公开(公告)号：US4067918A

公开(公告)日：1978-01-10

申请号：US737764

申请日：1976-11-01

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: C07C2/02 ,  C07C2/42 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C13/605 ,  C07C43/188 ,  C07C3/035

CPC classification number: C07C43/188 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C13/605 ,  C07C2/02 ,  C07C2/42 ,  C07C2101/14 ,  C07C2101/16 ,  C07C2101/18 ,  C07C2101/20 ,  C07C2103/84

Abstract: A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.

Abstract translation: 一系列单环，双和三环化合物，其中大多数在环中具有烯属不饱和键，其可以具有或不具有取代基。 虽然双环和三环可以是未取代的，但是具有烯属不饱和键，特别是多个烯属不饱和键的这些化合物在已知的聚合体系中是可聚合的和可共聚的。 它们是特别好的交联剂。 这些化合物在它们可以被氧化裂解的意义上可进一步用于在增塑剂和洗涤剂领域已知有用的相应的羧酸，醛和/或醇。 不具有烯属不饱和键的化合物也可被氧化裂解以产生氧化的，例如酸，醇或醛，已知有用的化合物。

公开(公告)号：US3965142A

公开(公告)日：1976-06-22

申请号：US250533

申请日：1972-05-05

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: B01J31/24 ,  C07C69/74

CPC classification number: B01J31/185 ,  B01J2231/328 ,  B01J2531/847 ,  C07C2101/20 ,  C07C2102/32 ,  C07C2103/38

Abstract: Cyclocooligomerization of at least one conjugated diene and an alkyl acrylate in the presence of a noncarbonyl containing, zero-valent nickel complex compound catalyst to form an olefinically unsaturated alicyclic ring compound having the non-hydrocarbon functional group pendent from the ring.

Abstract translation: 在不含羰基的零价镍络合物催化剂的存在下，使至少一种共轭二烯和丙烯酸烷基酯进行环冷成型，形成具有从该环引发的非烃官能团的烯属不饱和脂环族化合物。

公开(公告)号：US4080388A

公开(公告)日：1978-03-21

申请号：US621187

申请日：1975-10-09

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: B01J31/22 ,  C07C29/68 ,  C07C33/02 ,  C07C33/14 ,  C07C33/26 ,  C07C33/28 ,  C07C33/30 ,  C07D307/42 ,  C07F15/04 ,  C07C43/20

CPC classification number: C07F15/04 ,  B01J31/2213 ,  B01J31/2291 ,  B01J31/2295 ,  C07C29/68 ,  C07C33/02 ,  C07C33/14 ,  C07C33/26 ,  C07C33/28 ,  C07C33/30 ,  C07D307/42 ,  B01J2531/847 ,  C07C2101/16

Abstract: Process of producing nickel alcoholates by reacting .pi.-allyl nickel compounds with carbonyl compounds. The nickel alcoholates so produced can be hydrolyzed to their corresponding alcohols and these alcohols can in part be dehydrated to their corresponding olefins. The nickel alcoholate products are useful for the production of their corresponding alcohols and these alcohols are useful for the production of their corresponding olefins.

Abstract translation: 通过使pi烯丙基镍化合物与羰基化合物反应生产镍醇化物的方法。 如此生产的镍醇盐可以水解成其相应的醇，这些醇可以部分脱水成相应的烯烃。 镍醇化物产品可用于生产其相应的醇，这些醇可用于生产其相应的烯烃。

公开(公告)号：US4070406A

公开(公告)日：1978-01-24

申请号：US737765

申请日：1976-11-01

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: C07C2/02 ,  C07C2/42 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C13/605 ,  C07C43/188 ,  C07C15/00 ,  C07C3/035

CPC classification number: C07C43/188 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C13/605 ,  C07C2/02 ,  C07C2/42 ,  C07C2101/14 ,  C07C2101/16 ,  C07C2101/18 ,  C07C2101/20 ,  C07C2103/84

Abstract: A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.

Abstract translation: 一系列单环，双和三环化合物，其中大多数在环中具有烯属不饱和键，其可以具有或不具有取代基。 虽然双环和三环可以是未取代的，但是具有烯属不饱和键，特别是多个烯属不饱和键的这些化合物在已知的聚合体系中是可聚合的和可共聚的。 它们是特别好的交联剂。 这些化合物在它们可以被氧化裂解的意义上可进一步用于在增塑剂和洗涤剂领域已知有用的相应的羧酸，醛和/或醇。 不具有烯属不饱和键的化合物也可被氧化裂解以产生氧化的，例如酸，醇或醛，已知有用的化合物。

公开(公告)号：US4056552A

公开(公告)日：1977-11-01

申请号：US565282

申请日：1975-04-04

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: C07C69/74

CPC classification number: C07C2102/32 ,  C07C2103/84

Abstract: A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.

Abstract translation: 一系列单环，双和三环化合物，其中大多数在环中具有烯属不饱和键，其可以具有或不具有取代基。 虽然双环和三环可以是未取代的，但是具有烯属不饱和键，特别是多个烯属不饱和键的这些化合物在已知的聚合体系中是可聚合的和可共聚的。 它们是特别好的交联剂。 这些化合物在它们可以被氧化裂解的意义上可进一步用于在增塑剂和洗涤剂领域已知有用的相应的羧酸，醛和/或醇。 不具有烯属不饱和键的化合物也可被氧化裂解以产生氧化的，例如酸，醇或醛，已知有用的化合物。

公开(公告)号：US4048214A

公开(公告)日：1977-09-13

申请号：US605367

申请日：1975-08-15

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: B01J31/24 ,  C07C67/30

CPC classification number: B01J31/185 ,  B01J2231/20 ,  B01J2231/328 ,  B01J2531/847 ,  C07C2101/20 ,  C07C2102/32 ,  C07C2103/38

Abstract: Cyclocooligomerization of at least one conjugated diene and an alkyl acrylate in the presence of a non-carbonyl containing, zero-valent nickel complex compound catalyst to form an olefinically unsaturated alicyclic ring compound having the non-hydrocarbon functional group pendent from the ring.

Abstract translation: 在含有非羰基的0价镍配位化合物催化剂的存在下，至少一种共轭二烯和丙烯酸烷基酯进行环冷成型，形成具有从该环引发的非烃官能团的烯属不饱和脂环族化合物。

公开(公告)号：US4032585A

公开(公告)日：1977-06-28

申请号：US585287

申请日：1975-06-09

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: C07C2/02 ,  C07C2/42 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C13/605 ,  C07C13/26

CPC classification number: C07C13/605 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C2/02 ,  C07C2/42 ,  C07C2101/14 ,  C07C2101/16 ,  C07C2101/18 ,  C07C2101/20 ,  C07C2103/84

Abstract: A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.

公开(公告)号：US4076757A

公开(公告)日：1978-02-28

申请号：US737766

申请日：1976-11-01

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: C07C2/02 ,  C07C2/42 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C13/605 ,  C07C43/188 ,  C07C43/18

CPC classification number: C07C43/188 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C13/605 ,  C07C2/02 ,  C07C2/42 ,  C07C2101/14 ,  C07C2101/16 ,  C07C2101/18 ,  C07C2101/20 ,  C07C2103/84

Abstract: A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.

Abstract translation: 一系列单环，双和三环化合物，其中大多数在环中具有烯属不饱和键，其可以具有或不具有取代基。 虽然双环和三环可以是未取代的，但是具有烯属不饱和键，特别是多个烯属不饱和键的这些化合物在已知的聚合体系中是可聚合的和可共聚的。 它们是特别好的交联剂。 这些化合物在它们可以被氧化裂解的意义上可进一步用于在增塑剂和洗涤剂领域已知有用的相应的羧酸，醛和/或醇。 不具有烯属不饱和键的化合物也可被氧化裂解以产生氧化的，例如酸，醇或醛，已知有用的化合物。

公开(公告)号：US4054610A

公开(公告)日：1977-10-18

申请号：US621185

申请日：1975-10-09

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: C07C29/09 ,  C07C29/128 ,  C07C29/17 ,  C07C29/38 ,  C07C29/68 ,  C07C33/02 ,  C07C33/28 ,  C07C33/30 ,  C07C35/46 ,  C07D307/42 ,  C07C33/06

CPC classification number: C07D307/42 ,  C07C29/09 ,  C07C29/128 ,  C07C29/17 ,  C07C29/38 ,  C07C29/68 ,  C07C33/02 ,  C07C33/28 ,  C07C33/30 ,  C07C35/46 ,  C07C403/24 ,  C12C11/02

Abstract: This invention relates to novel nickel alcoholates and alcohols thereof and to a process of preparing said novel nickel alcoholates and alcohols.

Abstract translation: 本发明涉及新型镍醇化物及其醇，以及制备所述新型镍醇盐和醇的方法。

公开(公告)号：US4052435A

公开(公告)日：1977-10-04

申请号：US739166

申请日：1976-11-01

Applicant: Gunther Wilke ,  Paul Heimbach

Inventor： Gunther Wilke ,  Paul Heimbach

IPC: C07C2/02 ,  C07C2/42 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C13/605 ,  C07C69/74

CPC classification number: C07C13/605 ,  C07C13/00 ,  C07C13/20 ,  C07C13/263 ,  C07C13/271 ,  C07C13/277 ,  C07C13/28 ,  C07C13/32 ,  C07C2/02 ,  C07C2/42 ,  C07C2101/14 ,  C07C2101/16 ,  C07C2101/18 ,  C07C2101/20 ,  C07C2103/84

Abstract: A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.