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    Digital imaging with high chloride emulsions
    1.
    发明授权
    Digital imaging with high chloride emulsions 失效
    数字成像与高氯化物乳剂

    公开(公告)号：US5783373A

    公开(公告)日：1998-07-21

    申请号：US740535

    申请日：1996-10-30

    Applicant: Jerzy Z. Mydlarz ,  Jerzy A. Budz ,  Eric L. Bell

    Inventor： Jerzy Z. Mydlarz ,  Jerzy A. Budz ,  Eric L. Bell

    IPC: G03C1/005 ,  G03C1/035 ,  G03C1/047 ,  G03C1/08 ,  G03C1/09 ,  G03C7/30

    CPC classification number: G03C1/035 ,  G03C1/0053 ,  G03C1/08 ,  G03C1/09 ,  G03C7/3022 ,  G03C1/047 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/03541 ,  G03C2001/0845 ,  G03C2001/0854 ,  G03C2001/093 ,  G03C2001/094 ,  G03C2200/01 ,  G03C2200/39 ,  G03C2200/42 ,  G03C5/164

    Abstract: An electronic printing method is disclosed which comprises subjecting a radiation sensitive silver halide emulsion layer of a recording element to actinic radiation of at least 10.sup.-4 ergs/cm.sup.2 for up to 100.mu. seconds duration in a pixel-by-pixel mode. The silver halide emulsion layer is comprised of grains predominantly bounded by {100} crystal faces and internally containing three dopants each selected to satisfy a different one of the following class requirements: (i) a metal coordination complex containing a nitrosyl or thionitrosyl ligand in combination with a transition metal chosen from groups 5 to 10 inclusive of the periodic table of elements, (ii) a shallow electron trapping dopant, and (iii) a iridium coordination complex having ligands each of which are more electropositive than a cyano ligand. A gelatino-peptizer for the grains is employed that contains less than 30 micromoles of methionine per gram. The dopants and peptizer in combination increase contrast and provide a highly unexpected increase in high density contrast.

    Abstract translation: 公开了一种电子印刷方法，其包括以逐像素模式对记录元件的辐射敏感卤化银乳剂层进行至少10-4erg / cm2的光化辐射长达100μs的持续时间。 卤化银乳剂层由主要由{100}晶面限定的晶粒组成，内部含有三种掺杂剂，每种掺杂剂选择满足以下类别要求中的不同之一：（i）含有亚硝酰基或亚硫酰基配位体的金属配位络合物 具有选自元素周期表第5至10族的过渡金属，（ii）浅电子俘获掺杂剂，和（iii）具有比氰基配体更具有正电性的配体的铱配位络合物。 使用含有每克少于30微摩尔甲硫氨酸的晶粒的明胶胶溶剂。 掺杂剂和胶溶剂组合增加了对比度，并提供了高度意想不到的高密度对比度的增加。

    High chloride emulsions with optimized digital reciprocity characteristics
    2.
    发明授权
    High chloride emulsions with optimized digital reciprocity characteristics 失效
    具有优化数字互惠特性的高氯化物乳液

    公开(公告)号：US06733961B1

    公开(公告)日：2004-05-11

    申请号：US10328493

    申请日：2002-12-23

    Applicant: Jerzy A. Budz ,  Eric L. Bell ,  Jess B. Hendricks, III ,  Jerzy Z. Mydlarz

    Inventor： Jerzy A. Budz ,  Eric L. Bell ,  Jess B. Hendricks, III ,  Jerzy Z. Mydlarz

    IPC: G03C109

    CPC classification number: G03C1/035 ,  G03C1/09 ,  G03C5/04 ,  G03C2001/03517 ,  G03C2001/03535 ,  G03C2001/03541 ,  G03C2001/093 ,  G03C2200/39

    Abstract: A method for forming a radiation-sensitive high chloride silver halide emulsion is described comprising growing cubical silver halide grains having a central portion accounting for up to 98 percent of total silver of the grains which central portion contains an iridium coordination complex dopant, and chemically sensitizing the surface of the emulsion grains at a pH of at least 5.75. Localized addition of the known in the art reciprocity-controlling iridium dopants to an internal portion of the emulsion grains and chemical finishing of such an emulsion at elevated pH conditions improves reciprocity and latent image stability of the formed high chloride emulsions.

    Abstract translation: 描述了形成辐射敏感性高氯化卤化银乳剂的方法，其包括生长立方卤化银颗粒，其中心部分占中心部分含有铱配位络合物掺杂剂的颗粒的总银的98％，并且化学增感 乳液颗粒的表面在至少5.75的pH下。 将本领域已知的互易控制铱掺杂剂局部添加到乳液颗粒的内部，并且在升高的pH条件下对这种乳液进行化学处理改善了形成的高氯化物乳液的互易性和潜像稳定性。

    High chloride emulsion that contains a dopant and peptizer combination that increases high density contrast
    4.
    发明授权
    High chloride emulsion that contains a dopant and peptizer combination that increases high density contrast 失效
    含有掺杂剂和胶溶剂组合的高氯化物乳液，增加了高密度的对比度

    公开(公告)号：US5783378A

    公开(公告)日：1998-07-21

    申请号：US739980

    申请日：1996-10-30

    Applicant: Jerzy Z. Mydlarz ,  Jerzy A. Budz ,  Eric L. Bell

    Inventor： Jerzy Z. Mydlarz ,  Jerzy A. Budz ,  Eric L. Bell

    IPC: G03C1/035 ,  G03C1/047 ,  G03C1/08 ,  G03C1/09 ,  G03C1/35

    CPC classification number: G03C1/08 ,  G03C1/035 ,  G03C1/047

    Abstract: A radiation-sensitive high chloride emulsion is disclosed comprised of grains predominantly bounded by {100} crystal faces and internally containing three dopants each selected to satisfy a different one of the following class requirements: (i) a metal coordination complex containing a nitrosyl or thionitrosyl ligand in combination with a transition metal chosen from groups 5 to 10 inclusive of the periodic table of elements, (ii) a shallow electron trapping dopant, and (iii) an iridium coordination complex having ligands each of which are more electropositive than a cyano ligand. A gelatino-peptizer for the grains is employed that contains less than 30 micromoles of methionine per gram. The dopants and peptizer in combination increase contrast and provide a highly unexpected increase in high density contrast.

    Abstract translation: 公开了一种辐射敏感的高氯化物乳液，其包含主要由{100}晶面限定的晶粒，并且内部含有三种掺杂剂，每种掺杂剂选择为满足以下类别要求中的不同之一：（i）含有亚硝酰基或亚硫酰基 配体与选自元素周期表第5至10组的过渡金属组合，（ii）浅电子捕获掺杂剂，和（iii）铱配位络合物，其配体各自比氰基配体更具有正电性 。 使用含有每克少于30微摩尔甲硫氨酸的晶粒的明胶胶溶剂。 掺杂剂和胶溶剂组合增加了对比度，并提供了高度意想不到的高密度对比度的增加。

    High chloride emulsions doped with combination of metal complexes
    6.
    发明授权
    High chloride emulsions doped with combination of metal complexes 有权
    掺有金属络合物的高氯化物乳剂

    公开(公告)号：US6107018A

    公开(公告)日：2000-08-22

    申请号：US250200

    申请日：1999-02-16

    Applicant: Jerzy Z. Mydlarz ,  Eric L. Bell ,  Michael S. Graham

    Inventor： Jerzy Z. Mydlarz ,  Eric L. Bell ,  Michael S. Graham

    IPC: G03C5/08 ,  G03C1/00 ,  G03C1/035 ,  G03C1/07 ,  G03C1/09 ,  G03C1/047

    CPC classification number: G03C1/09 ,  G03C1/035 ,  G03C1/07 ,  Y10S430/145 ,  Y10S430/146

    Abstract: A radiation-sensitive emulsion is disclosed comprised of silver halide grains (a) containing greater than 50 mole percent chloride, based on silver, (b) having greater than 50 percent of their surface area provided by {100} crystal faces, and (c) having a central portion accounting for from 95 to 99 percent of total silver and containing two dopants selected to satisfy each of the following class requirements: (i) a hexacoordination metal complex which satisfies the formula (I)[ML.sub.6 ].sup.nwherein n is zero, -1, -2, -3 or -4; M is a filled frontier orbital polyvalent metal ion, other than iridium; and L.sub.6 represents bridging ligands which can be independently selected, provided that least four of the ligands are anionic ligands, and at least one of the ligands is a cyano ligand or a ligand more electronegative than a cyano ligand; and (ii) an iridium coordination complex containing a thiazole or substituted thiazole ligand. A photographic recording element comprising a support and at least one light sensitive silver halide emulsion layer comprising silver halide grains as described above is also disclosed, as well as an electronic printing method which comprises subjecting a radiation sensitive silver halide emulsion layer of a recording element to actinic radiation of at least 10.sup.-4 ergs/cm.sup.2 for up to 100.mu. seconds duration in a pixel-by-pixel mode, wherein the silver halide emulsion layer is comprised of silver halide grains as described above.

    Abstract translation: 公开了一种辐射敏感乳液，其包含基于银的大于50摩尔百分比的氯化银（a）的卤化银颗粒（a），（b）其具有由{100}晶面提供的其表面积的50％以上，（c ），其中心部分占总银的95％至99％，并且含有两种掺杂剂，其选择为满足以下各项要求：（i）满足式（I）[ML6] n的六配位金属络合物，其中n为零 ，-1，-2，-3或-4; M是除铱之外的填充边界轨道多价金属离子; 并且L6表示可以独立选择的桥连配体，条件是至少四种配体是阴离子配体，并且至少一种配体是氰基配体或比氰基配体更具有负电性的配体; 和（ii）含有噻唑或取代的噻唑配体的铱配位络合物。 还公开了一种包含载体和包含如上所述的包含卤化银颗粒的至少一种感光卤化银乳剂层的照相记录元件，以及电子印刷方法，其包括将记录元件的辐射敏感卤化银乳剂层 以像素为单位的模式，至少10-4erg / cm2的光化辐射长达100μs的持续时间，其中卤化银乳剂层由如上所述的卤化银颗粒组成。

    High intensity exposure photographic imaging method employing iridium doped high chloride emulsion
    10.
    发明授权
    High intensity exposure photographic imaging method employing iridium doped high chloride emulsion 失效
    使用铱掺杂高氯化物乳液的高强度曝光照相成像方法

    公开(公告)号：US06518009B1

    公开(公告)日：2003-02-11

    申请号：US09608841

    申请日：2000-06-30

    Applicant: Jerzy Z. Mydlarz ,  Roger L. Klaus

    Inventor： Jerzy Z. Mydlarz ,  Roger L. Klaus

    IPC: G03C1005

    CPC classification number: G03C1/015 ,  G03C1/035 ,  G03C5/16 ,  G03C2001/03517 ,  G03C2001/03541 ,  Y10S430/145 ,  Y10S430/146

    Abstract: A method of imaging employing sensitized high chloride silver halide emulsions which exhibit improved speed and high intensity reciprocity performance for use with short duration, high intensity exposure optical and digital exposure systems. The method comprising providing a photographic element comprising at least one high chloride silver halide emulsion layer, exposing said element utilizing a high intensity actinic radiation exposure for an exposure time of less than {fraction (1/100)} second, and developing said element to produce a photographic image, wherein the high chloride silver halide emulsion layer is comprised of silver halide emulsion grains containing at least 90 mole percent chloride, based on silver, obtained by providing a high chloride host emulsion, bringing a Lippmann emulsion comprising primarily fine silver bromide grains doped with iridium into contact with said high chloride host emulsion, and subsequently chemically sensitizing the high chloride emulsion.

    Abstract translation: 使用敏化的高氯化物卤化银乳剂的成像方法，其表现出改善的速度和高强度互易性能，用于短时间，高强度曝光光学和数字曝光系统。 该方法包括提供包含至少一种高氯化物卤化银乳剂层的照相元件，利用高强度光化辐射曝光暴露所述元件，曝光时间小于1/100秒，并显影所述元件以产生照相图像， 其中所述高氯化物卤化银乳剂层由卤化银乳剂颗粒组成，所述卤化银乳剂颗粒含有基于银的至少90摩尔百分数的氯化物，通过提供高氯化物主体乳液获得，使包含主要细小的掺有铱的溴化银颗粒的Lippmann乳液进入 与所述高氯化物主体乳液接触，随后对高氯化物乳液进行化学增感。

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