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    Polysilicate esters for oil reservoir permeability control
    2.
    发明授权
    Polysilicate esters for oil reservoir permeability control 失效
    用于油藏渗透性控制的聚硅酸酯

    公开(公告)号：US4660640A

    公开(公告)日：1987-04-28

    申请号：US697098

    申请日：1985-02-01

    申请人： Dennis H. Hoskin ,  Louis D. Rollmann

    发明人： Dennis H. Hoskin ,  Louis D. Rollmann

    IPC分类号： C09K8/508 ,  C09K8/88 ,  E21B33/138

    CPC分类号： C09K8/885 ,  C09K8/5086

    摘要： The permeability of subterranean oil-bearing formations is controlled by injection of an organic polysilicate ester. The ester may be derived from simple, monohydroxylic alcohols such as methanol, ethanol, propanol or butanol, from diols such as ethylene glycol, from polyols such as glycerol and alkylene oxide polymerization products and from other organic compounds containing function hydroxy groups, for example, partial ethers and esters of glycols and polyols. The polysilicates are injected into a formation through injection wells, suitably in an amount from 10 to 100% of the pore volume of the zone to be treated. In the formation, the polysilicate esters form gels which selectively plug the high permeability regions of the formation, to divert the flow of flooding liquid used in flooding operations to the less permeable regions of the formation.

    摘要翻译： 通过注入有机聚硅酸酯酯来控制地下含油地层的渗透性。 该酯可以从二醇如乙二醇，多元醇如甘油和烯化氧聚合产物和其它含有官能羟基的有机化合物衍生自简单的单羟基醇如甲醇，乙醇，丙醇或丁醇，例如， 二醇和多元醇的部分醚和酯。 将多硅酸盐通过注入孔注入地层中，适当地为待处理区域的孔体积的10至100％。 在形成中，聚硅酸酯形成凝胶，其选择性地堵塞地层的高渗透性区域，以将用于淹没操作的溢流液体的流动转移到地层的较不可渗透的区域。

    Method for production of heavy oil from tar sands
    3.
    发明授权
    Method for production of heavy oil from tar sands 失效
    从焦油砂生产重油的方法

    公开(公告)号：US4379489A

    公开(公告)日：1983-04-12

    申请号：US209355

    申请日：1980-11-24

    申请人： Louis D. Rollmann

    发明人： Louis D. Rollmann

    IPC分类号： E21B36/02 ,  E21B43/16 ,  E21B43/24 ,  E21B43/40 ,  E21B43/22

    CPC分类号： E21B43/243 ,  E21B43/16 ,  E21B43/40

    摘要： An enhanced recovery process in which liquid sulfur is burned in an oyxgen-containing gas underground to form SO.sub.2. The SO.sub.2 may itself act as a drive fluid for the recovery of oil or it may react with limestone in the formation to form CO.sub.2, an alternate drive fluid.

    摘要翻译： 一种增强的回收方法，其中液体硫在含有含氧气体的地下燃烧形成SO 2。 SO 2本身可以作为用于回收油的驱动流体，或者它可能与地层中的石灰石反应形成二氧化碳，另一驱动流体。

    Synthesis ZSM-48
    4.
    发明授权
    Synthesis ZSM-48 失效
    合成ZSM-48

    公开(公告)号：US5961951A

    公开(公告)日：1999-10-05

    申请号：US5969

    申请日：1998-01-12

    申请人： Carrie L. Kennedy ,  Louis D. Rollmann ,  John L. Schlenker

    发明人： Carrie L. Kennedy ,  Louis D. Rollmann ,  John L. Schlenker

    IPC分类号： B01J29/74 ,  C01B39/48

    CPC分类号： C01B39/48

    摘要： The present invention relates to a composition and a method for preparing ZSM-48 exhibiting an X-ray pattern having values as set forth in Table 1 of the specification. The method of the present invention includes (a) preparing a reaction mixture; and (b) maintaining the mixture under crystallization conditions until crystals of the ZSM-48 are formed. The mixture includes a source of silica, a source of trivalent metal oxide, an alkali metal oxide, ethylenediamine and water. The mixture, in terms of mole ratios of oxides, has the following composition ranges:SiO.sub.2 /Me.sub.2 O.sub.3 : 100 to 1500,M.sub.2/n O/SiO.sub.2 : 0 to 0.2,RN/SiO.sub.2 : 2.0 to 5.0,OH.sup.- /SiO.sub.2 : 0 to 0.3, andH.sub.2 O/SiO.sub.2 : 10 to 100,wherein Me is a trivalent metal, M is an alkali metal and RN is ethylenediamine.

    摘要翻译： 本发明涉及一种制备ZSM-48的组合物和方法，该ZSM-48具有如本说明书的表1中所列的值的X射线图案。 本发明的方法包括（a）制备反应混合物; 和（b）将混合物保持在结晶条件下，直到形成ZSM-48的晶体。 该混合物包括二氧化硅源，三价金属氧化物源，碱金属氧化物，乙二胺和水。 该混合物以氧化物的摩尔比计具有以下组成范围：SiO 2 / Me 2 O 3：100至1500，M 2 / nO / SiO 2：0至0.2，RN / SiO 2：2.0至5.0 OH- / SiO 2：0至 0.3，H 2 O / SiO 2：10〜100，其中Me为三价金属，M为碱金属，RN为乙二胺。

    Upgrading heavy crude oils to lighter products with a dispersed zeolite
    5.
    发明授权
    Upgrading heavy crude oils to lighter products with a dispersed zeolite 失效
    将重质原油用分散的沸石升级到较轻的产品

    公开(公告)号：US4536282A

    公开(公告)日：1985-08-20

    申请号：US616883

    申请日：1984-06-04

    申请人： Louis D. Rollmann

    发明人： Louis D. Rollmann

    IPC分类号： C10G11/05 ,  C10G11/14

    CPC分类号： C10G11/05 ,  C10G11/14

    摘要： This invention provides a process for upgrading a variety of hydrocarbon oils including low-grade crudes and fractions thereof. In this process, a hydrocarbon oil having an ASTM 50% temperature not higher than 550.degree. F. is converted at low temperature and pressure to more volatile products by a dispersion of crystalline zeolite catalysts having a silica: alumina ratio of at least 12 and a C.I. within 1-12. Initially, 0.02-10 wt % of the catalyst is dispersed in the feed until the catalyst inventory in the reactor stage accumulates. Thereafter, catalyst is added and removed to maintain a total catalyst content not greater than about 35 wt % of the feed in the reactor.

    摘要翻译： 本发明提供了一种升级包括低级原油及其馏分在内的各种烃油的方法。 在该方法中，具有ASTM50％温度不高于550°F的烃油通过二氧化硅：氧化铝比至少为12的结晶沸石催化剂的分散体在低温和高压下转化成更易挥发的产物， CI 在1-12之内。 最初，将0.02-10重量％的催化剂分散在进料中，直到反应器阶段的催化剂存量累积。 此后，加入并除去催化剂以保持反应器中进料总催化剂含量不超过约35重量％。

    Polysilicate esters for oil reservoir permeability control
    10.
    发明授权
    Polysilicate esters for oil reservoir permeability control 失效
    用于油藏渗透性控制的聚硅酸酯

    公开(公告)号：US4785883A

    公开(公告)日：1988-11-22

    申请号：US940305

    申请日：1986-12-10

    申请人： Dennis H. Hoskin ,  Louis D. Rollmann

    发明人： Dennis H. Hoskin ,  Louis D. Rollmann

    IPC分类号： C09K8/508 ,  C09K8/88 ,  E21B33/138 ,  E21B43/24

    CPC分类号： C09K8/885 ,  C09K8/5086

    摘要： The permeability of subterranean oil-bearing formations is controlled by injection of an organic polysilicate ester. The ester may be derived from simple, monohydroxylic alcohols such as methanol, ethanol, propanol or butanol, from diols such as ethylene glycol, from polyols such as glycerol and alkylene oxide polymerization products and from other organic compounds containing functional hydroxy groups, for example, partial ethers and esters of glycols and polyols. The polysilicates are injected into a formation through injection wells, suitably in an amount from 10 to 100% of the pore volume of the zone to be treated. In the formation, the polysilicate esters form gels which selectively decrease the permeability of the high permeability regions of the formation, to divert the flow of flooding liquid used in flooding operations to the less permeable regions of the formation.

    摘要翻译： 通过注入有机聚硅酸酯酯来控制地下含油地层的渗透性。 酯可以由二醇如乙二醇，多元醇如甘油和烯化氧聚合产物和其它含有官能羟基的有机化合物衍生自简单的单羟基醇如甲醇，乙醇，丙醇或丁醇，例如， 二醇和多元醇的部分醚和酯。 将多硅酸盐通过注入孔注入地层中，适当地为待处理区域的孔体积的10至100％。 在形成中，聚硅酸酯形成凝胶，其选择性地降低地层的高渗透率区域的渗透性，以将在淹没操作中使用的淹没液体的流动转移到地层的较不可渗透的区域。