranging from zero to about 1.5; c is a number ranging from zero to about 0.3; d is a number ranging from about 20 to about 500; e is a number ranging from zero to about 200. The X-ray diffraction pattern for these metallosilicates indicates a ZSM-5 like crystalline structure. A method for making these metallosilicates, and a method for dehydrating and reforming methanol using these metallosilicates are disclosed.
摘要翻译： 公开了一种分子筛金属硅酸盐，其包含以下列化学式的氧化物的摩尔比表示的络合物：其中A是铵，烷基铵，烷基鏻或烷基钪离子; D是碱金属或碱土金属离子或其两种或多种的混合物; E选自Al，B，Mo，W，Fe或其两种或更多种的混合物; M是选自镧系元素或锕系元素的四价金属; a是从零到大约25的数字; b是从零到大约1.5的数字; c为零至约0.3的数; d为约20至约500的数; e是从零到约200的数。这些金属硅酸盐的X射线衍射图表示ZSM-5样晶体结构。 公开了制造这些金属硅酸盐的方法，以及使用这些金属硅酸盐使甲醇脱水和重整的方法。
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公开(公告)号：US4891164A
公开(公告)日：1990-01-02
申请号：US294951
申请日：1989-01-06
IPC分类号： G21F9/10
CPC分类号： G21F9/10
摘要： A method is disclosed for separating and immobilizing a radioactive material comprising: contacting an aqueous medium containing said radioactive material with a reactive composition comprising at least one alkali metal, at least one Group IIIB metal and at least one phosphorus oxide; maintaining said reactive composition in contact with said aqueous medium for an effective period of time to react a desired amount of said radioactive material with said reactive composition to form a radioactive-material-containing composition; and separating said radioactive-material-containing composition from said aqueous medium. Radioactive-material-containing compositions exhibiting low leach rates are also disclosed.
摘要翻译： 公开了用于分离和固定放射性材料的方法，包括：使含有所述放射性物质的水性介质与包含至少一种碱金属，至少一种IIIB族金属和至少一种氧化磷的反应性组合物接触; 保持所述反应性组合物与所述水性介质接触有效的时间以使所需量的所述放射性物质与所述反应性组合物反应以形成含放射性材料的组合物; 并将所述含放射性材料的组合物与所述水性介质分离。 还公开了显示低浸出率的含放射性材料的组合物。
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公开(公告)号：US4603185A
公开(公告)日：1986-07-29
申请号：US565430
申请日：1983-12-27
CPC分类号： C08F38/00
摘要： Acetylene and other 1-alkynes are polymerized by a catalyst system comprised of a transition metal complex consisting of at least one binucleating ligand attached to at least one transition metal containing nucleus; and at least one organometallic cocatalyst containing at least one element of Group 1a, 2a or Group 3a.
摘要翻译： 乙炔和其它1-炔烃通过催化剂体系聚合，所述催化剂体系包含由至少一个连接至至少一个含有过渡金属的过渡金属的双核配体组成的过渡金属络合物; 和至少一种含有1a，2a或3a族的至少一种元素的有机金属助催化剂。
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公开(公告)号：US4630176A
公开(公告)日：1986-12-16
申请号：US801111
申请日：1985-11-22
IPC分类号： H01G11/22 , C01B31/08 , H01G9/00 , H01G11/24 , H01G11/30 , H01G11/42 , H01G11/44 , H01G11/86
摘要： Improved activated carbon electrodes are disclosed which electrodes have increased charge storage capacity and reduced leakage current. Such improved electrodes are incorporated into energy storage devices such as electric double layer capacitors. The improved charge storage capacity is due to the adsorption of polyoxometalate compounds onto the activated carbon, and reduced leakage current is achieved by stabilizing the polyoxometalate compounds within the activated carbon through the use of a compound capable of generating at least one ionic site.
摘要翻译： 公开了改进的活性炭电极，其中电极具有增加的电荷存储容量和减少的漏电流。 这种改进的电极被并入诸如双电层电容器的能量存储装置中。 改进的电荷存储容量是由于多金属氧酸盐化合物吸附到活性炭上，并且通过使用能够产生至少一个离子位点的化合物稳定活性炭内的多金属氧酸盐化合物来实现减少的漏电流。
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8.发明授权Preparation of polyamide with catalyst comprising transition metal attached to a ligand which contains electron withdrawing groups 失效用包含连接到含有吸电子基团的配体的过渡金属的催化剂制备聚酰胺
公开(公告)号：US4628077A
公开(公告)日：1986-12-09
申请号：US794584
申请日：1985-11-01
摘要： A novel transition metal complex catalyst comprised of a transition metal attached to a ligand containing electron withdrawing substituents is employed in a polymerization process for producing nylon type polyamides.
摘要翻译： 在连接到含有吸电子取代基的配位体上的过渡金属组成的新型过渡金属络合物催化剂用于生产尼龙型聚酰胺的聚合方法中。
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公开(公告)号：US4766265A
公开(公告)日：1988-08-23
申请号：US59433
申请日：1987-06-08
申请人： Michael J. Desmond , Joann Henry
发明人： Michael J. Desmond , Joann Henry
IPC分类号： B01J29/42 , B01J29/40 , B01J29/48 , C07B61/00 , C07C1/00 , C07C2/00 , C07C2/42 , C07C67/00 , C07C
CPC分类号： C07C2/00 , C07C2529/40
摘要： The invention relates to a process for the conversion of ethane to liquid aromatic hydrocarbons comprising contacting, at a temperature of from about 500.degree. C. to about 700.degree. C., an ethane rich feedstock with a catalyst comprising a gallium modified molecular sieve catalyst, promoted with rhenium and a metal selected from the group consisting of nickel, palladium, platinum, rhodium and iridium.
摘要翻译： 本发明涉及一种将乙烷转化成液体芳烃的方法，包括在约500℃至约700℃的温度下，将富含乙烷的原料与包含镓改性分子筛催化剂的催化剂接触， 用铼和选自镍，钯，铂，铑和铱的金属促进。
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公开(公告)号：US4634686A
公开(公告)日：1987-01-06
申请号：US729594
申请日：1985-05-02
CPC分类号： B01J29/04
摘要： A yttrium-silicate molecular sieve is disclosed which comprises a complex represented in terms of mole ratios of oxides as follows:aA.sub.2 O:Y.sub.2 O.sub.3 :bSiO.sub.2 :cH.sub.2 Owherein A is an alkali metal; a is a number ranging from about 0.5 to about 20; b is a number ranging from about 2 to about 400; and c is a number ranging from about 1 to about 500.
摘要翻译： 公开了一种钇硅酸盐分子筛，其包含以下列氧化物摩尔比表示的络合物：aA 2 O：Y 2 O 3 :bSiO 2 :cH 2 O其中A为碱金属; a为约0.5至约20的数; b为约2至约400; 且c为约1至约500的数。
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