Amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors
    1.
    发明申请
    Amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors 审中-公开
    N-(正丁基)硫代磷酸三酰胺(NBPT)和尿素肥料的氨基醇溶液使用尿素酶抑制剂

    公开(公告)号:US20100206031A1

    公开(公告)日:2010-08-19

    申请号:US12378499

    申请日:2009-02-17

    IPC分类号: C05C9/00 C09K3/00

    CPC分类号: C05C9/00 Y10S71/902 C05G3/08

    摘要: A method of producing reduced volatility of urea fertilizers comprising: dissolving N-(n-butyl)-thiophosphoric triamide (NBPT) in an amino alcohol having the formula 1 —(H)x—N—((CH2)m—OH)n where m is 1-3, x is 0 or 1, and n is 2 when x is 1 and 3 when x is 0: or the formula 2 —(H)y—N—((CH2)—CHOH—CH3)z such that the length of the carbon chain where the secondary hydroxyl group is located is 3, y is 0 or 1, and z is 2 when y is 1 and 3 when y is 0 to form an NBPT solution; and combining a urea fertilizer in granular or liquid form with the NBPT solution.

    摘要翻译: 一种生产尿素肥料的挥发性降低的方法,包括:将N-(正丁基) - 硫代磷酸三酰胺(NBPT)溶解在具有式1-(H)x-N - ((CH 2)m -OH)n 其中m为1-3,x为0或1,当x为1时n为2,x为0时n为2或式2 - (H)y -N - ((CH 2)-CHOH -CH 3)z 使得仲羟基所位于的碳链的长度为3,y为0或1,当y为1时z为2,当y为0时,z为3,形成NBPT溶液; 并将颗粒状或液态的尿素肥料与NBPT溶液混合。

    Phosphate coated urea
    2.
    发明授权
    Phosphate coated urea 失效
    磷酸盐涂层尿素

    公开(公告)号:US6030659A

    公开(公告)日:2000-02-29

    申请号:US85937

    申请日:1998-05-28

    IPC分类号: C05B17/00 C05C9/00 B05D7/00

    CPC分类号: C05B17/00 C05C9/00

    摘要: A method of coating urea by first wetting urea pellets with water or an aqueous acid solution, and then blended the wetted urea pellets with a phosphate salt. During the coating process, when using an aqueous acid solution, the acid liberates a portion of the phosphate to a form available to the plant, and reduces the loss of urea nitrogen due to volatilization.

    摘要翻译: 首先用水或酸水溶液润湿尿素颗粒,然后将润湿的尿素颗粒与磷酸盐混合来涂布尿素的方法。 在涂覆过程中,当使用酸性水溶液时,酸将磷酸盐的一部分释放到可用于植物的形式,并且由于挥发而减少尿素氮的损失。

    Buffered amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors
    3.
    发明授权
    Buffered amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors 有权
    N-(正丁基)硫代磷酸三酰胺(NBPT)和尿素肥料的缓冲氨基醇溶液,使用尿素酶抑制剂

    公开(公告)号:US08133294B2

    公开(公告)日:2012-03-13

    申请号:US13199534

    申请日:2011-09-01

    摘要: Reduced volatility of urea fertilizers are prepared in accordance with the present invention by first preparing an N-(n-butyl)-thiophosphoric triamide (NBPT) solution by dissolving NBPT in a mixture of an amino alcohol having the formula 1—(H)x—N—((CH2)m—OH)n where m is 1-3, x is 0 or 1, and n is 2 when x is 1 and 3 when x is 0: or the formula 2—(H)y—N—((CH2)—CHOH—CH3)z such that the length of the carbon chain where the secondary hydroxyl group is located is 3, y is 0 or 1, and z is 2 when y is 1 and 3 when y is 0, and a carboxylic acid having 6 or fewer carbon atoms. The solution is then combining with a urea fertilizer in granular or liquid form.

    摘要翻译: 通过首先通过将NBPT溶解在具有式1-(H)x的氨基醇的混合物中来制备N-(正丁基) - 硫代磷酸三酰胺(NBPT)溶液,从而制备尿素肥料的挥发性降低 -N - ((CH 2)m -OH)n,其中m为1-3,x为0或1,当x为1时n为2,x为0时n为3或式2-(H)y- N - ((CH 2)-CHOH-CH 3)z,使得仲羟基所位于的碳链的长度为3,y为0或1,当y为1时z为2,当y为0时,z为3 和碳原子数6以下的羧酸。 然后将溶液与颗粒状或液体形式的尿素肥料结合。

    Buffered amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors
    4.
    发明申请
    Buffered amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors 有权
    N-(正丁基)硫代磷酸三酰胺(NBPT)和尿素肥料的缓冲氨基醇溶液,使用尿素酶抑制剂

    公开(公告)号:US20110314883A1

    公开(公告)日:2011-12-29

    申请号:US13199534

    申请日:2011-09-01

    IPC分类号: C05C9/00

    摘要: Reduced volatility of urea fertilizers are prepared in accordance with the present invention by first preparing an N-(n-butyl)-thiophosphoric triamide (NBPT) solution by dissolving NBPT in a mixture of an amino alcohol having the formula 1—(H)x—N—((CH2)m—OH)n where m is 1-3, x is 0 or 1, and n is 2 when x is 1 and 3 when x is 0: or the formula 2—(H)y—N—((CH2)—CHOH—CH3)z such that the length of the carbon chain where the secondary hydroxyl group is located is 3, y is 0 or 1, and z is 2 when y is 1 and 3 when y is 0, and a carboxylic acid having 6 or fewer carbon atoms. The solution is then combining with a urea fertilizer in granular or liquid form.

    摘要翻译: 通过首先通过将NBPT溶解在具有式1-(H)x的氨基醇的混合物中来制备N-(正丁基) - 硫代磷酸三酰胺(NBPT)溶液,从而制备尿素肥料的挥发性降低 -N - ((CH 2)m -OH)n,其中m为1-3,x为0或1,当x为1时n为2,x为0时n为3或式2-(H)y- N - ((CH 2)-CHOH-CH 3)z,使得仲羟基所位于的碳链的长度为3,y为0或1,当y为1时z为2,当y为0时,z为3 和碳原子数6以下的羧酸。 然后将溶液与颗粒状或液体形式的尿素肥料结合。

    Amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors
    5.
    发明授权
    Amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors 有权
    N-(正丁基)硫代磷酸三酰胺(NBPT)和尿素肥料的氨基醇溶液使用尿素酶抑制剂

    公开(公告)号:US08163058B2

    公开(公告)日:2012-04-24

    申请号:US13135305

    申请日:2011-06-30

    CPC分类号: C05C9/00 Y10S71/902 C05G3/08

    摘要: A method of producing reduced volatility of urea fertilizers comprising: dissolving N-(n-butyl)-thiophosphoric triamide (NBPT) in an amino alcohol having the formula 1—(H)x—N—((CH2)m—OH)n where m is 1-3, x is 0 or 1, and n is 2 when x is 1 and 3 when x is 0: or the formula 2—(H)y—N—((CH2)—CHOH—CH3)z such that the length of the carbon chain where the secondary hydroxyl group is located is 3, y is 0 or 1, and z is 2 when y is 1 and 3 when y is 0 to form an NBPT solution; and combining a urea fertilizer in granular or liquid form with the NBPT solution.

    摘要翻译: 一种生产尿素肥料挥发性降低的方法,包括:将N-(正丁基) - 硫代磷酰三胺(NBPT)溶解在具有式1-(H)x-N - ((CH 2)m -OH)n 其中m为1-3,x为0或1,当x为1时n为2,当x为0时n为2或式2-(H)y -N - ((CH 2)-CHOH -CH 3)z 使得仲羟基所位于的碳链的长度为3,y为0或1,当y为1时z为2,当y为0时,z为3,形成NBPT溶液; 并将颗粒状或液态的尿素肥料与NBPT溶液混合。

    Buffered amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors
    6.
    发明申请
    Buffered amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors 有权
    N-(正丁基)硫代磷酸三酰胺(NBPT)和尿素肥料的缓冲氨基醇溶液,使用尿素酶抑制剂

    公开(公告)号:US20100206030A1

    公开(公告)日:2010-08-19

    申请号:US12378493

    申请日:2009-02-17

    IPC分类号: C05C9/00 C09K3/00

    摘要: Reduced volatility of urea fertilizers are prepared in accordance with the present invention by first preparing an N-(n-butyl)-thiophosphoric triamide (NBPT) solution by dissolving NBPT in a mixture of an amino alcohol having the formula 1—(H)x—N—((CH2)m—OH)n where m is 1-3, x is 0 or 1, and n is 2 when x is 1 and 3 when x is 0: or the formula 2—(H)y—N—((CH2)—CHOH—CH3)z such that the length of the carbon chain where the secondary hydroxyl group is located is 3, y is 0 or 1, and z is 2 when y is 1 and 3 when y is 0, and a carboxylic acid having 6 or fewer carbon atoms. The solution is then combining with a urea fertilizer in granular or liquid form.

    摘要翻译: 通过首先通过将NBPT溶解在具有式1-(H)x的氨基醇的混合物中来制备N-(正丁基) - 硫代磷酸三酰胺(NBPT)溶液来制备尿素肥料的挥发性降低 -N - ((CH 2)m -OH)n,其中m为1-3,x为0或1,当x为1时n为2,x为0时n为3或式2-(H)y- N - ((CH 2)-CHOH-CH 3)z,使得仲羟基所位于的碳链的长度为3,y为0或1,当y为1时z为2,当y为0时,z为3 和碳原子数6以下的羧酸。 然后将溶液与颗粒状或液体形式的尿素肥料结合。

    Process for making compounds containing chelated metal ions and
resultant products which are useful for agricultural, industrial,
environmental, and construction purposes
    7.
    发明授权
    Process for making compounds containing chelated metal ions and resultant products which are useful for agricultural, industrial, environmental, and construction purposes 失效
    制备含有螯合金属离子和所得产物的化合物的方法,其用于农业,工业,环境和建筑目的

    公开(公告)号:US4888421A

    公开(公告)日:1989-12-19

    申请号:US98317

    申请日:1987-09-18

    IPC分类号: C07C51/41

    CPC分类号: C07C51/418

    摘要: This invention discloses processes and resulting products for the manufacture of metal heptonates from saccharides via a Kiliani-Fisher reaction and subsequent reaction with the desired metal. Manganese, iron, copper zinc and magnesium heptonates are each made by a slightly different process but the resulting metal chelates provide a soluble form of the metal for agricultural, industrial, environmental and construction uses. The amount of metal chelated is directly related to the percentage of fructose in the initial monosaccharide mixture. For cations with no color, the chelating agent can be decolorized with H.sub.2 O.sub.2 to give a lighter colored product providing the NH.sub.3 concentration is reduced below 0.35% prior to the decolorizing step. An equivalent strong oxidizing agent may be used instead of H.sub.2 O.sub.2.

    摘要翻译: 本发明公开了通过Kiliani-Fisher反应和随后与期望的金属反应制备来自糖类的金属庚糖盐的方法和产生的产物。 锰,铁,铜锌和庚酮镁各自由稍微不同的方法制成,但所得到的金属螯合物为农业,工业,环境和建筑用途提供了可溶形式的金属。 金属螯合的量与初始单糖混合物中果糖的百分比直接相关。 对于没有颜色的阳离子,螯合剂可以用H 2 O 2脱色,得到较浅的产品,提供在脱色步骤之前NH 3浓度降低至0.35%以下。 可以使用等效的强氧化剂代替H 2 O 2。

    Volatility-inhibited urea fertilizers
    10.
    发明授权
    Volatility-inhibited urea fertilizers 有权
    挥发性抑制尿素肥料

    公开(公告)号:US06830603B2

    公开(公告)日:2004-12-14

    申请号:US10214751

    申请日:2002-08-07

    IPC分类号: C05C900

    CPC分类号: C05C9/00 C05G3/0041 C05G3/08

    摘要: Volatility-inhibited fertilizers are prepared by coating granular urea with a coating that includes a binding agent having a boron anion and a hydrogen bonding group to adhere the binding agent to the granular urea. The binding agent may be an amino alcohol borate in which the amino alcohol is selected from the group consisting of ethanolamine, diethanolamine, triethanolamine, and mixtures thereof, or a borate of an amino alcohol complex of a divalent metal. The borates are preferably prepared as an aqueous solution of the amino alcohol and boric acid, or the amino alcohol, a divalent metal salt, and boric acid, with the aqueous solution being applied to the urea granules. Additional plant nutrients may also be coated onto the urea granules.

    摘要翻译: 挥发性抑制肥料通过用包含具有硼阴离子和氢键基团的粘合剂的涂层涂覆颗粒尿来制备,以将结合剂粘附到颗粒状尿素上。 粘合剂可以是氨基醇硼酸盐,其中氨基醇选自乙醇胺,二乙醇胺,三乙醇胺及其混合物,或二价金属的氨基醇配合物的硼酸盐。 硼酸盐优选制备为氨基醇和硼酸或氨基醇,二价金属盐和硼酸的水溶液,其中水溶液被施加到尿素颗粒上。 另外的植物营养素也可以涂在尿素颗粒上。