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    Multicyclic metallocycle metallocenes and their use
    3.
    发明授权
    Multicyclic metallocycle metallocenes and their use 失效
    多环金属茂金属及其用途

    公开(公告)号：US06340651B1

    公开(公告)日：2002-01-22

    申请号：US09299461

    申请日：1999-04-26

    Applicant: Erik Licht ,  Helmut G. Alt ,  M. Bruce Welch

    Inventor： Erik Licht ,  Helmut G. Alt ,  M. Bruce Welch

    IPC: B01J3100

    CPC classification number: B01J31/14 ,  B01J31/122 ,  B01J31/2295 ,  B01J2531/48 ,  C07F17/00 ,  C08F4/65912 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/65927

    Abstract: A process for producing a metallocycle metallocene comprising reacting a reactant metallocene which has a cyclopentadienyl group having an alkenyl group attached which has at least 3 carbon atoms with about 2 molar equivalents of an alkali metal alkyl having at least 4 carbon atoms, catalyst systems resulting from the combination of the metallocycle metallocene and an organic cocatalyst, and polymerization processes using such catalyst systems are disclosed.

    Abstract translation: 一种制备金属茂金属茂的方法，包括使具有至少具有3个碳原子的具有链烯基的环戊二烯基的反应物金属茂与约2摩尔当量的具有至少4个碳原子的碱金属烷基反应，由 公开了金属茂金属和有机助催化剂的组合以及使用这种催化剂体系的聚合方法。

    Metallocycle metallocenes and their use
    4.
    发明授权
    Metallocycle metallocenes and their use 失效
    金属环茂金属及其用途

    公开(公告)号：US06329312B1

    公开(公告)日：2001-12-11

    申请号：US09334890

    申请日：1999-06-17

    Applicant: Erik Licht ,  Helmut G. Alt ,  M. Bruce Welch

    Inventor： Erik Licht ,  Helmut G. Alt ,  M. Bruce Welch

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65925 ,  C08F110/02 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/20

    Abstract: Metallocycle metallocenes are produced by reacting a first metallocene having an aralkyl group or an aryl dialkyl silyl group attached to a cyclodienyl group with about two molar equivalents of an alkali metal alkyl having at least 4 carbon atoms. The use of the metallocycle metallocenes as components of catalyst for the polymerization of olefins is also disclosed.

    Abstract translation: 金属环金属茂是通过使具有芳环烷基的第一茂金属或与环二烯基连接的芳基二烷基甲硅烷基与约2摩尔当量的具有至少4个碳原子的碱金属烷基反应来制备的。 还公开了使用金属茂金属茂作为烯烃聚合的催化剂的组分。

    Processes to produce metallocene compounds and polymerization processes therewith
    8.
    发明授权
    Processes to produce metallocene compounds and polymerization processes therewith 失效
    制备茂金属化合物的方法及其聚合方法

    公开(公告)号：US5726264A

    公开(公告)日：1998-03-10

    申请号：US663885

    申请日：1996-06-14

    Applicant: Michael Jung ,  Helmut G. Alt ,  M. Bruce Welch

    Inventor： Michael Jung ,  Helmut G. Alt ,  M. Bruce Welch

    IPC: C07F17/00 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/68 ,  C08F4/69 ,  C08F10/00

    CPC classification number: C07F17/00 ,  C08F10/00 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/63927

    Abstract: A process to produce an ethylene-bridged-metallocene-transition-metal compound that has an omega-alkenyl substitution on said ethylene bridge is provided. Said process comprises: contacting a diolefin compound with a peracid compound to form an omega-alkenyl oxirane compound; contacting said omega-alkenyl oxirane compound with an organometal compound to form an organo-omega-alkenyl-alcohol compound; contacting said organo-omega-alkenyl-alcohol compound with an organosulfur compound to form an organo-omega-alkenyl-organosulfur ester compound; contacting said organo-omega-alkenyl-organosulfur ester compound with an organometal to form an orgaomega-alkenyl-organo compound; contacting said organo-omega-alkenyl-organo compound with a transition metal compound to form a organo-omega-alkenyl-organo-transition compound. Additionally, processes to polymerize olefins using these compounds is provided.

    Abstract translation: 提供了一种制备在所述乙烯桥上具有ω-烯基取代基的乙烯桥连茂金属 - 过渡金属化合物的方法。 所述方法包括：使二烯烃化合物与过酸化合物接触以形成ω-烯基环氧乙烷化合物; 使所述ω-烯基环氧乙烷化合物与有机金属化合物接触以形成有机ω-链烯基 - 醇化合物; 使有机ω-链烯基醇化合物与有机硫化合物接触以形成有机ω-链烯基 - 有机硫酯化合物; 使所述有机ω-链烯基 - 有机硫酯化合物与有机金属化合物接触以形成有机 - 烯基 - 有机化合物; 使所述有机ω-烯基 - 有机化合物与过渡金属化合物接触以形成有机ω-烯基 - 有机 - 过渡化合物。 另外，提供了使用这些化合物聚合烯烃的方法。

    Catalyst systems and polymerization processes
    9.
    发明授权
    Catalyst systems and polymerization processes 失效
    催化剂体系和聚合方法

    公开(公告)号：US5565396A

    公开(公告)日：1996-10-15

    申请号：US444990

    申请日：1995-05-19

    Applicant: Krisztina Frey ,  Gabriele von Massow ,  Helmut G. Alt ,  M. Bruce Welch

    Inventor： Krisztina Frey ,  Gabriele von Massow ,  Helmut G. Alt ,  M. Bruce Welch

    IPC: C07F9/50 ,  C07F17/00 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/62 ,  C08F4/64

    CPC classification number: C08F10/00 ,  C07F17/00 ,  C07F9/5018 ,  C08F110/02 ,  C08F210/16 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/6392 ,  C08F4/65912 ,  C08F4/6592 ,  Y10S526/943

    Abstract: In accordance with the present invention there is provided a cyclopentadienyl-type ligand represented by the formula ZA, wherein Z is a cyclopentadienyl-type group, wherein A is --YPR.sub.2, --YNR.sub.2, or --NR.sub.2, wherein Y is an alkylene group containing 1 to 24 carbon atoms, wherein each R is individually selected from alkyl groups containing 1 to 20 carbon atoms. Another aspect of the invention is to provide a metallocene represented by the formula ZAMX.sub.3, wherein Z and A are as described above, M is a Group IVB or VB transition metal, and X is a halide. Other aspects of the present invention include catalyst systems comprising the metallocenes and an organoaluminoxane, processes for preparing the above defined ligands, metallocenes and catalyst systems, and polymerization processes employing the catalyst systems.

    Abstract translation: 根据本发明，提供由式ZA表示的环戊二烯基型配体，其中Z是环戊二烯基型基团，其中A是-YPR 2，-YNR 2或-NR 2，其中Y是含1的亚烷基 至24个碳原子，其中每个R各自选自含有1至20个碳原子的烷基。 本发明的另一方面是提供由式ZAMX3表示的金属茂，其中Z和A如上所述，M是IVB或VB族过渡金属，X是卤化物。 本发明的其它方面包括包含金属茂和有机铝氧烷的催化剂体系，制备上述配体的方法，金属茂和催化剂体系，以及采用催化剂体系的聚合方法。

    CH ACTIVATION/DEHYDROGENATION OF HYDROCARBONS
    10.
    发明申请
    CH ACTIVATION/DEHYDROGENATION OF HYDROCARBONS 审中-公开
    CH活化/脱氢烃

    公开(公告)号：US20080242911A1

    公开(公告)日：2008-10-02

    申请号：US11865882

    申请日：2007-10-02

    Applicant: Ingrid Boehmer ,  M. Bruce Welch ,  Roland Schmidt ,  Bruce B. Randolph ,  Helmut G. Alt

    Inventor： Ingrid Boehmer ,  M. Bruce Welch ,  Roland Schmidt ,  Bruce B. Randolph ,  Helmut G. Alt

    IPC: C07C5/333

    CPC classification number: B01J31/2404 ,  B01J31/1616 ,  B01J31/4092 ,  B01J2231/46 ,  B01J2231/70 ,  B01J2531/827 ,  B01J2531/828

    Abstract: A catalyst comprising a 1) complex comprising: a) at least one metal selected from the group consisting of Group 8 metals, Group 9 metals, Group 10 metals, and combinations thereof; b) a compound having the formula R3X wherein R is selected from the group consisting of hydrogen, an alkyl, an alkenyl, an alkynyl, cycloalkyls, cycloalkenyls, cycloalkynyls, aryls, substituted aryls, and substituted organic compounds and wherein X is a Group 15 element selected from the group consisting of nitrogen, phosphorus, arsenic, antimony and bismuth; and 2) support component comprising a silicon-containing compound and a method of making said catalyst, is disclosed. The catalyst is then used to dehydrogenate hydrocarbons in a dehydrogenation reaction zone under dehydrogenation reaction conditions.

    Abstract translation: 一种催化剂，其包含1）络合物，其包含：a）选自第8族金属，第9族金属，第10族金属及其组合的至少一种金属; b）具有式R 3 X的化合物，其中R选自氢，烷基，烯基，炔基，环烷基，环烯基，环炔基，芳基，取代的芳基和取代的 有机化合物，其中X是选自氮，磷，砷，锑和铋的第15族元素; 和2）包含含硅化合物的载体组分和制备所述催化剂的方法。 然后催化剂用于在脱氢反应条件下脱氢反应区中的烃脱氢。

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