公开(公告)号：US5066695A

公开(公告)日：1991-11-19

申请号：US374321

申请日：1989-06-29

Applicant: Georg Cseh ,  Paul Lienhard ,  Walter Wiedemann

Inventor： Georg Cseh ,  Paul Lienhard ,  Walter Wiedemann

IPC: C08K5/00 ,  C08K5/16 ,  C08K5/29 ,  C08K5/30 ,  C08L23/10 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00 ,  C09B26/02 ,  C09B57/10

CPC classification number: C08K5/0091 ,  C09B26/02 ,  C09B57/10

Abstract: High-molecular weight organic material containing at least one metal complex of a ligand of formula I: ##STR1## wherein A is a carbocyclic aromatic or heterocyclic aromatic radical, B is a carbocyclic aromatic radical or a heterocyclic aromatic radical containing at least one N atom, it being necessary for at least one of the radicals A and B to be heterocyclic, and R.sub.1 is --C.sub.1 -C.sub.18 -alkyl, a carbocyclic aromatic radical or a heterocyclic aromatic radical containing at least one N atom, and the metal is a transition metal cation carrying a double positive charge selected from Ni.sup.2+, Cu.sup.2+, Co.sup.2+, Zn.sup.2+, Mn.sup.2+, Fe.sup.2+, Cd.sup.2+ or Pt.sup.2+ or the radical VO.sup.2+.

Abstract translation: 含有式I配体的至少一种金属络合物的高分子量有机材料：其中A是碳环芳族或杂环芳族基团，B是至少含有碳环芳族基团或杂环芳族基团 一个N原子，基团A和B中的至少一个是杂环，R1是-C1-C18-烷基，含有至少一个N原子的碳环芳族基团或杂环芳族基团，金属 是携带选自Ni2 +，Cu2 +，Co2 +，Zn2 +，Mn2 +，Fe2 +，Cd2 +或Pt2 +或基团VO2 +的双正电荷的过渡金属阳离子。

公开(公告)号：US4670486A

公开(公告)日：1987-06-02

申请号：US745034

申请日：1985-06-13

Applicant: Georg Cseh ,  Paul Lienhard

Inventor： Georg Cseh ,  Paul Lienhard

IPC: C09B45/14 ,  C08K5/00 ,  C08K5/23 ,  C09B56/00 ,  C09B45/48 ,  C09B63/00 ,  C09B67/20 ,  C09D3/48

CPC classification number: C09B56/00 ,  C08K5/0091 ,  C08K5/23 ,  Y10S8/09 ,  Y10S8/92 ,  Y10S8/928

Abstract: High molecular weight organic material is effectively colored by the incorporation therein of a copper or nickel complex of the ligand compound of formula I ##STR1## wherein A is an isocyclic or heterocyclic aromatic moiety, R is H, halogen, lower alkyl or alkoxy, R.sub.1 is H, lower alkyl, phenyl or substituted phenyl, and B is H, lower alkyl, ureido or substituted ureido, guanidino, anilino, benzamido or a heterocyclic aromatic moiety.

Abstract translation: 高分子量有机材料通过掺入式I配体化合物（I）的铜或镍络合物而有效着色，其中A是一个环状或杂环芳族部分，R是H，卤素，低级烷基或 烷氧基，R 1为H，低级烷基，苯基或取代的苯基，B为H，低级烷基，脲基或取代的脲基，胍基，苯胺基，苯甲酰氨基或杂环芳族部分。

公开(公告)号：US4639477A

公开(公告)日：1987-01-27

申请号：US745033

申请日：1985-06-13

Applicant: Georg Cseh ,  Paul Lienhard

Inventor： Georg Cseh ,  Paul Lienhard

IPC: C09B45/04 ,  C08K5/00 ,  C09B45/00 ,  C09B56/02 ,  C08K5/23

CPC classification number: C09B45/00 ,  C08K5/0091 ,  C09B56/02

Abstract: Process for mass-coloring high-molecular organic material, which comprises using a metal complex of the formulae I and/or Ia ##STR1## in which R is a hydrogen or chlorine atom or a methyl or methoxy group, R.sub.1 is a hydrogen atom, C.sub.1 -C.sub.4 -alkyl or phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, --NO.sub.2, --CONH.sub.2 --CONHR.sub.2 or C.sub.2 -C.sub.5 -N-alkylcarbamoyl, X is --CH.dbd. or --N.dbd., M is a divalent transition metal, and A is phenyl or substituted phenyl and R.sub.2 is alkyl, phenyl or substituted phenyl.The resulting colorations are distinguished by high tinctorial strength and good fastness properties, such as light, weathering and migration fastness properties.

Abstract translation: 用于大量着色高分子有机材料的方法，其包括使用其中R是氢或氯原子的式I和/或Ia（Ia）的金属络合物或其甲基或 甲氧基，R1是氢原子，未被取代或被卤素，C1-C4-烷基，C1-C4-烷氧基，-NO2，-CONH2-CONHR2或C2-C5-N- 烷基氨基甲酰基，X是-CH =或-N =，M是二价过渡金属，A是苯基或取代的苯基，R 2是烷基，苯基或取代的苯基。 得到的着色具有高的着色强度和良好的牢度性质，例如光，耐候性和耐迁移性能。

公开(公告)号：US4775747A

公开(公告)日：1988-10-04

申请号：US15815

申请日：1987-02-17

Applicant: Georg Cseh ,  Paul Lienhard

Inventor： Georg Cseh ,  Paul Lienhard

IPC: C09B45/14 ,  C08K5/00 ,  C08K5/23 ,  C09B56/00 ,  C09B45/04 ,  C09B45/24 ,  C09B45/34

CPC classification number: C09B56/00 ,  C08K5/0091 ,  C08K5/23 ,  Y10S8/09 ,  Y10S8/92 ,  Y10S8/928

Abstract: Transition metal complexes of the compounds of the formulae I and II ##STR1## in which A is an isocylic or heterocyclic aromatic radical, R is --H, halogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, R.sub.1 is --H, C.sub.1 -C.sub.4 -alkyl or phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, --NO.sub.2, --CONH.sub.2, --CONHR.sub.2 or C.sub.2 -C.sub.5 -N-alkylcarbamoyl, X is --CH.dbd. or --N.dbd. andB is --H, C.sub.1 -C.sub.4 -alkyl, --NHCONH.sub.2, --NHCONH-C.sub.1 -C.sub.4 -alkyl, --NHCONR.sub.2, --NHCSNH.sub.2, --NHCSR.sub.3, --NHC(NH)NH.sub.2, --NHR.sub.2, --NHCOR.sub.3, --NHSO.sub.2 R.sub.3 or a heterocyclic aromatic radical, and R.sub.2 and R.sub.3 are phenyl or substituted phenyl, are suitable for pigmenting high-molecular organic material.

Abstract translation: 式I和II化合物的过渡金属络合物其中A是异环或杂环芳族基团，R是-H，卤素，C 1 -C 4 - 烷基或C 1 -C 4 - C 1 -C 4烷氧基，C 1 -C 4烷氧基，-CONH 2，-CONHR 2或C 2 -C 5 -N（C 1 -C 4）烷氧基，R 1为-H，C 1 -C 4 - 烷基或未被卤素， - 烷基氨基甲酰基，X是-CH =或-N =，B是-H，C1-C4-烷基，-NHCONH2，-NHCONH-C1-C4-烷基，-NHCONR2，-NHCSNH2，-NHCSR3，-NHC（NH） NH 2，-NHR 2，-NHCOR 3，-NHSO 2 R 3或杂环芳族基团，并且R 2和R 3为苯基或取代的苯基，适用于着色高分子有机材料。

公开(公告)号：US4065449A

公开(公告)日：1977-12-27

申请号：US639560

申请日：1975-12-10

Applicant: Georg Cseh

Inventor： Georg Cseh

IPC: C08K5/00 ,  C08K5/22 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L27/00 ,  C08L67/00 ,  C09B33/153 ,  C09B33/14

CPC classification number: C09B33/153

Abstract: Disazo pigments of the formula ##STR1## WHEREIN A represents a carbocyclic or heterocyclic aromatic radical, in particular, those of the formula ##STR2## WHEREIN EACH OF X and Y represents a hydrogen or a halogen atom, an alkyl or alkoxy group of 1 to 6 carbon atoms, an aryloxy, trifluoromethyl, nitro, cyano, carboxylic ester or carboxy amide group, or wherein X and Y together represent a fused benzene ring are valuable pigments coloring plastics and lacquers in yellow to orange shades of excellent fastness properties.

Abstract translation: 下式的双偶氮颜料：其中A表示碳环或杂环芳族基团，特别是X和Y各自表示氢或卤素的式 原子，1至6个碳原子的烷基或烷氧基，芳氧基，三氟甲基，硝基，氰基，羧酸酯或羧酰胺基，或其中X和Y一起代表稠合苯环是有价值的颜料，着色塑料和漆黄色 具有优异的牢度特性的橙色色调。

公开(公告)号：US4055559A

公开(公告)日：1977-10-25

申请号：US620689

申请日：1975-10-08

Applicant: Georg Cseh ,  Willy Mueller

Inventor： Georg Cseh ,  Willy Mueller

IPC: C09B33/153 ,  C09B33/14

CPC classification number: C09B33/153

Abstract: A disazo pigment of the formula ##STR1## WHEREIN X and Y are hydrogen, chlorine, alkyl of 1 - 4 C-atoms or one of X and Y can be alkoxy of 1 - 4 C-atoms and Z is chlorine or methyl, which is useful for pigmenting high molecular organic material and shows excellent fastness to light and weather.

Abstract translation: 式中，X和Y为氢，氯，1-4个碳原子的烷基或X和Y中的一个的双重颜料可以是1-4个C原子的烷氧基，Z是 氯或甲基，其可用于着色高分子有机材料并且显示出优异的耐光牢度和耐候性。

公开(公告)号：US5151505A

公开(公告)日：1992-09-29

申请号：US612764

申请日：1990-11-13

Applicant: Stefan Hari ,  Georg Cseh

Inventor： Stefan Hari ,  Georg Cseh

IPC: C08K5/34 ,  C08K5/3442 ,  C08K5/3445 ,  C08K5/41 ,  C08K5/42 ,  C08L101/00 ,  C09B29/01 ,  C09B29/46 ,  C09B29/50 ,  C09B69/04

CPC classification number: C09B29/0007 ,  C09B29/366 ,  C09B69/045

Abstract: Compounds of formula ##STR1## wherein a and b are each independently of the other halogen, --CH.sub.3, --C.sub.2 H.sub.5, --OC.sub.2 H.sub.5 or the group of formula --NHCO--C.sub.1 -C.sub.4 alkyl, c and d are each independently of the other hydrogen, halogen, --CH.sub.3, --C.sub.2 H.sub.5, --OCH.sub.3, --OC.sub.2 H.sub.5 or the group of formula --NHCO--C.sub.1 -C.sub.4 alkyl, and R.sup.1 is --CH.sub.3, phenyl, --COOCH.sub.3, --COOC.sub.2 H.sub.5, --NHCO--C.sub.1 -C.sub.4 alkyl or --CONH--C.sub.1 -C.sub.4 alkyl, and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl, unsubstituted or substituted by a chlorine atom or a --OH group, or are C.sub.7 -C.sub.9 aralkyl, C.sub.5 -C.sub.8 cycloalkyl, phenyl or phenyl which is substituted by 1 to 3 halogen atoms or methyl or methoxy groups, or is a heterocyclic radical of the benzimidazole, benzoxazole, benzthiazole or pyridine series, or R.sup.3 and R.sup.4, together with the linking nitrogen atom, are a pyrrolidine, imidazolidine, piperidine, piperazine or morpholine radical, or R.sup.3, R.sup.4 and R.sup.5, together with the linking nitrogen atom, are a pyrrole, pyridine, picoline, pyrazine, quinoline or isoquinoline radical, are most suitable for coloring high molecular organic material.

公开(公告)号：US4473500A

公开(公告)日：1984-09-25

申请号：US374120

申请日：1982-05-03

Applicant: Georg Cseh ,  Stefan Hari

Inventor： Georg Cseh ,  Stefan Hari

IPC: C09B29/09 ,  C09B29/00 ,  C09B29/20 ,  C09B29/33 ,  C09B29/036 ,  C09B29/32 ,  D06P1/44

CPC classification number: C09B29/337 ,  C09B29/0033 ,  C09B29/20

Abstract: Monoazo pigment compounds of the formula ##STR1## wherein X is a group of the formula ##STR2## R is hydrogen or methyl, R.sub.1 and R.sub.2 are hydrogen, chlorine, methyl or methoxy, Y is methyl or phenyl, or Y is --O, --S--, --N(R.sub.3)-- or --C(R.sub.4).dbd.CH--, each of which is bound on the ring A in the ortho-position with respect to the --NHCO-- group to form a benzoxazolone, benzothiazolone, benzimidazolone or quinolone-2, with R.sub.3 and R.sub.4 being hydrogen or methyl, and m and n independently of one another are each 1 or 2, are useful as high-grade pigments, for pigmenting high-molecular weight organic material. The pigments are distinguished in particular by good fastness to light, migration and weather.

Abstract translation: 其中X是下式的基团，其中X是氢或甲基，R 1和R 2是氢，氯，甲基或甲氧基，Y是甲基或苯基，或Y是-O， -S-，-N（R 3） - 或-C（R 4）= CH-，其各自相对于-NHCO-基团在邻位结合在环A上，形成苯并恶唑酮，苯并噻唑酮，苯并咪唑酮 或喹诺酮-2，其中R 3和R 4为氢或甲基，m和n彼此独立地为1或2，可用作高级颜料，用于着色高分子量有机材料。 颜料的特征是具有良好的耐光牢度，迁移性和耐候性。

公开(公告)号：US4070353A

公开(公告)日：1978-01-24

申请号：US655293

申请日：1976-02-04

Applicant: Georg Cseh ,  Karl Ronco

Inventor： Georg Cseh ,  Karl Ronco

IPC: C09B33/153 ,  C09B33/16

CPC classification number: C09B33/153

Abstract: Diazo pigments of the formula ##STR1## wherein R denotes an alkyl, cycloalkyl, aralkyl, aryl or heterocyclic radical, X denotes a hydrogen or halogen atom, an alkyl or alkoxy group containing 1 to 4 carbon atoms, or a nitro, cyano, trifluoromethyl or carboxylic acid ester group, and Y denotes a hydrogen or halogen atom, an alkyl or alkoxy group containing 1 to 4 carbon atoms or a nitro, cyano, trifluoromethyl or carboxylic acid ester group, are useful for coloring plastics and printing inks in fast yellow to orange shades.

Abstract translation: 其中R表示烷基，环烷基，芳烷基，芳基或杂环基，X表示氢或卤素原子，含有1至4个碳原子的烷基或烷氧基，或硝基，氰基，三氟甲基 或羧酸酯基，Y表示氢或卤素原子，含有1至4个碳原子的烷基或烷氧基或硝基，氰基，三氟甲基或羧酸酯基，可用于使快速黄色的塑料和印刷油墨着色 到橙色阴影。

公开(公告)号：US4062838A

公开(公告)日：1977-12-13

申请号：US686431

申请日：1976-05-14

Applicant: Georg Cseh ,  Stefan Hari

Inventor： Georg Cseh ,  Stefan Hari

IPC: C09B33/153 ,  C09B33/14

CPC classification number: C09B33/153

Abstract: Disazo pigments of the formula ##STR1## wherein A denotes a phenylene or naphthylene radical, R denotes an aryl, alkyl or alkenyl group optionally substituted by halogen atoms, by hydroxyl, alkoxy or alkylmercapto groups containing 1-6 C atoms, by alkoxycarbonyl groups containing 2-6 C atoms or cyano, aryl, aryloxy, arylmercapto or heterocyclic radicals, or denotes a heterocyclic radical, and the X and Y denote H atoms or substituents which do not confer solubility in water are useful for coloring plastics lacquers and printing inks in yellow to orange shade of good fastness properties.

Abstract translation: 其中A表示亚苯基或亚萘基，R表示任选被卤素原子取代的芳基，烷基或烯基，含1-6个碳原子的羟基，烷氧基或烷基巯基，通过含有 2-6个C原子或氰基，芳基，芳氧基，芳基巯基或杂环基，或表示杂环基，X和Y表示H原子或不赋予溶于水的取代基可用于着色塑料漆和印刷油墨 黄色至橙色，色牢度好。