公开(公告)号：US4097641A

公开(公告)日：1978-06-27

申请号：US748957

申请日：1976-12-09

申请人： Ray E. Smith ,  James A. Albright

发明人： Ray E. Smith ,  James A. Albright

IPC分类号： D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M15/673 ,  D06M23/06 ,  C09D1/00

CPC分类号： D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M15/673 ,  D06M23/06 ,  Y10S428/921 ,  Y10T442/2697

摘要： Improved flame retardant concentrates and finishes containing triesters of pentavalent phosphorus acid having the general formula ##STR1## WHEREIN X, X' and X" are hydrogen, chlorine and bromine; a is 0 or 1; n is an integer of from 1 to 7; m is an integer of from 1 to n; b is an integer of from 1 to 7; and z is an integer of from 1 to b.

摘要翻译： 具有通式为“X”，“X”和“X”的五价磷酸三酯的改进的阻燃浓缩物和表面处理剂是氢，氯和溴; a是0或1; n为1〜7的整数， m为1〜n的整数; b为1〜7的整数; z为1〜b的整数。

公开(公告)号：US4046701A

公开(公告)日：1977-09-06

申请号：US660502

申请日：1976-02-23

申请人： Ray E. Smith

发明人： Ray E. Smith

IPC分类号： D06M13/44 ,  D06M13/02 ,  D06M13/144 ,  D06M13/21 ,  D06M13/224 ,  D06M13/236 ,  D06M13/244 ,  D06M13/282 ,  D06M13/285 ,  D06M13/322 ,  D06M13/325 ,  D06M13/328 ,  D06M13/33 ,  D06M13/332 ,  D06M13/338 ,  D06M13/345 ,  D06M13/35 ,  D06M13/355 ,  D06M13/358 ,  D06M13/364 ,  D06M13/402 ,  D06M13/432 ,  D06M15/673 ,  C09K3/28

CPC分类号： D06M13/236 ,  D06M13/21 ,  D06M13/285 ,  D06M15/673

摘要： Novel flame retardant finishes comprising a water soluble quaternary phosphonium salt, a water soluble organic nitrogen containing compound, a halophthalate diol, water, and either an organic solvent characterized by having a flash point of at least 80.degree. F. and a boiling point within the range of about 300.degree. to about 350.degree. F. and an emulsifier having a hydrophile lipophile balance value of from about 10 to about 14 or an emulsifying agent which is capable of passing the following three tests: (1) Solubility (Compatability) Test: said emulsifying agent (20 parts by weight) must be soluble in 80 parts by weight of said phosphate ester at less than or equal to 80.degree. C.; (2) Shelf Life Test: a blend of said emulsifying agent and said phosphate ester prepared as in the Solubility Test must remain in one clear homogeneous phase at 22.degree. C. for at least one hour; (3) Finish Formulation Test: a flame retardant finish within the scope of this invention is prepared and must remain in one homogeneous phase for a minimum of one hour at 20.degree. C. These flame retardant finishes are excellent for flame retarding textile materials including polyester/cotton blend fabrics.

摘要翻译： 新型阻燃整理剂，其包含水溶性季鏻盐，水溶性有机氮化合物，卤代邻苯二甲酸酯二醇，水和有机溶剂，其特征在于闪点至少为80°F，沸点在 范围为约300至约350°F，亲水亲油平衡值为约10至约14的乳化剂或能够通过以下三个试验的乳化剂：（1）溶解度（兼容性）试验： 所述乳化剂（20重量份）在小于或等于80℃时必须溶于80重量份的所述磷酸酯中。 （2）保质期测试：如在溶解度试验中制备的所述乳化剂和所述磷酸酯的共混物必须在22℃下保持在一个清澈的均匀相中至少1小时; （3）精制制剂试验：制备本发明范围内的阻燃整理剂，并且必须在20℃下保持一个均匀相至少1小时。这些阻燃整理剂对于阻燃纺织品（包括聚酯）是优异的 /棉混纺面料。

公开(公告)号：US4345002A

公开(公告)日：1982-08-17

申请号：US76041

申请日：1979-09-17

申请人： Ray E. Smith ,  Jayendra G. Shukla ,  Richard R. Nicholson

发明人： Ray E. Smith ,  Jayendra G. Shukla ,  Richard R. Nicholson

IPC分类号： C07D251/70 ,  C07F9/09 ,  C07F9/146 ,  C07F9/24 ,  C09D5/18 ,  C09K21/10 ,  C09K21/12 ,  D06M15/673 ,  D04H1/58

CPC分类号： D06M15/673 ,  C07D251/70 ,  C07F9/091 ,  C07F9/146 ,  C07F9/2408 ,  C07F9/2458 ,  C09D5/185 ,  C09K21/10 ,  C09K21/12 ,  Y10S428/913 ,  Y10S428/921 ,  Y10T428/2938 ,  Y10T428/3196 ,  Y10T428/31967

摘要： An intumescent composition containing a cyclic nitrogen compound, a hydroxy-containing organo-phosphorus compound, an organo-phosphorus acid, and water, wherein:(a) said cyclic nitrogen compound is: ##STR1## wherein a, b, and c, are integers selected from the group consisting of 1 and 2, a plus b plus c equal about 3 to 6, and wherein and X, X', and X" are hydrogen or --CH.sub.3 ;(b) said hydroxy-containing organo-phosphorus compound is selected from the group consisting of: ##STR2## and mixtures thereof wherein R.sup.1, R.sup.2 and R.sup.3 are lower alkyl or haloalkyl radicals and R.sup.4 and R.sup.5 are hydrogen, lower alkyl or haloalkyl radicals;(c) said acid is selected from the group consisting of: ##STR3## and mixtures thereof, wherein R.sup.6, R.sup.7, R.sup.8 and R.sup.9 are hydrogen, lower alkyl, haloalkyl or hydroxyalkyl, R.sup.10 and R.sup.11 are lower alkyl, haloalkyl, hydroxy-polyalkyleneoxy, alkoxy, hydroxyalkoxy or haloalkoxy, ##STR4## wherein R.sup.12 is lower alkylene, haloalkylene, polyalkyleneoxy, hydroxy-alkylene and R.sup.13 and R.sup.14 are hydrogen, hydroxyl, lower alkyl, hydroxy-polyalkyleneoxy, alkoxy, hydroxyalkoxy or haloalkoxy.

摘要翻译： 包含环状氮化合物，含羟基的有机磷化合物，有机磷酸和水的膨胀性组合物，其中：（a）所述环状氮化合物是：其中a，b和c分别为 选自1和2，a加b加c等于3至6的整数，并且其中X，X'和X“是氢或-CH 3; （b）所述含羟基的有机磷化合物选自：其中R1，R2和R3是低级烷基或卤代烷基，R4和R5是氢，低级 烷基或卤代烷基; （c）所述酸选自：其中R 6，R 7，R 8和R 9是氢，低级烷基，卤代烷基或羟烷基，R 10和R 11是低级烷基 ，卤代烷基，羟基 - 聚亚烷基氧基，烷氧基，羟基烷氧基或卤代烷氧基，其中R12是低级亚烷基，卤代亚烷基，聚亚烷基氧基，羟基 - 亚烷基，R13和R14是氢，羟基，低级烷基，羟基 - 聚亚烷基氧基，烷氧基，羟基烷氧基或卤代烷氧基 。

公开(公告)号：US4265791A

公开(公告)日：1981-05-05

申请号：US101323

申请日：1979-12-06

申请人： Richard R. Nicholson ,  Ray E. Smith ,  Jayendra G. Shukla

发明人： Richard R. Nicholson ,  Ray E. Smith ,  Jayendra G. Shukla

IPC分类号： C07F9/09 ,  C09D5/18 ,  C09K21/12 ,  C09K3/28

CPC分类号： C09K21/12 ,  C07F9/091 ,  C09D5/185

摘要： A compound of the formula ##STR1## wherein a, b, c, d, and n are integers; a is from 1 to 3; b and c are independently selected from the group consisting of 0 and 1; d and n are independently selected from the group consisting of 1 and 2; R.sup.1 and R.sup.4 are independently selected from the group consisting of hydrogen, alkyl of 1 to 4 carbon atoms and haloalkyl of 1 to 4 carbon atoms and 1 to 2 halogen atoms; and R.sup.2 and R.sup.3 are independently selected from the group consisting of haloalkyl containing 1 to about 4 carbon atoms and 1 to about 2 halogen atoms selected from the group consisting of chlorine, bromine, and mixtures thereof.The use of this compound with specified amounts of a certain methylated methylol melamine and water allows one to produce an intumescent composition which is substantially superior to prior art intumescent compositions.

摘要翻译： 其中a，b，c，d和n是整数的式（Ⅰ）化合物：其中a，b，c，d和n是整数; a是1到3; b和c独立地选自0和1组成的组; d和n独立地选自1和2; R 1和R 4独立地选自氢，1至4个碳原子的烷基和1至4个碳原子的卤代烷基和1至2个卤素原子; 并且R 2和R 3独立地选自含有1至约4个碳原子的卤代烷基和1至约2个选自氯，溴及其混合物的卤素原子。 使用具有特定量的某些甲基化羟甲基三聚氰胺和水的该化合物允许产生基本上优于现有技术的膨胀组合物的膨胀组合物。

公开(公告)号：US4104172A

公开(公告)日：1978-08-01

申请号：US660500

申请日：1976-02-23

申请人： Ray E. Smith ,  James A. Albright

发明人： Ray E. Smith ,  James A. Albright

IPC分类号： D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M13/322 ,  D06M15/673 ,  C09K3/28

CPC分类号： D06M15/673 ,  D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M13/322

摘要： Novel flame retardant finishes comprising a water soluble quaternary phosphonium salt, a water soluble organic nitrogen containing compound, a haloalkyl phosphate of the formula ##STR1## WHEREIN EACH X is independently selected from chlorine, bromine, and hydrogen, wherein a is an integer from 1 to 2, wherein n is an integer from 1 to 8, wherein m is an integer from 0 to n, provided that when n is 1, m is 0, and mixtures of said haloalkyl phosphates, an emulsifiying agent which is capable of passing the following three tests: (1) Solubility (Compatability) Test: said emulsifying agent (20 parts by weight) must be soluble in 80 parts by weight of said phosphate ester at less than or equal to 80.degree. C.; (2) Shelf Life Test: a blend of said emulsifying agent and said phosphate ester prepared as in the Solubility Test must remain in one clear homogeneous phase at 22.degree. C. for at least 1 hour; (3) Finish Formulation Test: a flame retardant finish within the scope of this invention is prepared and must remain in one homogeneous phase for a minimum of 1 hour at 20.degree. C. These flame retardant finishes are excellent for flame retarding textile materials including polyester/cotton blend fabrics.

摘要翻译： 新型阻燃整理剂，其包含水溶性季鏻盐，水溶性有机氮化合物，每个X独立地选自式（ⅩⅩⅧ）的卤代烷基磷酸酯，其中a为1 至2，其中n为1至8的整数，其中m为0至n的整数，条件是当n为1时，m为0，所述卤代烷基磷酸酯的混合物为能够使 以下三个试验：（1）溶解性（兼容性）试验：所述乳化剂（20重量份）在80℃以下必须溶于80重量份的所述磷酸酯中。 （2）保质期测试：如在溶解性试验中制备的所述乳化剂和所述磷酸酯的共混物必须在22℃下保持在一个清澈的均匀相中至少1小时; （3）精加工试验：制备本发明范围内的阻燃整理剂，并且必须在20℃下保持在一个均相中至少1小时。这些阻燃整理剂对于阻燃纺织材料（包括聚酯）是优异的 /棉混纺面料。

公开(公告)号：US4088592A

公开(公告)日：1978-05-09

申请号：US660503

申请日：1976-02-23

申请人： Ray E. Smith

发明人： Ray E. Smith

IPC分类号： D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M13/322 ,  D06M15/673 ,  C09K3/28

CPC分类号： D06M15/673 ,  D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M13/322

摘要： Novel flame retardant finishes comprising a water soluble quaternary phosphonium salt, a water soluble organic nitrogen containing compound, a phosphate ester of haloalkanols, an emulsifying agent which is capable of passing the following three tests: (1) Solubility (Compatability) Test: said emulsifying agent (20 parts by weight) must be soluble in 80 parts by weight of said phosphate ester at less than or equal to 80.degree. C.; (2) Shelf Life Test: a blend of said emulsifying agent and said phosphate ester prepared as in the Solubility Test must remain in one clear homogeneous phase at 22.degree. C. for at least one hour; (3) Finish Formulation Test: a flame retardant finish within the scope of this invention is prepared and must remain in one homogeneous phase for a minimum of 1 hour at 20.degree. C., and water. These flame retardant finishes are excellent for flame retarding textile materials including polyester/cotton blend fabrics.

摘要翻译： 新型阻燃整理剂，其包含水溶性季鏻盐，水溶性有机氮化合物，卤代烷醇的磷酸酯，能够通过以下三个试验的乳化剂：（1）溶解性（兼容性）试验：所述乳化 试剂（20重量份）必须在小于或等于80℃下可溶于80重量份的所述磷酸酯。 （2）保质期测试：如在溶解度试验中制备的所述乳化剂和所述磷酸酯的共混物必须在22℃下保持在一个清澈的均匀相中至少1小时; （3）精制配方试验：制备本发明范围内的阻燃剂整理剂，并且必须在20℃保持一个均相至少1小时和水。 这些阻燃整理剂对于阻燃纺织材料（包括聚酯/棉混纺织物）是优异的。

公开(公告)号：US4015037A

公开(公告)日：1977-03-29

申请号：US660520

申请日：1976-03-22

申请人： Ray E. Smith ,  James A. Albright

发明人： Ray E. Smith ,  James A. Albright

IPC分类号： D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M15/673 ,  D06M23/06 ,  C09D1/00

CPC分类号： D06M13/285 ,  D06M13/295 ,  D06M13/298 ,  D06M15/673 ,  D06M23/06 ,  Y10S428/921 ,  Y10T442/2697

摘要： Novel flame retardant finishes comprising a water soluble quaternary phosphonium salt, a water soluble organic nitrogen containing compound, a haloalkyl phosphate of the formula ##STR1## WHEREIN EACH X is independently selected from chlorine, bromine, and hydrogen, wherein a is an integer from 1 to 2, wherein n is an integer from 1 to 8, and wherein m is an integer from 0 to n, provided that when n is 1, m is 0, an organic solvent characterized by having a flash point of at least 80.degree. F. and a boiling point within the range of about 300.degree. to about 350.degree. F., an emulsifier having a hydrophile lipophile balance value of from about 10 to about 14, and water. These flame retardant finishes are excellent for flame retarding textile materials including polyester/cotton blend fabrics.

摘要翻译： 新型阻燃整理剂，其包含水溶性季鏻盐，水溶性有机氮化合物，每个X独立地选自式（ⅩⅩⅧ）的卤代烷基磷酸酯，其中a为1 至2，其中n为1至8的整数，并且其中m为0至n的整数，条件是当n为1时，m为0，特征在于闪点为至少80°F的有机溶剂 沸点在约300至约350°F范围内，具有约10至约14的亲水亲油平衡值的乳化剂和水。 这些阻燃整理剂对于阻燃纺织材料（包括聚酯/棉混纺织物）是优异的。

公开(公告)号：USD348562S

公开(公告)日：1994-07-12

申请号：US3107

申请日：1992-12-28

申请人： Ray E. Smith

设计人： Ray E. Smith

公开(公告)号：US4952240A

公开(公告)日：1990-08-28

申请号：US366634

申请日：1989-06-15

申请人： Ray E. Smith

发明人： Ray E. Smith

IPC分类号： C09G1/02

CPC分类号： C09G1/02

摘要： A compound containing a tall oil fatty acid, oleic diethanol amide, aluminum oxide abrasive material, and organo-treated bentonite provides a polish for metals, such as aluminum, having a uniform viscosity and the abrasive particles uniformly dispersed throughout the carrier. Water may be added to form a scratch removing compound. Mineral spirits may be substituted for the fatty acid in the scratch remover to form a prepolish compound.

摘要翻译： 包含妥尔油脂肪酸，油酸二乙醇酰胺，氧化铝研磨材料和有机处理的膨润土的化合物提供具有均匀粘度的金属（例如铝）的抛光剂，并且磨料颗粒均匀地分散在整个载体中。 可以加入水以形成除去刮痕的化合物。 矿物精油可以代替刮擦去除剂中的脂肪酸以形成预混合物。

公开(公告)号：US4895675A

公开(公告)日：1990-01-23

申请号：US287120

申请日：1988-12-21

申请人： Ray E. Smith

发明人： Ray E. Smith

IPC分类号： C11D3/065

CPC分类号： C11D3/06 ,  C11D1/37 ,  C11D17/0013 ,  C11D1/143 ,  C11D1/22

摘要： An essentially neutral pH vehicle wheel cleaner for coated alloy vehicle wheels includes a builder, a surfactant, a buffer, a clarifier or mild abrasive, and a fragrance in water. The builder and surfactant interact to produce strong buffering to prevent a significant change in pH due to alkaline brake dust, road soil, and acidic road salts. A preferred embodiment utilizes tetrapotassium pyrophosphate as the builder, a sodium salt of sulfonated oleic acid as the buffer, and a ethylene oxide adduct of octylphenol as the surfactant. Various fragrances are disclosed.

摘要翻译： 用于涂覆合金车轮的基本上中性的pH车辆车轮清洁器包括助洗剂，表面活性剂，缓冲剂，澄清剂或温和的研磨剂和水中的香料。 助洗剂和表面活性剂相互作用以产生强烈的缓冲剂，以防止由于碱性制动粉尘，路面土壤和酸性路面盐引起的pH的显着变化。 优选的实施方案使用焦磷酸四钾作为助洗剂，磺化油酸的钠盐作为缓冲剂，辛基酚的环氧乙烷加合物作为表面活性剂。 公开了各种香料。