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    Non-aqueous electrolyte and electrochemical device comprising the same
    2.
    发明授权
    Non-aqueous electrolyte and electrochemical device comprising the same 失效
    非水电解质和包含其的电化学装置

    公开(公告)号：US06911281B2

    公开(公告)日：2005-06-28

    申请号：US09901945

    申请日：2001-07-10

    申请人： Kumiko Sonoda ,  Atsushi Ueda ,  Kazuya Iwamoto

    发明人： Kumiko Sonoda ,  Atsushi Ueda ,  Kazuya Iwamoto

    IPC分类号： C07F5/02 ,  H01G9/02 ,  H01G9/022 ,  H01M10/0568 ,  H01M10/40 ,  H01G9/035 ,  H01G9/038

    CPC分类号： H01G9/022 ,  H01M10/0568 ,  Y02E60/13

    摘要： A non-aqueous electrolyte is disclosed, which comprises a non-aqueous solvent and a solute represented by the general formula(1): MBR1R2R3R4, wherein M is an alkali metal atom or an ammonium group and R1 to R4 are each independently electron withdrawing groups or electron withdrawing atoms bound to B where at least one of R1 to R4 is other than a fluorine atom. The solute has a thermal stability substantially equal to that of LiBF4 and an anion portion having a high electronegativity, and easily dissociates into ions. Therefore, a non-aqueous electrolyte containing this solute has a high ionic conductivity and is difficult to cause a generation of a gas or deterioration in characteristics due to the decomposition of the solute, which occurs during use at high temperatures or after storage at high temperatures.

    摘要翻译： 公开了一种非水电解质，其包含非水溶剂和由通式（1）表示的溶质：MBR 1 R 2 2 R 3 R 4，其中M是碱金属原子或铵基，R 1至R 4各自独立地是吸电子 与B结合的基团或吸电原子，其中R 1至R 4中的至少一个不是氟原子。 溶质的热稳定性基本上等于LiBF 4 S的热稳定性和具有高电负性的阴离子部分，并且容易解离成离子。 因此，含有这种溶质的非水电解质具有高的离子导电性，并且难以引起气体的产生或由于在高温使用期间或在高温下保存后发生的溶质的分解导致的特性劣化 。

    Polymeric solid electrolyte and lithium secondary cell using the same
    3.
    发明授权
    Polymeric solid electrolyte and lithium secondary cell using the same 失效
    聚合物固体电解质和使用其的锂二次电池

    公开(公告)号：US06806004B1

    公开(公告)日：2004-10-19

    申请号：US09807124

    申请日：2001-07-31

    申请人： Kazuya Iwamoto ,  Takafumi Oura ,  Shinji Nakanishi ,  Atsushi Ueda ,  Hizuru Koshina

    发明人： Kazuya Iwamoto ,  Takafumi Oura ,  Shinji Nakanishi ,  Atsushi Ueda ,  Hizuru Koshina

    IPC分类号： H01M1040

    CPC分类号： H01M10/052 ,  C08F230/08 ,  H01B1/122 ,  H01M4/62 ,  H01M4/622 ,  H01M10/0565 ,  H01M2300/0082 ,  Y02T10/7011

    摘要： A polymeric solid electrolyte capable of conducting lithium ions which contains silylamide bonds in its polymer skeleton structure, for example, which is obtained by a method comprising subjecting a mixture of lithium silylamide and an organic compound having at least one carbon—carbon double bond to a polymerization in a dry atmosphere; and a lithium secondary cell using the polymeric solid electrolyte. The polymeric solid electrolyte is a “dry” polymeric solid electrolyte which contains counter ions forming lithium salts with lithium ions in its polymer skeleton structure and thus has a single ion electron conducting system wherein lithium ions alone are mobile ions, and hence has excellent conductivity, and further is easy to produce. The polymeric solid electrolyte can therefore be used for producing a novel lithium secondary cell which is an alternative for conventional lithium cells using an organic solvent and is safe and excellent in the capability of corresponding to a variety of shapes and has a high cell voltage.

    摘要翻译： 能够在其聚合物骨架结构中导电含有甲硅烷基酰胺键的锂离子的聚合物固体电解质，例如通过包括将具有至少一个碳 - 碳双键的锂甲硅烷基酰胺和有机化合物的混合物 在干燥气氛中聚合; 和使用聚合物固体电解质的锂二次电池。 聚合物固体电解质是一种“干”聚合物固体电解质，其包含在其聚合物骨架结构中与锂离子形成锂盐的反离子，因此具有单独的离子电子传导系统，其中单独的锂离子是移动离子，因此具有优异的导电性， 并且进一步易于生产。 因此，聚合物固体电解质可用于制造新的锂二次电池，其是使用有机溶剂的常规锂电池的替代方案，并且对于各种形状的能力安全且优异且具有高的电池电压。

    Secondary battery having a non-aqueous electrolyte
    4.
    发明授权
    Secondary battery having a non-aqueous electrolyte 有权
    具有非水电解质的二次电池

    公开(公告)号：US06682856B1

    公开(公告)日：2004-01-27

    申请号：US09959099

    申请日：2001-10-18

    申请人： Shoichiro Watanabe ,  Kazuya Iwamoto ,  Atsushi Ueda ,  Jun Nunome ,  Hizuru Koshina

    发明人： Shoichiro Watanabe ,  Kazuya Iwamoto ,  Atsushi Ueda ,  Jun Nunome ,  Hizuru Koshina

    IPC分类号： H01M616

    CPC分类号： H01M10/0567 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0525

    摘要： A non-aqueous electrolyte secondary battery which comprises a positive electrode containing a lithium-containing oxide; a negative electrode containing a material capable of absorbing and releasing lithium; and a non-aqueous electrolyte containing a non-aqueous solvent containing at least one non-cyclic ester and which is excellent in storage stability at high temperatures is provided by adding an oxidation resistance improving agent such as triphenylmethane, tetraphehylmethane or the like.

    摘要翻译： 一种非水电解质二次电池，其包含含有含锂氧化物的正极; 含有能够吸收和释放锂的材料的负极; 通过添加抗氧化性改善剂，例如三苯基甲烷，四苯甲烷等，可提供含有含有至少一种非环状酯的非水溶剂且非常高的储存稳定性优异的非水电解质。

    Non-aqueous electrochemical device
    7.
    发明授权
    Non-aqueous electrochemical device 失效
    非水电化学装置

    公开(公告)号：US06630272B1

    公开(公告)日：2003-10-07

    申请号：US09856242

    申请日：2001-05-18

    申请人： Kazuya Iwamoto ,  Takafumi Oura ,  Shinji Nakanishi ,  Atsushi Ueda ,  Hizuru Koshina

    发明人： Kazuya Iwamoto ,  Takafumi Oura ,  Shinji Nakanishi ,  Atsushi Ueda ,  Hizuru Koshina

    IPC分类号： H01M1040

    CPC分类号： H01M10/0567 ,  H01G11/58 ,  H01M6/168 ,  H01M10/052 ,  H01M10/054 ,  Y02E60/13

    摘要： The present invention relates to an electrolyte for non-aqueous electrochemical device containing at least one of 6-substituted-1,3,5-triazine-2,4-dithiol and derivatives thereof as an additive and a non-aqueous electrochemical device, particularly a lithium secondary battery by the use thereof. The additive of the present invention forms a stable and low resistance film on the positive electrode, inhibiting characteristics of the electrochemical device from deteriorating on account of gas generated due to the decomposition of electrolyte.

    摘要翻译： 本发明涉及含有6-取代-1,3,5-三嗪-2,4-二硫醇及其衍生物作为添加剂和非水电化学装置中的至少一种的非水电化学装置的电解质，特别是 锂二次电池。 本发明的添加剂在正极上形成稳定且低电阻的膜，由于电解质分解而产生的气体，电化学装置的特性受到抑制。