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公开(公告)号：US09504980B2
公开(公告)日：2016-11-29
申请号：US13637243
申请日：2011-03-14
IPC分类号： C08L33/20 , B01J13/14 , C08J9/32 , B01J13/18 , C08F283/10
CPC分类号： B01J13/14 , B01J13/185 , C08F283/10 , C08J9/32 , C08J2201/024 , C08J2203/22 , C08J2300/22 , C08F220/44 , C08F220/06
摘要： The present invention provides a thermally expandable microcapsule that maintains a high expansion ratio and hardly bursts and shrinks even at a high temperature, a foamable thermoplastic resin masterbatch and a foam molded product that are produced using the thermally expandable microcapsule, and a method for producing the thermally expandable microcapsule. The thermally expandable microcapsule comprises a volatile expansion agent included in a shell as a core agent and the shell formed of a polymer, the shell containing a thermosetting resin and a polymer obtainable by polymerization of a monomer composition containing a nitrile-type monomer and a monomer having a carboxyl group, and the thermosetting resin having no radical-polymerizable double bond and at least two functional groups reactive with a carboxyl group per molecule.
摘要翻译： 本发明提供一种热膨胀性微胶囊，其即使在高温下也保持高膨胀率且几乎不会发生爆裂和收缩，使用该热膨胀性微胶囊制造的可发泡热塑性树脂母料和发泡成型体， 热膨胀微胶囊。 热膨胀性微胶囊包含作为核心试剂的外壳中含有的挥发性膨胀剂，由聚合物形成的壳，含有热固性树脂的壳和可通过聚合含有腈型单体和单体的单体组合物得到的聚合物 具有羧基，所述热固性树脂不具有自由基聚合性双键和至少两个与每个分子具有羧基反应的官能团。
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2.发明申请THERMALLY EXPANDABLE MICROCAPSULE AND PROCESS FOR PRODUCTION OF THERMALLY EXPANDABLE MICROCAPSULE 审中-公开热膨胀微生物的热膨胀微生物和生产方法公开(公告)号：US20130085192A1
公开(公告)日：2013-04-04
申请号：US13637462
申请日：2011-03-03
CPC分类号： C08L33/26 , B01J13/14 , C08F220/44 , C08F220/56 , C08L33/20
摘要： The present invention provides a thermally expandable microcapsule that is excellent in heat resistance and durability. The present invention is a thermally expandable microcapsule, which comprises a shell containing a copolymer, and a volatile liquid as a core agent included in the shell, the copolymer being obtainable by polymerization of a monomer mixture containing a monomer A and a monomer B, the monomer A being at least one selected from the group consisting of a nitrile group-containing methacrylic monomer and an amide group-containing methacrylic monomer, the monomer B being at least one selected from the group consisting of a carboxyl group-containing methacrylic monomer and an ester group-containing methacrylic monomer, a total amount of the monomer A and the monomer B accounting for 70% by weight or more of the monomer mixture, a weight ratio of the monomer A and the monomer B being 5:5 to 9:1, and the monomer mixture containing methacrylonitrile and methacrylic acid in a total amount of not more than 70% by weight of the monomer mixture.
摘要翻译： 本发明提供耐热性和耐久性优异的热膨胀性微胶囊。 本发明是一种热可膨胀微胶囊，其包含含有共聚物的壳和包含在壳中的作为核心试剂的挥发性液体，该共聚物可通过含有单体A和单体B的单体混合物的聚合获得， 单体A是选自含腈基的甲基丙烯酸单体和含酰胺基的甲基丙烯酸单体中的至少一种，单体B是选自含羧基的甲基丙烯酸单体和 含有酯基的甲基丙烯酸单体，单体A和单体B的总量占单体混合物的70重量％以上，单体A和单体B的重量比为5:5〜9:1 ，并且含有甲基丙烯腈和甲基丙烯酸的单体混合物的总量不超过单体混合物的70重量％。
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公开(公告)号：US20130303639A1
公开(公告)日：2013-11-14
申请号：US13976629
申请日：2011-12-28
IPC分类号： C08L63/00
CPC分类号： C08L63/00 , C08G59/40 , C08J9/32 , C08J2203/22 , C08J2205/052 , C08J2300/22 , C08J2300/26 , C08J2353/02 , C08J2423/06 , C08J2463/00
摘要： The present invention provides a resin composition for foam molding which can achieve high expansion ratio and can significantly improve tactile impression and vibration damping properties of the foam molding to be obtained.The present invention relates to a resin composition for foam molding comprising: a thermally expandable microcapsule that includes a shell containing an epoxy resin and a core agent that is a volatile expansion agent encapsulated by the shell; a thermoplastic resin; and a curable compound having two or more functional groups each selected from the group consisting of a carboxy group, a hydroxy group, an amino group, an amido group, and an acid anhydride group in each molecule.
摘要翻译： 本发明提供一种发泡成型用树脂组合物，其能够实现高膨胀率，能够显着提高要获得的发泡成型体的触感和振动阻尼性。 泡沫塑料用树脂组合物技术领域本发明涉及发泡成型用树脂组合物，其特征在于，包括含有环氧树脂的外壳和由壳包封的挥发性膨胀剂的芯剂的热膨胀性微胶囊， 热塑性树脂; 以及在各分子中具有选自羧基，羟基，氨基，酰胺基和酸酐基的两个以上官能团的固化性化合物。
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4.发明申请THERMALLY EXPANDABLE MICROCAPSULE, METHOD FOR PRODUCING THERMALLY EXPANDABLE MICROCAPSULE, FOAMABLE MASTERBATCH, AND FOAM MOLDED ARTICLE 有权热膨胀微生物，生产热膨胀微球的方法，可泡沫主板和泡沫塑料制品公开(公告)号：US20130065976A1
公开(公告)日：2013-03-14
申请号：US13637216
申请日：2011-03-03
CPC分类号： B01J13/14 , C08F220/44 , C08F220/56
摘要： The present invention provides a thermally expandable microcapsule that is excellent in heat resistance and durability and exhibits an excellent foaming property in a wide temperature range from low temperatures to high temperatures. The present invention is a thermally expandable microcapsule, which comprises a shell containing a copolymer, and a volatile liquid as a core agent included in the shell, the copolymer being obtainable by polymerization of a monomer mixture containing a monomer A and a monomer B, the monomer A being at least one selected from the group consisting of a nitrile group-containing acrylic monomer and an amide group-containing acrylic monomer, the monomer B being at least one selected from the group consisting of a carboxyl group-containing acrylic monomer and an ester group-containing acrylic monomer, a total amount of the monomer A and the monomer B accounting for 70% by weight or more of the monomer mixture, and a weight ratio of the monomer A and the monomer B being 5:5 to 9:1.
摘要翻译： 本发明提供耐热性和耐久性优异的热膨胀性微胶囊，并且在从低温到高温的宽温度范围内具有优异的发泡性。 本发明是一种热可膨胀微胶囊，其包含含有共聚物的壳和包含在壳中的作为核心试剂的挥发性液体，该共聚物可通过含有单体A和单体B的单体混合物的聚合获得， 单体A是选自含有腈基的丙烯酸类单体和含酰胺基的丙烯酸类单体中的至少一种，单体B是选自含羧基的丙烯酸类单体和 含有酯基的丙烯酸类单体，单体A和单体B的总量占单体混合物的70重量％以上，单体A和单体B的重量比为5：5〜9： 1。
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公开(公告)号：US09776157B2
公开(公告)日：2017-10-03
申请号：US13637216
申请日：2011-03-03
IPC分类号： C08L33/08 , C08J9/16 , C08L33/26 , C08L33/02 , C08L33/10 , C08L33/20 , B01J13/14 , C08F220/44 , C08F220/56
CPC分类号： B01J13/14 , C08F220/44 , C08F220/56
摘要： The present invention provides a thermally expandable microcapsule that is excellent in heat resistance and durability and exhibits an excellent foaming property in a wide temperature range from low temperatures to high temperatures. The present invention is a thermally expandable microcapsule, which comprises a shell containing a copolymer, and a volatile liquid as a core agent included in the shell, the copolymer being obtainable by polymerization of a monomer mixture containing a monomer A and a monomer B, the monomer A being at least one selected from the group consisting of a nitrile group-containing acrylic monomer and an amide group-containing acrylic monomer, the monomer B being at least one selected from the group consisting of a carboxyl group-containing acrylic monomer and an ester group-containing acrylic monomer, a total amount of the monomer A and the monomer B accounting for 70% by weight or more of the monomer mixture, and a weight ratio of the monomer A and the monomer B being 5:5 to 9:1.
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公开(公告)号：US20130184362A1
公开(公告)日：2013-07-18
申请号：US13820800
申请日：2011-09-01
IPC分类号： C08J9/228
CPC分类号： C08J9/228 , C08J9/0066 , C08J9/06 , C08J9/32 , C08J2201/024 , C08J2203/02 , C08J2203/04 , C08J2203/10 , C08J2203/22 , C08J2300/22 , C08J2323/06
摘要： The present invention aims to provide a foamable resin composition which enables foam molding at high expansion ratios and reduction of open cells. The present invention also aims to provide a foam molded body produced from the foamable resin composition. The present invention is a foamable resin composition including a thermoplastic resin, thermal expansion microcapsules, and a chemical foaming agent, wherein Ts is not lower than 120° C., Tmax is not lower than 190° C., and Ts-Tc is not lower than −30° C. and not higher than 6° C., where Ts denotes a foaming starting temperature of the thermal expansion microcapsules, Tmax denotes a maximum foaming temperature of the thermal expansion microcapsules, and Tc denotes a decomposition temperature of the chemical foaming agent.
摘要翻译： 本发明的目的在于提供一种发泡性树脂组合物，其能够以高膨胀率进行发泡成型并使开孔减少。 本发明的目的还在于提供一种由发泡性树脂组合物制成的发泡成型体。 本发明是一种发泡性树脂组合物，其包含热塑性树脂，热膨胀微胶囊和化学发泡剂，其中Ts不低于120℃，Tmax不低于190℃，Ts-Tc不为 低于-30℃且不高于6℃，其中Ts表示热膨胀微胶囊的发泡起始温度，Tmax表示热膨胀微胶囊的最大发泡温度，Tc表示化学品的分解温度 发泡剂。
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公开(公告)号：US20130065975A1
公开(公告)日：2013-03-14
申请号：US13637243
申请日：2011-03-14
IPC分类号： C08L33/20
CPC分类号： B01J13/14 , B01J13/185 , C08F283/10 , C08J9/32 , C08J2201/024 , C08J2203/22 , C08J2300/22 , C08F220/44 , C08F220/06
摘要： The present invention provides a thermally expandable microcapsule that maintains a high expansion ratio and hardly bursts and shrinks even at a high temperature, a foamable thermoplastic resin masterbatch and a foam molded product that are produced using the thermally expandable microcapsule, and a method for producing the thermally expandable microcapsule. The thermally expandable microcapsule comprises a volatile expansion agent included in a shell as a core agent and the shell formed of a polymer, the shell containing a thermosetting resin and a polymer obtainable by polymerization of a monomer composition containing a nitrile-type monomer and a monomer having a carboxyl group, and the thermosetting resin having no radical-polymerizable double bond and at least two functional groups reactive with a carboxyl group per molecule.
摘要翻译： 本发明提供一种热膨胀性微胶囊，其即使在高温下也保持高膨胀率且几乎不会发生爆裂和收缩，使用该热膨胀性微胶囊制造的可发泡热塑性树脂母料和发泡成型体， 热膨胀微胶囊。 热膨胀性微胶囊包含作为核心试剂的外壳中含有的挥发性膨胀剂，由聚合物形成的壳，含有热固性树脂的壳和可通过聚合含有腈型单体和单体的单体组合物得到的聚合物 具有羧基，所述热固性树脂不具有自由基聚合性双键和至少两个与每个分子具有羧基反应的官能团。
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公开(公告)号：US08138252B2
公开(公告)日：2012-03-20
申请号：US11886721
申请日：2005-12-13
CPC分类号： C08F290/062 , C04B35/195 , C04B35/565 , C04B35/584 , C04B35/63488 , C04B35/638 , C04B38/0615 , C04B2111/00793 , C04B2235/3217 , C04B2235/3409 , C04B2235/349 , C04B2235/3852 , C04B2235/6562 , C08F220/14 , C08F222/1006 , C08J3/12 , C08J2371/02 , Y10T428/2982 , Y10T428/2989 , C04B35/00
摘要： It is an object of the present invention to provide a thermally disappearing resin particle and a thermally disappearing hollow resin particle which can be decomposed at a low temperature in a short time and do not cause deformation or cracking of a sintered body to be obtained in the case of using as a binder for a ceramic or a lightening material; a method of producing the thermally disappearing hollow resin particle; a ceramic composition which can be degreased and fired at a low temperature in a short time and gives a molded body with a high porosity without deformation or cracking even in the case a large quantity of a pore-forming material is used; and a method of producing a porous ceramic filter.The present invention is directed to a thermally disappearing resin particle, which contains a polyoxyalkylene resin, and 10% by weight or more of the whole particle disappearing within an hour by heating at a prescribed temperature in a range from 100 to 300° C.
摘要翻译： 本发明的目的是提供一种热消失树脂颗粒和热消失的中空树脂颗粒，其可以在短时间内在低温下分解，并且不会引起烧结体的变形或开裂 用作陶瓷或减轻材料的粘合剂的情况; 制造热消失中空树脂颗粒的方法; 可以在短时间内在低温下脱脂和烧制的陶瓷组合物，并且即使在使用大量造孔材料的情况下也能赋予具有高孔隙率而没有变形或破裂的成型体; 以及多孔陶瓷过滤器的制造方法。 本发明涉及含有聚氧化烯树脂的热消失性树脂颗粒，并且在100〜300℃的规定温度下加热，在1小时内全部颗粒的10重量％以上消失。
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公开(公告)号：US07678486B2
公开(公告)日：2010-03-16
申请号：US11324487
申请日：2006-01-04
申请人： Hiroshi Yamauchi , Kenji Yamaga , Ko Takahashi
发明人： Hiroshi Yamauchi , Kenji Yamaga , Ko Takahashi
IPC分类号： H01M2/02
CPC分类号： H01M8/0228 , H01M8/0208 , H01M8/021 , H01M8/0221 , H01M8/0254 , H01M8/0263 , H01M8/0267 , H01M8/242 , H01M8/2483
摘要： A separator includes an electrically conductive flat plate and two electrically conductive channel plates superposed on each other with the electrically conductive flat plate interposed therebetween. The separator includes a plurality of manifolds for passing a reaction fluid to an adjacent cell are provided in the electrically conductive flat plate, and a plurality of zigzag or straight through-channels for permitting the flowing of the reaction fluid from the manifolds are formed in each of the two channel plates. The separator includes the through-channels in any one of the two electrically conductive channel plates disposed so that they are partially overlapped with the manifolds in the electrically conductive flat plate, and the through-channels in the other electrically conductive channel plate are formed to be partially larger than the contour of the electrically conductive flat plate.
摘要翻译： 分离器包括导电平板和两个彼此重叠的导电通道板，导电平板插入其间。 分离器包括用于将反应流体传递到相邻电池的多个歧管设置在导电平板中，并且在每个中形成用于允许反应流体从歧管流动的多个之字形或直通通道 的两个通道板。 分离器包括两个导电通道板中的任一个中的贯通通道，其布置成使得它们与导电平板中的歧管部分重叠，并且另一个导电通道板中的通道形成为 部分地大于导电平板的轮廓。
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公开(公告)号：US20070196707A1
公开(公告)日：2007-08-23
申请号：US11244237
申请日：2005-10-06
申请人： Masahiro Komachiya , Hiroshi Yamauchi , Katsunori Nishimura , Kou Takahashi , Yoshinari Hori , Yoshihide Kondo
发明人： Masahiro Komachiya , Hiroshi Yamauchi , Katsunori Nishimura , Kou Takahashi , Yoshinari Hori , Yoshihide Kondo
CPC分类号： G01R31/3658 , G01R31/362 , G01R31/3665 , H01M4/8642 , H01M4/921 , H01M8/026 , H01M8/04007 , H01M8/0432 , H01M8/04365 , H01M8/04373 , H01M8/04544 , H01M8/04552 , H01M8/04559 , H01M8/04664 , H01M8/04679 , H01M8/04686 , H01M8/04738 , H01M8/04776 , H01M8/0491 , H01M8/0606 , H01M8/1004 , H01M2250/10 , Y02B90/14 , Y02E60/521
摘要： A part of cell stack portions constituting a part of a fuel cell stack is used as a voltage detection portion, the size of a frequency component belonging to a predetermined specific frequency range is extracted from a voltage signal detected and the existence/absence of abnormality of a fuel cell system is diagnosed on the basis of the frequency component extracted.
摘要翻译： 构成燃料电池堆的一部分的电池组部分的一部分被用作电压检测部分，从检测到的电压信号中提取属于预定特定频率范围的频率分量的大小，并且存在/不存在异常 基于提取的频率分量来诊断燃料电池系统。
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