公开(公告)号：US20170320731A1

公开(公告)日：2017-11-09

申请号：US15534998

申请日：2015-12-01

Applicant: IFP Energies nouvelles ,  Total Raffinage Chimie

Inventor： Tiago SOZINHO ,  Mahdi YAZDANPANAH ,  Florent GUILLOU ,  Ann CLOUPET ,  Stephane BERTHOLIN ,  Hélène STAINTON

IPC: C01B3/44 ,  F23C10/01 ,  F23C10/22 ,  C01B3/38 ,  B01J8/26 ,  B01J8/18

CPC classification number: C01B3/44 ,  B01J8/0055 ,  B01J8/1827 ,  B01J8/26 ,  B01J2208/00752 ,  B01J2208/00893 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/025 ,  C01B2203/0255 ,  C01B2203/06 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  F23C10/01 ,  F23C10/22 ,  F23C2900/99008 ,  Y02E20/346

Abstract: The invention relates to a method and to a plant for chemical looping oxidation-reduction combustion (CLC) of a gaseous hydrocarbon feed, for example natural gas essentially containing methane. According to the invention, catalytic steam reforming of the feed is performed between two successive feed combustion steps on contact with an oxidation-reduction active mass in form of particles. The reforming catalyst is arranged in a fixed bed in an intermediate reforming zone (130) between the two reduction zones (120, 140) where the two combustion steps are conducted.FIG. 2 to be published.

公开(公告)号：US20200094213A1

公开(公告)日：2020-03-26

申请号：US16577665

申请日：2019-09-20

Applicant: IFP Energies nouvelles

Inventor： Frederic AUGIER ,  Alexandre VONNER ,  Tiago SOZINHO ,  Natacha TOUCHAIS

IPC: B01J10/00 ,  B01J23/755 ,  C07C2/08 ,  B01J19/00

Abstract: Compartmentalized reactor which makes possible the oligomerization of olefins to give linear olefins and preferably to give linear α-olefins, comprising a reaction chamber and at least one heat exchanger(s). The compartmentalized reactor is also employed in an oligomerization process.

公开(公告)号：US20200001266A1

公开(公告)日：2020-01-02

申请号：US16456313

申请日：2019-06-28

Applicant: IFP Energies nouvelles

Inventor： Frederic AUGIER ,  Alexandre VONNER ,  Tiago SOZINHO ,  Natacha TOUCHAIS

IPC: B01J19/24 ,  B01J8/22 ,  B01J23/755 ,  C07C2/24 ,  B01J8/18 ,  B01F3/04 ,  B01J23/26

Abstract: Reaction device which makes possible the oligomerization of olefins to give linear olefins and preferably linear α-olefins, comprising a gas/liquid reactor and a reactor of plug-flow type. The reaction device is also employed in an oligomerization process.

公开(公告)号：US20210107846A1

公开(公告)日：2021-04-15

申请号：US17256786

申请日：2019-06-21

Applicant: IFP Energies Nouvelles

Inventor： Frederic AUGIER ,  Alexandre VONNER ,  Tiago SOZINHO ,  Natacha TOUCHAIS

IPC: C07C2/32 ,  B01J19/00 ,  B01J19/24

Abstract: The invention relates to a process for the oligomerization of ethylene, carried out at a pressure of between 0.1 and 10.0 MPa, at a temperature of between 30 and 200° C., in a cascade of N gas/liquid reactors in series, N being at least equal to 2, comprising a step of introducing a catalytic oligomerization system into at least the first reactor of the cascade, a step of bringing said catalytic system and an optional solvent into contact with ethylene by introducing said ethylene into the lower part of the reaction chamber of at least the first reactor of the cascade, for each reactor n, a step of withdrawing a liquid fraction in the lower part of the reaction chamber of the reactor n, the liquid fraction being separated into two streams: a first stream corresponding to a first, “main”, part of the liquid fraction, which is conveyed to a heat exchanger for cooling; a second stream corresponding to the second part of the liquid fraction which constitutes the liquid feedstock of the following reactor n+1 in the cascade, a step of introducing said second part of the liquid phase withdrawn from the reactor n towards the reaction chamber of the following reactor n+1 in the direction of flow, a step of cooling said first part of the liquid fraction withdrawn from the reactor n in step c) by passing said first part of the liquid fraction into a heat exchanger in order to obtain a cooled liquid fraction, a step of introducing said liquid fraction cooled in step e) at the top of the reaction chamber of said reactor n, the steps a) to f) being carried out, unless indicated otherwise, for each reactor n of the cascade, n being between 1 and N. The invention also relates to a device of N stirred gas/liquid reactors in a cascade, enabling the oligomerization process to be carried out.

公开(公告)号：US20170321886A1

公开(公告)日：2017-11-09

申请号：US15535004

申请日：2015-12-01

Applicant: IFP Energies nouvelles ,  Total Raffinage Chimie

Inventor： Florent GUILLOU ,  Beatrice FISCHER ,  Tiago SOZINHO ,  Ann CLOUPET ,  Stephane BERTHOLIN ,  Mahdi YAZDANPANAH ,  Hélène STAINTON

IPC: F23C10/01 ,  B01J8/06 ,  F23C10/04 ,  C01B3/40 ,  F23C10/22 ,  F23C10/20

Abstract: The invention relates to a plant and to a method for chemical looping oxidation-reduction combustion of a gaseous hydrocarbon feed, for example natural gas essentially containing methane. According to the invention, catalytic pre-reforming of the feed is performed in a pre-reforming zone comprising a fixed reforming catalyst, while benefiting from a heat transfer between the reduction or oxidation zone of the chemical loop and the pre-reforming zone adjoining the reduction or oxidation zone. Pre-reforming zone (130) and oxidation zone (110) or pre-reforming zone (130) and reduction zone (120) are thus thermally integrated within the same reactor (100) while being separated by at least one thermally conductive separation wall (140).

公开(公告)号：US20170321887A1

公开(公告)日：2017-11-09

申请号：US15535010

申请日：2015-12-01

Applicant: IFP Energies nouvelles ,  Total Raffinage Chimie

Inventor： Mahdi YAZDANPANAH ,  William PELLETANT ,  Tiago SOZINHO ,  Stephane BERTHOLIN ,  Hélène STAINTON ,  Ann CLOUPET ,  Florent GUILLOU

IPC: F23C10/01 ,  B01J8/18 ,  F23C10/02 ,  F23C10/20 ,  C01B3/44 ,  F23C10/22

Abstract: The invention relates to a method and to a plant for chemical looping oxidation-reduction combustion (CLC) of a gaseous hydrocarbon feed, for example natural gas essentially containing methane. According to the invention, catalytic reforming of the feed is performed within the reduction zone where combustion of the feed is conducted on contact with an oxidation-reduction active mass in form of particles. The reforming catalyst comes in form of untransported fluidized particles within the reduction zone. The catalyst thus confined in the reduction zone does not circulate in the CLC loop.

公开(公告)号：US20160146456A1

公开(公告)日：2016-05-26

申请号：US14897866

申请日：2014-06-12

Applicant: TOTAL RAFFINAGE CHIMIE ,  IFP Energies nouvelles

Inventor： Florent GUILLOU ,  Tiago SOZINHO ,  Heloise DREUX ,  Helene STAINTON

IPC: F23C10/01 ,  F23C10/00 ,  F23C10/28 ,  F23C10/20 ,  F23C10/22 ,  F23D1/00 ,  F23C10/04

CPC classification number: F23C10/01 ,  F23C10/002 ,  F23C10/005 ,  F23C10/04 ,  F23C10/20 ,  F23C10/22 ,  F23C10/26 ,  F23C10/28 ,  F23C2900/99008 ,  F23D1/00 ,  Y02E20/346

Abstract: The invention relates to a method and to a device for chemical looping combustion CLC of a solid hydrocarbon feed wherein it is proposed to inject the solid hydrocarbon feed so as to limit any occurrence of sticking of the feed to the walls of the injection device. The solid feed is fed into a conveying zone operating under fluidized bed conditions and opening into a combustion reactor. A fluidization gas is injected into this conveying zone while controlling the flow of gas in such a way that the superficial velocity of the gas in the conveying zone is higher than the terminal velocity of the solid hydrocarbon feed particles and the terminal velocity of solid particles present in the combustion reactor, and while controlling the fluidization gas temperature in such a way that the temperature in the conveying zone is less than or equal to 500° C.

Abstract translation: 本发明涉及一种用于固体烃进料的化学循环燃烧CLC的方法和装置，其中建议注入固体烃进料以便限制进料粘附到注射装置的壁上。 将固体进料送入在流化床条件下运行并输送到燃烧反应器中的输送区。 流化气体被注入到该输送区域中，同时控制气体的流动，使得输送区域中的气体的表观速度高于固体烃进料颗粒的末端速度和存在的固体颗粒的终端速度 在燃烧反应器中，并且以使输送区域的温度小于或等于500℃的方式控制流化气体温度。