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公开(公告)号:US20110162345A1
公开(公告)日:2011-07-07
申请号:US12670871
申请日:2009-02-26
IPC分类号: F01N3/10
CPC分类号: B01D53/8656 , B01D53/501 , B01D53/64 , B01D53/8625 , B01D53/869 , B01D2251/2062 , B01D2251/304 , B01D2251/404 , B01D2255/102 , B01D2255/20707 , B01D2255/20715 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01D2255/2092 , B01D2255/30 , B01D2255/50 , B01D2257/302 , B01D2257/404 , B01D2257/602
摘要: In an exhaust gas treatment, the amount of a highly corrosive mercury-halogenating agent to be added is reduced with the mercury-removing efficiency maintained high.A mercury-halogenating agent (40) and ammonia (30) are added to combustion exhaust gas from a boiler, the exhaust gas containing NOx, SOx and mercury. The exhaust gas is brought into contact with a CO/HC oxidation catalyst (50) and is then subjected to reduction denitration (60) in the presence of a solid catalyst. Thereafter, metallic mercury is oxidized to halogenated mercury. Then, the exhaust gas is wet-desulfurized (100) with the alkaline absorbing solution, and the halogenated mercury is removed.
摘要翻译: 在废气处理中,要加入的高度腐蚀性的汞卤化剂的量随着除汞效率的提高而降低。 向来自锅炉的燃烧废气中加入汞卤化剂(40)和氨(30),该废气含有NOx,SOx和汞。 使废气与CO / HC氧化催化剂(50)接触,然后在固体催化剂存在下进行还原脱硝(60)。 此后,金属汞被氧化成卤化汞。 然后,用碱性吸收溶液对废气进行湿式脱硫(100),除去卤化汞。
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公开(公告)号:US07887768B2
公开(公告)日:2011-02-15
申请号:US12522044
申请日:2007-07-18
CPC分类号: B01D53/64 , B01D53/8625 , B01D53/8665 , B01D2251/206 , B01D2251/2062 , B01D2251/502 , B01D2257/602 , F23J15/003 , F23J15/02 , F23J2215/20 , F23J2215/60 , F23J2219/10 , F23J2219/60 , F23L15/04 , Y02A50/2328 , Y02E20/348
摘要: An air pollution control apparatus according to the present invention reduces nitrogen oxides and oxidizes mercury in flue gas 16 discharged from a boiler by an ammonia denitrating catalyst. The air pollution control apparatus includes an economizer bypassing unit 15a that diverts high-temperature combustion gas 11 to a downstream side while bypassing an economizer 15 provided in a gas flue 10a for combustion gas 11 from the boiler, provided with an ammonium-chloride supply unit 101 that supplies powdery ammonium chloride (NH4Cl) to the economizer bypassing unit 15a. The air pollution control apparatus sublimates the ammonium chloride in an atmosphere at a high temperature of the combustion gas 11, and supplies hydrogen chloride and ammonium into the flue gas flue 102.
摘要翻译: 根据本发明的空气污染控制装置通过氨脱硝催化剂还原氮氧化物并氧化从锅炉排出的废气16中的汞。 空气污染控制装置包括节能器旁通单元15a,其将高温燃烧气体11转移到下游侧,同时旁路设置有来自锅炉的用于燃烧气体11的气体烟道气体10a的节能器15,设置有氯化铵供应单元 101向粉末状氯化铵(NH 4 Cl)供应到节能器旁路单元15a。 空气污染控制装置在燃烧气体11的高温气氛中使氯化铵升华,向烟道气102供给氯化氢和铵。
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公开(公告)号:US08420034B2
公开(公告)日:2013-04-16
申请号:US12670871
申请日:2009-02-26
CPC分类号: B01D53/8656 , B01D53/501 , B01D53/64 , B01D53/8625 , B01D53/869 , B01D2251/2062 , B01D2251/304 , B01D2251/404 , B01D2255/102 , B01D2255/20707 , B01D2255/20715 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01D2255/2092 , B01D2255/30 , B01D2255/50 , B01D2257/302 , B01D2257/404 , B01D2257/602
摘要: In an exhaust gas treatment, the amount of a highly corrosive mercury-halogenating agent to be added is reduced with the mercury-removing efficiency maintained high.A mercury-halogenating agent (40) and ammonia (30) are added to combustion exhaust gas from a boiler, the exhaust gas containing NOx, SOx and mercury. The exhaust gas is brought into contact with a CO/HC oxidation catalyst (50) and is then subjected to reduction denitration (60) in the presence of a solid catalyst. Thereafter, metallic mercury is oxidized to halogenated mercury. Then, the exhaust gas is wet-desulfurized (100) with the alkaline absorbing solution, and the halogenated mercury is removed.
摘要翻译: 在废气处理中,要加入的高度腐蚀性的汞卤化剂的量随着除汞效率的提高而降低。 向来自锅炉的燃烧废气中加入汞卤化剂(40)和氨(30),该废气含有NOx,SOx和汞。 使废气与CO / HC氧化催化剂(50)接触,然后在固体催化剂存在下进行还原脱硝(60)。 此后,金属汞被氧化成卤化汞。 然后,用碱性吸收溶液对废气进行湿式脱硫(100),除去卤化汞。
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公开(公告)号:US07939038B2
公开(公告)日:2011-05-10
申请号:US12602420
申请日:2008-04-30
申请人: Katsumi Nochi , Masashi Kiyosawa , Shintaro Honjo
发明人: Katsumi Nochi , Masashi Kiyosawa , Shintaro Honjo
CPC分类号: B01D53/8625 , B01D53/64 , B01D2251/206 , B01D2251/502 , B01D2257/30 , B01D2257/602 , F23J15/003 , F23J15/02 , F23J2215/10 , F23J2215/60
摘要: An exhaust gas treating apparatus removes nitrogen oxides and mercury in exhaust gas from a boiler using an ammonia denitration catalyst, including: an ammonium chloride powder feed unit for feeding ammonium chloride, in powder form, into a vicinity of an entrance of an economizer provided to a combustion gas flue of the boiler and/or an economizer bypass unit, the fed ammonium chloride in powder form being sublimed by a combustion gas, to thereby feed hydrogen chloride and ammonia into the flue; and an ammonium chloride liquid feed unit for feeding ammonium chloride, in liquid form, into a vicinity of the entrance of the economizer and/or the economizer bypass unit, the ammonium chloride liquid feed unit also being capable of feeding ammonium chloride, vaporization of the fed ammonium chloride in liquid form by the combustion gas also allowing hydrogen chloride and ammonia to be fed into the flue.
摘要翻译: 废气处理装置使用氨脱硝催化剂除去来自锅炉的排气中的氮氧化物和汞,所述氨脱硝催化剂包括:用于将粉末状的氯化铵供给到供给到节能器的入口附近的氯化铵粉末供给单元, 锅炉和/或节能器旁路单元的燃烧气体烟道,粉末形式的进料氯化铵由燃烧气体升华,从而将氯化氢和氨进料到烟道中; 以及用于将液体形式的氯化铵供给到节能器和/或节能器旁路单元的入口附近的氯化铵液体进料单元,氯化铵液体进料单元也能够进料氯化铵,蒸发 通过燃烧气体以液体形式供给氯化铵,还允许将氯化氢和氨进料到烟道中。
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公开(公告)号:US20100183493A1
公开(公告)日:2010-07-22
申请号:US12602420
申请日:2008-04-30
申请人: Katsumi Nochi , Masashi Kiyosawa , Shintaro Honjo
发明人: Katsumi Nochi , Masashi Kiyosawa , Shintaro Honjo
CPC分类号: B01D53/8625 , B01D53/64 , B01D2251/206 , B01D2251/502 , B01D2257/30 , B01D2257/602 , F23J15/003 , F23J15/02 , F23J2215/10 , F23J2215/60
摘要: An exhaust gas treating apparatus removes nitrogen oxides and mercury in an exhaust gas from a boiler by use of an ammonia denitration catalyst, the exhaust gas treating apparatus including: an ammonium chloride powder feed unit 101 for feeding ammonium chloride, in powder form, into any one of or both of a vicinity of an entrance of an economizer 15 provided to a combustion gas flue of the boiler and an economizer bypass unit 15a, the fed ammonium chloride in powder form being sublimed by a combustion gas, to thereby feed hydrogen chloride and ammonia into the flue 102; and an ammonium chloride liquid feed unit 110 for feeding ammonium chloride, in liquid form, into any one of or both of a vicinity of the entrance of the economizer 15 and the economizer bypass unit 15a, the ammonium chloride liquid feed unit 110 also being capable of feeding ammonium chloride, vaporization of the fed ammonium chloride in liquid form by the combustion gas also allowing hydrogen chloride and ammonia to be fed into the flue 102.
摘要翻译: 废气处理装置通过使用氨脱硝催化剂从锅炉除去来自锅炉的废气中的氮氧化物和汞,该废气处理装置包括:将粉末状的氯化铵供给到粉末状的氯化铵粉末供给单元101 提供给锅炉的燃烧气体烟道的节能器15的入口附近的一个或两个以及经济器旁路单元15a,由燃烧气体升华的粉末形式的进料氯化铵,从而进料氯化氢和 氨进入烟道102; 以及用于将液体形式的氯化铵供给到节能器15和节能器旁路单元15a的入口附近的任意一个或两个的氯化铵液体供给单元110,氯化铵液体供给单元110也能够 进料氯化铵,通过燃烧气体将液体形式的进料氯化铵蒸发,同时还允许将氯化氢和氨进料到烟道102中。
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公开(公告)号:US20100074818A1
公开(公告)日:2010-03-25
申请号:US12522044
申请日:2007-07-18
CPC分类号: B01D53/64 , B01D53/8625 , B01D53/8665 , B01D2251/206 , B01D2251/2062 , B01D2251/502 , B01D2257/602 , F23J15/003 , F23J15/02 , F23J2215/20 , F23J2215/60 , F23J2219/10 , F23J2219/60 , F23L15/04 , Y02A50/2328 , Y02E20/348
摘要: An air pollution control apparatus according to the present invention reduces nitrogen oxides and oxidizes mercury in flue gas 16 discharged from a boiler by an ammonia denitrating catalyst. The air pollution control apparatus includes an economizer bypassing unit 15a that diverts high-temperature combustion gas 11 to a downstream side while bypassing an economizer 15 provided in a gas flue 10a for combustion gas 11 from the boiler, provided with an ammonium-chloride supply unit 101 that supplies powdery ammonium chloride (NH4Cl) to the economizer bypassing unit 15a. The air pollution control apparatus sublimates the ammonium chloride in an atmosphere at a high temperature of the combustion gas 11, and supplies hydrogen chloride and ammonium into the flue gas flue 102.
摘要翻译: 根据本发明的空气污染控制装置通过氨脱硝催化剂还原氮氧化物并氧化从锅炉排出的废气16中的汞。 空气污染控制装置包括节能器旁通单元15a,其将高温燃烧气体11转移到下游侧,同时旁路设置有来自锅炉的用于燃烧气体11的气体烟道气体10a的节能器15,设置有氯化铵供应单元 101向粉末状氯化铵(NH 4 Cl)供应到节能器旁路单元15a。 空气污染控制装置在燃烧气体11的高温气氛中使氯化铵升华,向烟道气102供给氯化氢和铵。
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公开(公告)号:US20110135541A1
公开(公告)日:2011-06-09
申请号:US13058736
申请日:2009-08-04
申请人: Nobuyasu Sakata , Rikuma Shijo , Toshihiro Sato , Moritoshi Murakami , Nobuyuki Ukai , Katsumi Nochi , Masashi Kiyosawa
发明人: Nobuyasu Sakata , Rikuma Shijo , Toshihiro Sato , Moritoshi Murakami , Nobuyuki Ukai , Katsumi Nochi , Masashi Kiyosawa
IPC分类号: B01D53/56
CPC分类号: B01D53/64 , B01D53/501 , B01D53/56 , B01D53/8631 , B01D2251/108 , B01D2251/2062 , B01D2255/102 , B01D2255/20723 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20769 , B01D2255/20776 , B01D2257/302 , B01D2257/404 , B01D2257/602 , F23J2215/60
摘要: An air pollution control apparatus includes at least one denitration catalyst layer for reducing the amounts of nitrogen oxides in flue gas from a boiler and oxidizing mercury with hydrogen chloride sprayed into the flue gas. Spraying pipe headers 51 are disposed in a flue gas duct 19. The spraying pipe headers 51 are inserted into the flue gas duct 19 and arranged in a direction orthogonal to the direction of a gas flow in the flue gas duct 19. At least four spray nozzles 52-1 to 52-4 are disposed on the spraying pipe header 51 to form a vertical vortex flow 53 in the gas flow direction. The diffusion of hydrogen chloride is thereby facilitated in a rapid manner. Therefore, the number of the nozzles can be reduced, and the uniformity of the concentration of hydrogen chloride at the location of the catalyst can be ensured even when the spacing between the nozzles is increased.
摘要翻译: 空气污染控制装置包括至少一个用于减少来自锅炉的烟道气中的氮氧化物的数量的脱硝催化剂层,并且用喷射到烟道气中的氯化氢氧化汞。 喷管套管51设置在烟气管道19中。喷管集管51插入烟气管道19中,沿与烟气管道19中气流方向正交的方向排列。至少四喷 喷嘴52-1至52-4设置在喷射管集管51上,以沿气体流动方向形成垂直涡流53。 从而有利于快速的氯化氢扩散。 因此,可以减少喷嘴的数量,并且即使当喷嘴之间的间隔增加时也可以确保催化剂位置处的氯化氢浓度的均匀性。
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公开(公告)号:US20110123403A1
公开(公告)日:2011-05-26
申请号:US13056419
申请日:2009-07-23
申请人: Toshihiro Sato , Nobuyasu Sakata , Rikuma Shijo , Moritoshi Murakami , Nobuyuki Ukai , Katsumi Nochi , Masashi Kiyosawa
发明人: Toshihiro Sato , Nobuyasu Sakata , Rikuma Shijo , Moritoshi Murakami , Nobuyuki Ukai , Katsumi Nochi , Masashi Kiyosawa
IPC分类号: B01D53/00
CPC分类号: F23J15/006 , B01D53/64 , B01D53/8631 , B01D2251/502 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/1026 , B01D2255/1028 , B01D2255/20707 , B01D2255/20715 , B01D2255/20723 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2255/20769 , B01D2255/20776 , B01D2255/30 , B01D2257/404 , B01D2257/602 , F23J15/003 , F23J2215/10 , F23J2215/60 , F23J2219/10 , F23J2219/20 , F23M9/003 , Y02C20/10
摘要: An air pollution control apparatus 10 according to an embodiment of the present invention has a denitration catalyst layer 13 that removes nitrogen oxides in flue gas, and atomizes hydrochloric acid into flue gas to oxidize mercury, and also includes a swirling-flow generating member 15A including a vertical axis 22 provided in a passage 14 of a honeycomb catalyst, and four swirling-flow generating vanes 23 provided radially with respect to the vertical axis 22 for generating a turbulent flow in flue gas, with the swirling-flow generating vanes 23 being arranged in a direction of the vertical axis 22 with a predetermined gap therebetween. With this configuration, by generating a swirling flow in flue gas in the passage 14 in the denitration catalyst layer 13, a contact time between flue gas and a denitration catalyst can be increased, and the oxidation reaction efficiency between mercury in flue gas and the denitration catalyst can be improved.
摘要翻译: 根据本发明的实施方式的空气污染控制装置10具有去除烟道气中的氮氧化物的脱硝催化剂层13,并且将盐酸雾化成烟道气以氧化汞,并且还包括旋流产生件15A,其包括 设置在蜂窝催化剂的通道14中的纵轴22和相对于垂直轴线22径向设置的四个旋流产生叶片23,用于在烟道气中产生湍流,其中旋流产生叶片23布置 在垂直轴线22的方向上具有预定的间隙。 由此,通过在脱硝催化剂层13的通路14中的烟道气中产生回旋流,可以提高烟气与脱硝催化剂的接触时间,并且烟道气中的汞与脱硝之间的氧化反应效率 可以改善催化剂。
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公开(公告)号:US20110116981A1
公开(公告)日:2011-05-19
申请号:US13003956
申请日:2009-07-23
申请人: Toshihiro Sato , Nobuyasu Sakata , Rikuma Shijo , Moritoshi Murakami , Nobuyuki Ukai , Katsumi Nochi , Masashi Kiyosawa
发明人: Toshihiro Sato , Nobuyasu Sakata , Rikuma Shijo , Moritoshi Murakami , Nobuyuki Ukai , Katsumi Nochi , Masashi Kiyosawa
CPC分类号: B01D53/64 , B01D53/8631 , B01D2251/108 , B01D2255/102 , B01D2255/20723 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20769 , B01D2255/20776 , B01D2257/302 , B01D2257/602 , F23J15/003 , F23J2215/10 , F23J2215/60 , F23J2219/10 , F23M9/003
摘要: An air pollution control apparatus 10 according to an embodiment of the present invention has a denitration catalyst layer 13 that removes NOx in flue gas 12, and atomizes HCl into the flue gas 12 to oxidize Hg, and also includes a swirling-flow generating member 30A that includes a swirling-flow generating-member body being partitioned to correspond to each passage of the denitration catalyst layer 13 and a plurality of swirling-flow generating vanes arranged on the partition inner walls to generate a turbulent flow, on an inlet 13a side of the denitration catalyst layer 13. With this configuration, a laminar flow of the flue gas 12 in a flue gas duct 19 is changed to a swirling flow, thereby enabling to increase a contact time between the flue gas 12 and a denitration catalyst and to improve the oxidation reaction efficiency between Hg in the flue gas 12 and the denitration catalyst.
摘要翻译: 根据本发明的一个实施方案的空气污染控制装置10具有去除烟道气12中的NOx的脱硝催化剂层13,并将HCl雾化到烟道气12中以氧化Hg,并且还包括旋流产生件30A 其包括涡流发生构件体,其被分隔成对应于脱硝催化剂层13的每个通道以及布置在隔壁内壁上的多个涡流生成叶片以产生湍流,在涡流产生构件主体的入口13a侧 脱硝催化剂层13.利用这种构造,将烟道管道19中的烟道气12的层流改变为旋流,从而能够增加烟道气12与脱硝催化剂之间的接触时间并提高 烟气12中的Hg与脱硝催化剂之间的氧化反应效率。
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公开(公告)号:US07256155B2
公开(公告)日:2007-08-14
申请号:US10705365
申请日:2003-11-10
CPC分类号: B01D53/8631 , B01D53/8628 , B01J23/002 , B01J23/30 , B01J35/04 , B01J37/0238
摘要: Provided are a flue gas denitration catalyst having high denitration activity and capable of suppressing a side reaction, that is, oxidation of SO2; and a preparation process of the catalyst. The flue gas denitration catalyst comprises TiO2, WO3 and V2O5. In the surface layer of the catalyst within 200 μm from the surface thereof, V2O5 is supported on a carrier containing TiO2 and WO3. The supported amounts of V2O5 range from 0.4 to 5 wt. % based on the weight of the surface layer and range from 0.1 to 0.9 wt. % based on the total weight of the catalyst. The V2O5 thus supported has a crystallite size of less than 10 nm as measured by X-ray diffraction. The catalyst can be available by preparing a mixture containing TiO2 and WO3 and having V2O5 supported on the surface of an extruded product of the prepared mixture by a vapor phase method. The catalyst can be also available by having V2O5 supported on a powder of the prepared mixture by a vapor phase method and having the resulting powder supported on the surface of a formed product.
摘要翻译: 提供了具有高脱硝活性并能够抑制副反应,即SO 2氧化的烟道气脱硝催化剂。 和催化剂的制备方法。 烟道气脱硝催化剂包括TiO 2,WO 3和V 2 O 5。 在催化剂的表面200μm以内的表面层中,V 2 O 2 O 5负载在含有TiO 2和WO 2的载体上 3 SUB>。 V 2 O 5的支持量为0.4-5重量%。 %,基于表层的重量,为0.1-0.9wt。 %,基于催化剂的总重量。 如此支撑的V 2 O 5 5具有通过X射线衍射测量的小于10nm的微晶尺寸。 催化剂可以通过制备含有TiO 2和WO 3的混合物并具有V 2 O 5 O 5 在制备的混合物的挤出产物的表面上通过气相法。 催化剂也可以通过使V 2 O 2 O 5通过气相法负载在所制备的混合物的粉末上,并将所得粉末负载在表面上 成型产品。
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