公开(公告)号：US5349057A

公开(公告)日：1994-09-20

申请号：US772375

申请日：1992-01-10

Applicant: Holger M. Buch ,  Hartmut Springer

Inventor： Holger M. Buch ,  Hartmut Springer

IPC: C09B62/51 ,  C09B62/44 ,  C09B62/513 ,  C09B62/515 ,  D06P3/10 ,  D06P3/66 ,  C09B62/08 ,  D06P1/38

CPC classification number: C09B62/4411

Abstract: Water-soluble azo dyes and their heavy metal complex derivatives, such as copper, cobalt and chromium complex azo dyes are described, which have the general formula (1) shown below, have fiber-reactive properties and dye natural and synthetic hydroxyl- and/or carboxamido-containing materials, in particular fiber materials, such as wool and in particular cellulose fiber materials, by the dyeing and printing processes customary for fiber-reactive dyes, in hues which have high color strength and good fastness properties. ##STR1##

Abstract translation: PCT No.PCT / EP90 / 00716 Sec。 371日期1992年1月10日 102（e）日期1992年1月10日PCT提交1990年5月4日PCT公布。 WO90 / 13603 PCT出版物 日本1990年11月15日。描述了水溶性偶氮染料及其重金属络合物衍生物，例如铜，钴和铬络合偶氮染料，其具有如下通式（1），具有纤维反应性和染料 天然和合成的含羟基和/或甲酰氨基的材料，特别是纤维材料，如羊毛，特别是纤维素纤维材料，通常用于纤维活性染料的染色和印花工艺，色度高，色泽好 坚牢性。 （1）

公开(公告)号：US5079347A

公开(公告)日：1992-01-07

申请号：US280682

申请日：1988-12-06

Applicant: Holger M. Buch

Inventor： Holger M. Buch

IPC: C09B62/09 ,  C09B62/44 ,  C09B62/513 ,  D06P1/38 ,  D06P3/10 ,  D06P3/66

CPC classification number: C09B62/09 ,  C09B62/4415

Abstract: Disazo compounds conforming to a general formula (1) shown below which have fiber-reactive dye properties and dye hydroxy- and/or carboxamido-containing fiber materials, such as wool and in particular cellulose, in strong fast shades. ##STR1## where R is a hydrogen atom or a sulfo group,R.sup.1 is a hydroxy group, a methoxy group or an ethoxy group,M is a hydrogen atom or an alkali metal,X is a chlorine atom or a fluorine atom,Y is a chlorine atom or an amino group or a group of the general formula (2) ##STR2## where R* is a hydrogen atom or a methyl or ethyl group,n is zero, 1 or 2,R.sup.2 is a hydrogen atom or a sulfo group or a .beta.-sulfatoethylsulfonyl group or a vinylsulfonyl group, andR.sup.3 is a sulfo group or a .beta.-sulfatoethylsulfonyl group or a vinylsulfonyl group,it being possible for R.sup.2 and R.sup.3 to be identical to or different from each other.

Abstract translation: 符合下述通式（1）的双唑类化合物具有纤维反应性染料性质和染料含羟基和/或羧酰氨基的纤维材料，如羊毛，特别是纤维素，具有强烈的快速色调。 （1）其中R为氢原子或磺基，R1为羟基，甲氧基或乙氧基，M为氢原子或碱金属，X为氯 原子或氟原子，Y是氯原子或氨基或通式（2）的基团其中R *是氢原子或甲基或乙基，n是0，1 或2，R 2为氢原子或磺基或β-磺酰基乙基磺酰基或乙烯基磺酰基，R 3为磺基或β-磺酰基乙基磺酰基或乙烯基磺酰基，则R2和R3可以相同 彼此之间或彼此不同。

公开(公告)号：US5243034A

公开(公告)日：1993-09-07

申请号：US794688

申请日：1991-11-18

Applicant: Horst Tappe ,  Dieter Oehme ,  Holger M. Buch ,  Werner H. Russ

Inventor： Horst Tappe ,  Dieter Oehme ,  Holger M. Buch ,  Werner H. Russ

IPC: C09B62/44 ,  C09B62/513

CPC classification number: C09B62/4415 ,  C09B62/513

Abstract: Disazo dyestuffs containing sulfo groups and having fiber-reactive properties, which are capable of dyeing materials containing hydroxyl groups and/or carboxamide groups, in particular fiber materials, such as synthetic polyamide fibers, wool and in particular cellulose fiber materials, in deep fast shades. They contain a group corresponding to the formula ##STR1## in which R.sup..alpha. is hydrogen or alkyl having 1 to 4 carbon atoms, which can be substituted by carboxyl, sulfo, cyano, hydroxyl or chlorine;B is fluorine, chlorine, bromine, lower alkylsulfonyl, phenylsulfonyl, methoxy or sulfo;Q is a group of the formula ##STR2## in which Y is vinyl, .beta.-sulfatoethyl, .beta.-halogenoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl or .beta.-acetoxyethyl,R is hydrogen or lower alkyl,k is the number zero to 4 andX, together with the N atom, forms the bivalent radical of a heterocyclic ring which optionally contains additional hetero atoms.

Abstract translation: 能够染色含有羟基和/或羧酰胺基团的物质的具有磺基并具有纤维反应性的双偶氮染料，特别是纤维材料，例如合成聚酰胺纤维，羊毛，特别是纤维素纤维材料，具有深快速色调 。 它们包含对应于其中Rα是氢或具有1至4个碳原子的烷基的式“IMAGE”的基团，其可以被羧基，磺基，氰基，羟基或氯取代; B是氟，氯，溴，低级烷基磺酰基，苯基磺酰基，甲氧基或磺基; Q是其中Y是乙烯基，β-磺基乙基，β-卤代乙基，β-硫代乙酰基乙基，β-磷酰乙基或β-乙酰氧基乙基的式 的基团，R是氢或低级烷基，k是数 0至4和X与N原子一起形成杂环的二价基团，其任选地含有另外的杂原子。

公开(公告)号：US5138041A

公开(公告)日：1992-08-11

申请号：US629257

申请日：1990-12-18

Applicant: Holger M. Buch ,  Werner H. Russ ,  Horst Tappe

Inventor： Holger M. Buch ,  Werner H. Russ ,  Horst Tappe

IPC: C09B62/51 ,  C09B62/507 ,  C09B62/513 ,  C09B62/515 ,  D06P3/10 ,  D06P3/66

CPC classification number: C09B62/507

Abstract: Water-soluble dyes having fiber-reactive properties and conforming to the general formula (1) ##STR1## where F is the radical of a metal-free or heavy metal complex monoazo or disazo dye which contains at least one sulfo group,n is 1 or 2,Y is vinyl, .beta.-sulfatoethyl, .beta.-haloethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl or .beta.-acetoxyethyl,R.sup..alpha. is hydrogen or lower alkyl which may be substituted by carboxy, sulfo, cyano, hydroxyl or chlorine,A is a group of the general formula (2a) or (2b) ##STR2## where G is alkylene of 1 to 6 carbon atoms, alkylene of 2 to 6 carbon atoms which is interrupted by 1 or 2 hetero groups, or methyl-substituted cycloalkylene,R is hydrogen, halogen, hydroxy, sulfato, cyano, carboxy, carbamoyl, lower carbalkoxy, lower alkanoylamino, substituted or unsubstituted benzoylamino or a group of the formula --SO.sub.2 --Y.sup.2 where Y.sup.2 has one of the meanings of Y or is .beta.-hydroxyethyl,k is zero, 1 or 2,k* is zero, 1, 2, 3, or 4,X forms together with the N-atom the bivalent radical of a heterocyclic ring,Y.sup.1 has one of the meanings specified for Y,W is hydrogen, methyl, sulfomethyl, carboxymethyl, substituted or unsubstituted lower alkyl, substituted or methyl-substituted cycloalkylene or substituted or unsubstituted phenyl, andB has one of the meanings specified for A.The dyes of the general formula (1) make it possible to obtain strong, fast dyeings and prints on carboxamido-containing and/or hydroxy-containing materials, in particular fiber materials, such as wool, synthetic polyamide and in particular cellulose fiber materials.

Abstract translation: 具有纤维反应性并符合通式（1）的水溶性染料（1）其中F是含有至少一个磺基的无金属或重金属络合物单偶氮或双偶氮染料的基团， n是1或2，Y是乙烯基，β-磺基乙基，β-卤代乙基，β-硫代乙酰基乙基，β-磷酸乙基或β-乙酰氧基乙基，Rα是氢或可以被羧基，磺基，氰基，羟基或 氯，A是通式（2a）或（2b）的基团，其中G是1至6个碳原子的亚烷基，被中断的2至6个碳原子的亚烷基 卤素，羟基，硫酸根，氰基，羧基，氨基甲酰基，低级烷酰氧基，低级烷酰氨基，取代或未取代的苯甲酰基氨基或式-SO2-Y2基团，其中， Y2具有Y的含义之一或为β-羟乙基，k为零，1或2，k *为0,1,2,3或4，X f 与N原子一起形成杂环的二价基团，Y1具有对Y定义的含义之一，W是氢，甲基，磺甲基，羧甲基，取代或未取代的低级烷基，取代或甲基取代的亚环烷基或取代或取代的 未取代的苯基，B具有对A规定的含义之一。通式（1）的染料使得有可能在含甲酰氨基和/或羟基的材料，特别是纤维材料上获得强烈，快速的染色和印刷 ，如羊毛，合成聚酰胺，特别是纤维素纤维材料。

公开(公告)号：US5166338A

公开(公告)日：1992-11-24

申请号：US654873

申请日：1991-02-13

Applicant: Holger M. Buch ,  Josef Geisenberger ,  Hartmut Springer

Inventor： Holger M. Buch ,  Josef Geisenberger ,  Hartmut Springer

IPC: C09B62/503

CPC classification number: C09B62/503

Abstract: Anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone and perylenetetracarbimide dyes which contain one or two groups of the general formula ##STR1## where Y is vinyl or an ethyl group which contains in a .beta.-position a substituent which is eliminable by means of alkali to form a vinyl group, and W is a direct bond or a group of the general formula ##STR2## where M is a hydrogen atom or an alkali metal and n is zero, 1 or 2. The dyes have very good fiber-reactive properties and are advantageously suitable for dyeing carboxamino- and/or hydroxy-containing material, for example wool, in particular cellulose fiber materials; on these materials they produce strong fast shades in a high degree of fixation.

Abstract translation: 蒽醌，酞菁，甲an，偶氮甲碱，二恶嗪，吩嗪，三苯甲烷，呫吨，噻吨酮，硝基芳基，萘醌，芘醌和苝醌四酰亚胺染料，其含有一个或两个通式为“IMAGE”的基团，其中Y是乙烯基或含有 β位，可通过碱可以除去形成乙烯基的取代基，W是直接键或通式为“IMAGE”的基团，其中M是氢原子或碱金属，n是0， 染料具有非常好的纤维反应性，并且有利地适用于染色含羧基氨基和/或羟基的材料，例如羊毛，特别是纤维素纤维材料; 在这些材料上，它们在高度的固定下产生强烈的快速色调。

公开(公告)号：US5021558A

公开(公告)日：1991-06-04

申请号：US496534

申请日：1990-03-20

Applicant: Holger M. Buch

Inventor： Holger M. Buch

IPC: C09B62/002 ,  C09B62/44

CPC classification number: C09B62/4403

Abstract: Water-soluble fiber-reactive azo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylemthane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dyes which contain once or twice the group of the general formula ##STR1## in which: R.sup.x and R.sup.z are, independently of one another, hydrogen or lower alkyl, which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato;W is fluorine, chlorine, bromine, sulfo, phenylsulfonyl or alkylsulfonyl of 1 to 4 carbon atoms;Y is vinyl, .beta.-substituted, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-alkanoyloxyethyl of 2 to 5 carbon atoms in the alkanoyl radical, .beta.-benozoyloxyethyl, .beta.-(sulfobenzoyloxy)ethyl, .beta.-(p-toluenesulfonyloxy)ethyl or .beta.-halogenoethyl.The fiber-reactive dyes are highly suitable for the dyeing of carboxamido-containing and/or hydroxyl-containing materials, such as, for example, synthetic polyamide fiber materials, wool and in particular cellulose fiber materials with a high degree of fixation in hues which have a high color strength and good fastness properties.

Abstract translation: 金属络合物偶氮，蒽醌，酞菁，甲an，偶氮甲碱，二恶嗪，吩嗪，芪，三苯酚，呫吨，噻吨酮，硝基芳基，萘醌，芘醌或苝四亚甲基亚胺染料，其含有一般或一般为 羟基，氰基，低级烷氧基，低级烷氧基羰基，羧基，氨磺酰基，磺基或硫酸根取代的氢或低级烷基;其中：R 1和R 3彼此独立地为氢或低级烷基。 W是1至4个碳原子的氟，氯，溴，磺基，苯基磺酰基或烷基磺酰基; Y是乙酰基，β-取代的，β-硫代硫代乙基，β-磷酰乙基，在链烷酰基中具有2至5个碳原子的β-烷酰氧基乙基，β-苯并氧乙基，β-（磺基苯甲酰氧基）乙基，β-（对甲苯磺酰氧基）乙基或 β-卤代乙基。 纤维反应性染料非常适合于含有羧酰胺的和/或含羟基材料的染色，例如合成聚酰胺纤维材料，羊毛，特别是具有高度固色度的纤维素纤维材料 具有高的色强度和良好的牢度性能。

公开(公告)号：US5227475A

公开(公告)日：1993-07-13

申请号：US776305

申请日：1992-01-10

Applicant: Holger M. Buch ,  Reinhard Hahnle ,  Hartmut Springer

Inventor： Holger M. Buch ,  Reinhard Hahnle ,  Hartmut Springer

IPC: C09B62/503 ,  C09B62/44 ,  D06P1/384 ,  D06P3/10 ,  D06P3/66

CPC classification number: C09B62/4403 ,  C09B62/503 ,  Y10S8/918 ,  Y10S8/921

Abstract: Water-soluble dyestuffs which correspond to the formula (1) given below, have fiber-reactive properties and dye synthetic and natural materials, in particular fiber materials, containing hydroxyl and/or carboxamide groups, such as wool and in particular cellulose fiber materials, in deep shades ##STR1## in which: F is the radical of a dyestuff, such as of an azo dyestuff, heavy metal complex azo dyestuff, anthraquinone dyestuff or phthalocyanine dyestuff,R.sup.x is hydrogen or lower alkyl, which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato;n is the number 1 or 2; andQ is a group of the formula ##STR2## in whichR.sup.z is hydrogen or lower alkyl, which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, carboxyl, sulfamoyl, sulfo, sulfato or by optionally substituted phenyl, or is cyclohexyl or optionally substituted phenyl, W is optionally substituted arylene or a combined radical of alkylene and arylene, in which the alkylene radicals and arylene radicals can be substituted and the alkylene radicals and alkylene-arylene radicals can likewise be interrupted by hetero groups; the group --SO.sub.2 --Y is a fiber-reactive group from the vinylsulfone series, z is the number 1 or 2, A is the number zero or 1, B is the number 1 or 2, the sum of (A+B) being 2, X, together with the N atom and 1 or 2 lower alkylene groups and if appropriate 1 or 2 hetero groups, forms the radical of a heterocyclic ring and alk is a lower alkylene,are described.

Abstract translation: PCT No.PCT / EP90 / 00715 Sec。 371日期1992年1月10日 102（e）日期1992年1月10日PCT提交1990年5月4日PCT公布。 出版物WO90 / 13604 1990年11月15日。对应于下面给出的式（1）的水溶性染料具有纤维反应性质和染料合成和天然材料，特别是含有羟基和/或羧酰胺基团的纤维材料，例如羊毛 特别是纤维素纤维材料，其中：F是染料的基团，例如偶氮染料，重金属络合物偶氮染料，蒽醌染料或酞菁染料，Rx是氢或 羟基，氰基，低级烷氧基，低级烷氧基羰基，羧基，氨磺酰基，磺基或硫酸根取代的低级烷基; n是数字1或2; 其中Rz是氢或低级烷基，其可以被卤素，羟基，氰基，低级烷氧基，羧基，氨磺酰基，磺基， 硫酸根或任选取代的苯基，或是环己基或任选取代的苯基，W是任选取代的亚芳基或亚烷基和亚芳基的组合基团，其中亚烷基和亚芳基可以被取代，并且亚烷基和亚烷基 - 亚芳基可以 同样被杂基中断; 基团-SO 2 -Y是来自乙烯基砜系列的纤维反应性基团，z是数字1或2，A是数字0或1，B是数字1或2，（A + B）的和 2，X与N原子和1或2个低级亚烷基，如果合适的话，1或2个杂原子形成杂环基，而alk是低级亚烷基。

公开(公告)号：US5112970A

公开(公告)日：1992-05-12

申请号：US397526

申请日：1989-08-23

Applicant: Holger M. Buch ,  Hartmut Springer

Inventor： Holger M. Buch ,  Hartmut Springer

IPC: C07D498/04 ,  C07D519/00 ,  C09B19/02 ,  C09B62/503 ,  D06P3/10 ,  D06P3/66

CPC classification number: C09B62/5033

Abstract: Water-soluble triphendioxazine compounds of the formula (1) with quaternary ammonium groups ##STR1## in which the substituents are defined in claim 1. The compounds (1) have fiber-reactive dyestuff properties and dye, for example, cellulose fiber materials, wool and synthetic polyamide in deep, fast shades.

Abstract translation: 具有季铵基团的式（1）的水溶性三苯并二恶嗪化合物其中取代基如权利要求1所定义。化合物（1）具有纤维反应性染料性质和染料，例如 ，纤维素纤维材料，羊毛和合成聚酰胺深深，色泽浅。

公开(公告)号：US4873320A

公开(公告)日：1989-10-10

申请号：US133009

申请日：1987-12-15

Applicant: Hartmut Springer ,  Manfred Kuhn ,  Holger M. Buch

Inventor： Hartmut Springer ,  Manfred Kuhn ,  Holger M. Buch

IPC: C09B62/503 ,  C07D251/50 ,  C09B62/44 ,  C09B62/507 ,  C09B62/51 ,  D06P1/38

CPC classification number: C09B62/4411

Abstract: Water-soluble dyes which contain one or two fiber-reactive groups of the formula ##STR1## in which each R is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, it being possible for both R to have a meaning which is identical to or different from one another, Y is the vinyl group or a group of the general formula --CH.sub.2 --CH.sub.2 --X in which X represents a substituent which can be eliminated as an anion, and m represents the number 2 or 3. These novel dyes can be used to dye hydroxy and/or carboxamide group-containing materials in particular fiber-materials, such as, in particular, cellulose fiber materials, in fast shades.

Abstract translation: 含有一个或两个式（IMAGE）的纤维反应性基团的水溶性染料，其中每个R是氢原子或具有1至4个碳原子的烷基，两个R可能具有的意义是 Y是乙烯基或通式-CH 2 -CH 2 -X的基团，其中X表示作为阴离子可被除去的取代基，m表示2或3.这些 新颖的染料可以用于以特别的纤维材料，特别是纤维素纤维材料，以快速色调染料含羟基和/或含羧酰胺基的材料。