摘要:
A process for producing aliphatic amines which comprises reacting an aliphatic alcohol or an aliphatic aldehyde with an aminating agent selected from the group consisting of ammonia, a primary amine and a secondary amine in the liquid phase in the presence of an unsupported catalyst consisting essentially of (1) copper oxide or copper hydroxide (2) nickel oxide or nickel hydroxide, and, optionally, (3) an oxide or an hydroxide of a Group II A metal.
摘要:
A process for producing aliphatic amines which comprises reacting an aliphatic alcohol or an aliphatic aldehyde with an aminating agent selected from the group consisting of ammonia, a primary amine and a secondary amine in the liquid phase in the presence of an unsupported catalyst consisting essentially of (1) copper oxide or copper hydroxide and (2) a Group II A metal oxide or hydroxide. In a preferred embodiment the catalyst system also contains an organo nickel compound.
摘要:
A process for producing aliphatic amines which comprises reacting an aliphatic alcohol or an aliphatic aldehyde with an aminating agent selected from the group consisting of ammonia, a primary amine and a secondary amine in the liquid phase in the presence of an unsupported catalyst consisting essentially of (1) copper oxide or copper hydroxide and (2) an organo nickel compound.
摘要:
A process for preparing alkyldimethylamines which comprises passing through a fixed bed, containing a copper catalyst and, optionally, chromium oxide, mounted on magnesium aluminate spinel support, dimethylamine and an alcohol or mixture of alcohols.
摘要:
A process for preparing acrylonitrile which comprises passing a gaseous mixture comprising propylene, ammonia and molecular oxygen and an ammoxidation catalyst through a reaction zone while controlling the superficial linear gas velocity and solids feeds rate to achieve a state of fast fluidization.
摘要:
Acrylonitrile is produced by passing a gaseous mixture comprising propylene, molecular oxygen and ammonia upwardly through a fluidized bed comprising particles of a highly-active acrylonitrile catalyst in physical admixture with particles of a composite consisting essentially of antimony oxide and silica. The use of the antimony oxide-silica composite moderates the effect of the highly-active acrylonitrile catalyst reducing its activity sufficiently to enable the use of longer residence times, but without reducing the acrylonitrile selectivity of the catalyst.
摘要:
A process for preparing alkyldimethylamines which comprises passing through a fixed bed, containing a copper catalyst, optionally chromium oxide, and an oxide of a Group I metal, selected amounts of dimethylamine and an alcohol or mixtures of alcohols.
摘要:
A process and apparatus for coating a surface of an elongated strip article, e.g. aluminum sheet, with a layer of solid polymer material. The process involves heating the polymer to produce a melt having a viscosity of at least 1000 centipoise when measured according to ASTM D4449 at 1 radian per second, extruding the melt onto a moving surface of the strip article through an elongated slot in a coating head having an extended surface adjacent to the slot arranged at an angle to the moving surface to form a coating gap converging in the direction of movement, thereby forming a coating on the strip article, and pushing the coating head towards the surface of the strip article as the melt is extruded as the coating onto the surface from the slot to reduce the coating thickness to a desired range by pressing the extended surface of the coating head onto the coating as the coating is formed. The apparatus includes coating heat, provided with a heater to maintain the viscosity of the melt, and load application device for the coating head, as well as equipment for melting the polymer and supplying the melt under pressure and at the desired temperature to the coating head. The process and apparatus allows strip articles to be coated with thin (1-100 microns) coatings of polymer materials without employing liquids as solvents or the like that cause atmospheric pollution problems.
摘要:
A crystalline zeolite SSZ-32 of novel composition is prepared using an N-lower alkyl-N'-isopropyl-imidazolium cation as a template. Also disclosed is a process for converting hydrocarbons with crystalline zeolite SSZ-32.