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    Metallocene compositions
    1.
    发明授权
    Metallocene compositions 有权

    公开(公告)号：US06376410B1

    公开(公告)日：2002-04-23

    申请号：US09620175

    申请日：2000-07-19

    Applicant: Terry J. Burkhardt ,  Udo M. Stehling ,  James R. Hart ,  William T. Haygood, Jr. ,  Robert T. Li ,  James C. Vizzini ,  Matthew C. Kuchta

    Inventor： Terry J. Burkhardt ,  Udo M. Stehling ,  James R. Hart ,  William T. Haygood, Jr. ,  Robert T. Li ,  James C. Vizzini ,  Matthew C. Kuchta

    IPC: B01J3700

    CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/21

    Abstract: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; R13 is —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15 and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.

    Supported ionic catalyst compositions
    2.
    发明授权
    Supported ionic catalyst compositions 有权

    公开(公告)号：US6143686A

    公开(公告)日：2000-11-07

    申请号：US184389

    申请日：1998-11-02

    Applicant: James C. Vizzini ,  Rajan K. Chudgar

    Inventor： James C. Vizzini ,  Rajan K. Chudgar

    IPC: B01J31/00 ,  C08F4/02 ,  C08F4/06 ,  C08F4/44 ,  C08F4/62 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/06

    CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/65908 ,  C08F4/65927

    Abstract: This invention relates to supported metallocene catalyst compositions useful for addition reactions of prochiral .alpha.-olefins. Polymers, specifically propylene polymers, produced with this catalyst possess higher stereoregularities and consequently higher melting points compared to propylene polymers produced using previously known supported metallocene catalysts. The microstructure of the polymers obtained using the supported catalyst systems of this invention is similar to that obtained using analogous unsupported catalysts. The catalyst compositions comprise transition metal (i.e., metallocene) cations and beam comprising anionic activators in prescribed ratios on metal or metalloid oxide supports. The transition metal compound is represented by the formula: ##STR1## wherein M is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten;R.sup.1 and R.sup.2 are identical or different, and are one of a hydrogen atom, a C.sub.1 -C.sub.10 alkyl group, a C.sub.1 -C.sub.10 alkoxy group, a C.sub.6 -C.sub.10 aryl group, a C.sub.6 -C.sub.10 aryloxy group, a C.sub.2 -C.sub.10 alkenyl group, a C.sub.2 -C.sub.4 alkenyl group, a C.sub.7 -C.sub.40 arylalkyl group, a C.sub.7 -C.sub.40 alkylaryl group, a C.sub.8 -C.sub.40 arylalkenyl group, or a halogen atom;R.sup.5 and R.sup.6 are identical or different, and are one of a halogen atom, a C.sub.1 -C.sub.10 alkyl group which may be halogenated, a C.sub.6 -C.sub.10 aryl group which may be halogenated, a C.sub.2 -C.sub.10 alkenyl group, a C.sub.7 -C.sub.40 -arylalkyl group, a C.sub.7 -C.sub.40 alkylaryl group, a C.sub.8 -C.sub.40 arylalkenyl group, a --NR.sub.2.sup.15, --SR.sup.15, --OR.sup.15, --OSiR.sub.3.sup.15 or --PR.sub.2.sup.15 radical, wherein R.sup.15 is one of a halogen atom, a C.sub.1 --C.sub.10 alkyl group, or a C.sub.6 -C.sub.10 aryl group;R.sup.7 is ##STR2## --B(R.sup.11)--, --Al(R.sup.11)--, --Ge--, --Sn, --O--, --S--, --SO--, --SO.sub.2 --, --N(R.sup.11)--, --CO--, --P(R.sub.11)--, or --P(O)(R.sup.11)--;wherein:R.sup.11, R.sup.12 and R.sup.13 are identical or different and are a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.20 alkyl group, a C.sub.1 -C.sub.20 fluoroalkyl group, a C.sub.6 -C.sub.30 aryl group, a C.sub.6 -C.sub.30 fluoroaryl group, a C.sub.1 -C.sub.20 alkoxy group, a C.sub.2 -C.sub.20 alkenyl group, a C.sub.7 -C.sub.40 arylalkyl group, a C.sub.8 -C.sub.40 arylalkenyl group, a C.sub.7 -C.sub.40 alkylaryl group, or R.sup.11 and R.sup.12, or R.sup.11 and R.sup.13, together with the atoms binding them, can form ring systems;M.sup.2 is silicon, germanium or tin;R.sup.8 and R.sup.9 are identical or different and have the meanings stated for R.sup.11 ;m and n are identical or different and are zero, 1 or 2, m plus n being zero, 1 or 2; andthe radicals R.sup.3, R.sup.4 and R.sup.10 are identical or different and have the meanings stated for R.sup.11, R.sup.12 and R.sup.13 and two adjacent R.sup.10 radicals can be joined together to form a ring system.

    Metallocene compositions
    6.
    发明授权
    Metallocene compositions 有权

    公开(公告)号：US06376627B1

    公开(公告)日：2002-04-23

    申请号：US09619748

    申请日：2000-07-19

    Applicant: Terry J. Burkhardt ,  Udo M. Stehling ,  James R. Hart ,  William T. Haygood, Jr. ,  Robert T. Li ,  James C. Vizzini ,  Matthew C. Kuchta

    Inventor： Terry J. Burkhardt ,  Udo M. Stehling ,  James R. Hart ,  William T. Haygood, Jr. ,  Robert T. Li ,  James C. Vizzini ,  Matthew C. Kuchta

    IPC: B01J3100

    CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/21

    Abstract: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; R13 is  —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15 and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.

    Metallocene compositions
    7.
    发明授权
    Metallocene compositions 有权

    公开(公告)号：US06376408B1

    公开(公告)日：2002-04-23

    申请号：US09619759

    申请日：2000-07-19

    Applicant: Terry J. Burkhardt ,  Udo M. Stehling ,  James R. Hart ,  William T. Haygood, Jr. ,  Robert T. Li ,  James C. Vizzini ,  Matthew C. Kuchta

    Inventor： Terry J. Burkhardt ,  Udo M. Stehling ,  James R. Hart ,  William T. Haygood, Jr. ,  Robert T. Li ,  James C. Vizzini ,  Matthew C. Kuchta

    IPC: B01J3100

    CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/21

    Abstract: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; R13 is  —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical;  wherein: R14, R15and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.

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