Abstract:
Sometimes, a problem is obvious, everyone sees it, but nothing happens until someone decides to do something useful about it. Methods are herein provided for recovering heavy hydrocarbons from plastic materials and/or geo-formation. In one solution set, PVC waste materials are emulsified by an amine solvent in an aqueous phase, thereby extracting heavier hydrocarbons from the primary structure of PVC into the amine aqueous phase; followed by de-emulsifying the extracted heavier hydrocarbons by separating and recovering the amine solvent, and then separating the de-emulsified heavier hydrocarbons from the aqueous phase by a hydrophobic membrane.
Abstract:
Methods are herein provided for preparing a material for casting a flat-sheet, extruding a solid-fiber, and/or extruding a hollow-fiber utilizing a chlorinated aqueous amine solution as an effective solvent to form a crystalline polymorph structure of the material. This material in the form of, for example, an effective vapor permeable membrane can be used in membrane distillation to desalinate saline streams.
Abstract:
The invention presents innovative methods to de-scale sulfate-rich saline streams such as seawater and the like in conjunction with desalination processes. The effective de-scaling of such streams by the inventive methods: (1) enhances the performance, efficiency and cost effectiveness of desalination processes; and (2) allows the viable use of the de-scaled reject brine from desalination processes, for example, as a suitable saline water for oil-gas field's water injection operations to improve hydrocarbons recovery and/or as a feed stock for chlor-alkali industries.
Abstract:
Methods are disclosed to treat produced water from hydrocarbons production facilities. The disclosed methods can be used to either: (1) de-NORM produced water; or (2) de-NORM and partially de-salt produced water; or (3) de-NORM and partially de-salt and de-ionize produced water; or (4) de-oil, de-NORM, de-salt and de-ionize produced water.
Abstract:
Methods for the removal of alkaline and sulfate scales from aqueous saline streams such as seawater, oil-gas fields produced waters, formation waters, and the like. Such processing methods can also be extended for the simultaneous removal of hydrogen sulfide, and/or sulfur dioxide, and/or oxides of nitrogen, and/or carbon dioxide from gaseous streams. The same processing concept with modified methods can further be employed for the removal of gases such as radon, hydrogen sulfide, sulfur dioxide, oxides of nitrogen, and carbon dioxide from gaseous streams.
Abstract:
Providing new distilling and/or de-scaling methods and systems herein is a matter of allowing for thermal balance without the need to fill a hot wet emulsion separation system with more steam and heat rejection devices to waste steam. A solutions set begins with efficiently utilizing three types of waste: (1) de-oiled and/or cooled down produced water; (2) blowdown steam from drum-type boilers (DBs); and (3) return condensate of dry steam from the DBs. It ends with: (1) removing calcium hardness, magnesium hardness and silica, thereby recovering them as useful minerals; and (2) producing distillate for viscous oil recovery by steam injection and de-scaled hot brine for improved oil recovery by hot water flooding and/or other related methods. The vehicle to attain this solutions' set is a multi-effect distillation train comprises a backward feed section along with two flashing stages.
Abstract:
Dumping a reverse osmosis (RO) reject stream from a wastewater treatment and reclamation plant (WWTRP) into the sea directly destroys aquatic life and indirectly affects public health. This triggers solving the problem by methods and systems provided herein. One embodiment begins with utilizing two types of waste; one is the RO reject stream in its entirety, and the other is letdown steam from once-through-steam-generators (OTSGs) or steam from a standalone OTSG fueled by co-produced sour gas. It ends with thermally sterilizing toxicity and isolating it by the alkalinity content of the RO reject stream itself, combating sulfate scale and recovering it as a useful product, and producing distillate for heavy oil recovery by steam injection and de-scaled brine for improved oil recovery by water flooding. The vehicle to attain this set of solutions is a recycle-brine multi-stage flash (RB-MSF) desalination train with two modified flashing stages.
Abstract:
This invention presents innovative and off the beaten path methods to mainly produce suitable saline streams for oil-fields water injection operations. The production of such suitable saline streams can: (1) be achieved economically; and (2) meet the actual stringent requirements for injection operations to steadily enhance oil production from depleted and plugged wells.
Abstract:
Methods are disclosed to de-sulfate saline streams such as seawater, brine from seawater desalination plants, and the like. The disclosed methods can also co-produce de-ionized water and inorganic materials from such de-sulfated saline streams.
Abstract:
Methods are disclosed for the selective separation of sulfate from a saline stream such as seawater to produce nearly sulfate-free saline stream for oil-fields water injection operations. The separated sulfate in the form of gypsum from the treated saline stream can be used in different applications.