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    Durable flame retardant for polyester textile materials
    1.
    发明授权
    Durable flame retardant for polyester textile materials 失效
    耐用的阻燃聚酯纺织材料

    公开(公告)号：US4160795A

    公开(公告)日：1979-07-10

    申请号：US869084

    申请日：1978-01-13

    申请人： James A. Albright ,  Richard R. Nicholson

    发明人： James A. Albright ,  Richard R. Nicholson

    IPC分类号： C08K5/00 ,  C07F9/6571 ,  C07F9/6574 ,  C08K5/52 ,  C08K5/527 ,  C08K5/5398 ,  C08L67/00 ,  D01F1/07 ,  D06M13/02 ,  D06M13/244 ,  D06M13/282 ,  D06M13/288 ,  D06M13/29 ,  D06M13/292 ,  D06M13/298 ,  C07F9/165 ,  C07F9/08

    CPC分类号： C08K5/5398 ,  C07F9/657118 ,  C07F9/657136 ,  C07F9/65742 ,  C07F9/65746 ,  C08K5/527

    摘要： Disclosed are novel compounds of the formula: ##STR1## WHEREIN EACH Z is independently selected from the group consisting of hydrogen and halogen; Y is oxygen or sulfur; n is an integer of from 1 to 3; a, b, and c are integers of from 0 to 1; n+a+b+c=4; and wherein X, X', X" are independently selected from the group consisting of hydrogen, halogen, alkyl of 1 to about 8 carbon atoms and --OC(O)R, provided that at least one of said X, X', X" substituents is --OC(O)R, and R is independently selected from the group consisting of alkyl of 1 to about 18 carbon atoms, haloalkyl of 1 to about 18 carbon atoms, alkoxyalkyl of from 1 to about 18 carbon atoms, aryl of from 6 to about 18 carbon atoms, and haloaryl of from about 6 to about 18 carbon atoms.The above compounds may be topically applied to polyester-containing textile materials in order to flame retard them; and the materials so treated have a durable flame retardance.

    摘要翻译： 公开了下式的新化合物：每个Z独立地选自氢和卤素; Y是氧或硫; n为1〜3的整数， a，b和c为0〜1的整数; n + a + b + c = 4; 并且其中X，X'，X“独立地选自氢，卤素，1至约8个碳原子的烷基和-OC（O）R，条件是所述X，X'， X“取代基是-OC（O）R，R独立地选自1至约18个碳原子的烷基，1至约18个碳原子的卤代烷基，1至约18个碳原子的烷氧基烷基， 6至约18个碳原子的芳基和约6至约18个碳原子的卤代芳基。

    Haloaryl halobenzenesulfonate flame retardants
    2.
    发明授权
    Haloaryl halobenzenesulfonate flame retardants 失效
    卤代芳基卤苯磺酸盐阻燃剂

    公开(公告)号：US4178330A

    公开(公告)日：1979-12-11

    申请号：US828581

    申请日：1977-08-29

    申请人： James A. Albright

    发明人： James A. Albright

    IPC分类号： C08L23/00 ,  C07C67/00 ,  C07C301/00 ,  C07C309/73 ,  C08J9/00 ,  C08K5/00 ,  C08K5/41 ,  C08K5/42 ,  C08L7/00 ,  C08L21/00 ,  C08L33/00 ,  C08L33/18 ,  C08L51/00 ,  C08L51/02 ,  C08L101/00

    CPC分类号： C08K5/42 ,  C07C309/73 ,  C08J9/0033

    摘要： Disclosed are haloaryl halobenzene sulfonates of the formula ##STR1## wherein X and X' are each independently selected halogen, preferably chlorine or bromine; n is a integer of from 1 to 5 and m is an integer from 1 to 4, provided that the sum of n plus m is an integer of from 4 to 9; and R is selected from hydrogen, halogen (preferably chlorine and bromine), and ##STR2## wherein Y and Y' are each independently selected halogen, preferably chlorine and bromine, m' is an integer from 1 to 4 and n' is an integer of from 1 to 5, provided that m'+n' is from 4 to 9 and Z is an alkylene or alkylidene containing from 1 to 6 carbon atoms. Also disclosed are polymeric compositions containing these compounds as flame retardants.

    摘要翻译： 公开了式I的卤代芳基卤代苯磺酸盐，其中X和X'各自独立地选自卤素，优选氯或溴; n为1〜5的整数，m为1〜4的整数，n + m的总和为4〜9的整数。 并且R选自氢，卤素（优选氯和溴），和其中Y和Y'各自独立地选自卤素，优选氯和溴，m'是1至4的整数，n'是 如果m'+ n'为4〜9，Z为含有1〜6个碳原子的亚烷基或亚烷基，则为1〜5的整数。 还公开了含有这些化合物作为阻燃剂的聚合物组合物。

    Polymeric compositions containing a flame retardant amount of a bis(2,3-dibromopropyl)-chloroalkyl phosphate
    3.
    发明授权
    Polymeric compositions containing a flame retardant amount of a bis(2,3-dibromopropyl)-chloroalkyl phosphate 失效
    含有阻燃剂量的双（2,3-二溴丙基） - 氯代烷基磷酸酯的聚合物组合物

    公开(公告)号：US4083826A

    公开(公告)日：1978-04-11

    申请号：US683356

    申请日：1976-05-05

    申请人： James A. Albright

    发明人： James A. Albright

    IPC分类号： C08K5/521 ,  C08K5/53 ,  C07F9/09

    CPC分类号： C08K5/521

    摘要： A compound of the formula ##STR1## WHEREIN R is a straight or branched chain alkyl group containing from about 2 to about 12 carbon atoms and polymeric compositions comprising a polyurethane, polyester, cellulosic-polyester blend or styrenated polyester polymer and a flame retarding amount of the described compound.

    摘要翻译： 下式的化合物，其中R是含有约2至约12个碳原子的直链或支链烷基，和包含聚氨酯，聚酯，纤维素 - 聚酯共混物或苯乙烯化聚酯聚合物的聚合物组合物和阻燃量 所述化合物。

    Reactive phosphate flame retardants
    5.
    发明授权
    Reactive phosphate flame retardants 失效
    反应性磷酸盐阻燃剂

    公开(公告)号：US4281097A

    公开(公告)日：1981-07-28

    申请号：US142936

    申请日：1980-04-23

    申请人： James A. Albright

    发明人： James A. Albright

    IPC分类号： C07F9/09 ,  C08G18/38 ,  C08K5/521 ,  C08G18/30 ,  C08G63/20

    CPC分类号： C07F9/091 ,  C07F9/093 ,  C08G18/3885 ,  C08K5/52 ,  C08K5/521

    摘要： Novel esters of pentavalent phosphorus acid having the formula ##STR1## wherein R and R'are haloalkyl containing from 2 to 6 carbon atoms and from 1 to 6 halogen atoms; n is an integer of from 1 to 3; each X is independently selected from hydrogen, halogen, alkyl, or hydroxyl, provided that at least one X is hydroxyl. The above compounds are effective reactive flame retardants in polyurethane and polyester polymeric compositions.

    摘要翻译： 具有式“IMAGE”的五价磷酸的新型酯，其中R和R'为含2至6个碳原子和1至6个卤原子的卤代烷基; n为1〜3的整数， 每个X独立地选自氢，卤素，烷基或羟基，条件是至少一个X是羟基。 上述化合物是聚氨酯和聚酯聚合物组合物中有效的反应性阻燃剂。

    Durable flame retardant finishes for textile materials
    10.
    发明授权
    Durable flame retardant finishes for textile materials 失效
    耐用的阻燃涂料用于纺织材料

    公开(公告)号：US4104172A

    公开(公告)日：1978-08-01

    申请号：US660500

    申请日：1976-02-23

    申请人： Ray E. Smith ,  James A. Albright

    发明人： Ray E. Smith ,  James A. Albright

    IPC分类号： D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M13/322 ,  D06M15/673 ,  C09K3/28

    CPC分类号： D06M15/673 ,  D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M13/322

    摘要： Novel flame retardant finishes comprising a water soluble quaternary phosphonium salt, a water soluble organic nitrogen containing compound, a haloalkyl phosphate of the formula ##STR1## WHEREIN EACH X is independently selected from chlorine, bromine, and hydrogen, wherein a is an integer from 1 to 2, wherein n is an integer from 1 to 8, wherein m is an integer from 0 to n, provided that when n is 1, m is 0, and mixtures of said haloalkyl phosphates, an emulsifiying agent which is capable of passing the following three tests: (1) Solubility (Compatability) Test: said emulsifying agent (20 parts by weight) must be soluble in 80 parts by weight of said phosphate ester at less than or equal to 80.degree. C.; (2) Shelf Life Test: a blend of said emulsifying agent and said phosphate ester prepared as in the Solubility Test must remain in one clear homogeneous phase at 22.degree. C. for at least 1 hour; (3) Finish Formulation Test: a flame retardant finish within the scope of this invention is prepared and must remain in one homogeneous phase for a minimum of 1 hour at 20.degree. C. These flame retardant finishes are excellent for flame retarding textile materials including polyester/cotton blend fabrics.

    摘要翻译： 新型阻燃整理剂，其包含水溶性季鏻盐，水溶性有机氮化合物，每个X独立地选自式（ⅩⅩⅧ）的卤代烷基磷酸酯，其中a为1 至2，其中n为1至8的整数，其中m为0至n的整数，条件是当n为1时，m为0，所述卤代烷基磷酸酯的混合物为能够使 以下三个试验：（1）溶解性（兼容性）试验：所述乳化剂（20重量份）在80℃以下必须溶于80重量份的所述磷酸酯中。 （2）保质期测试：如在溶解性试验中制备的所述乳化剂和所述磷酸酯的共混物必须在22℃下保持在一个清澈的均匀相中至少1小时; （3）精加工试验：制备本发明范围内的阻燃整理剂，并且必须在20℃下保持在一个均相中至少1小时。这些阻燃整理剂对于阻燃纺织材料（包括聚酯）是优异的 /棉混纺面料。