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公开(公告)号:US11951465B2
公开(公告)日:2024-04-09
申请号:US16454709
申请日:2019-06-27
发明人: Xingcheng Xiao , Gongshin Qi , Ryan J. Day , Ming Yang
CPC分类号: B01J37/035 , B01J23/42 , B01J23/44 , B01J35/0013 , B01J35/0086 , B01J37/08 , B01J37/18
摘要: Catalyst systems that are resistant to high-temperature sintering and methods for preparing such catalyst systems that are resistant to sintering at high temperatures are provided. Methods of forming such catalyst systems include contacting a support having a surface including a catalyst particle with a solution comprising a metal salt and having an acidic pH. The metal salt is precipitated onto the surface of the support. Next, the metal salt is calcined to selectively generate a porous coating of metal oxide on the surface of the support distributed around the catalyst particle.
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公开(公告)号:US11376567B2
公开(公告)日:2022-07-05
申请号:US16704092
申请日:2019-12-05
发明人: Ming Yang , Se H. Oh , Gongshin Qi , Wei Li
IPC分类号: B01J21/04 , B01J23/10 , B01J23/46 , B01J23/63 , B01J23/72 , B01J23/83 , B01J35/10 , B01J37/02 , B01J37/03 , B01J37/10 , B01D53/94
摘要: Methods for preparing catalytic systems include passivating a gamma-phase alumina support body to yield a theta-phase alumina support body and applying catalytic metal to passivated theta-phase alumina support body. Passivating can include heating, optionally in the presence of steam. The gamma-phase alumina can be lanthanum-doped gamma-phase alumina and can be about 0.1-55 wt. % lanthanum. The catalytic metal can include rhodium, copper, or nickel. The catalytic metal can be rhodium or nickel, and the catalytic metal can be applied to the passivated theta-phase alumina support body at a loading of about 0.1-10 wt. %. The catalytic metal can be copper, and the catalytic metal can be applied to the passivated theta-phase alumina support body at a loading of about 0.1-30 wt. %. The gamma-phase alumina support body can be at least about 90 wt. % gamma-phase alumina. The passivated theta-phase alumina support body can be at least about 80 wt. % theta-phase alumina.
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公开(公告)号:US10596563B2
公开(公告)日:2020-03-24
申请号:US15418214
申请日:2017-01-27
发明人: Gongshin Qi , Ming Yang , Ryan J. Day , Xingcheng Xiao , Wei Li
IPC分类号: B01J37/02 , B01J35/00 , B01J23/63 , B01J23/83 , B01J21/04 , B01J23/44 , B01J35/04 , B01J37/00 , B01J37/03 , B01J37/08
摘要: Methods of preparing a sinter-resistant catalyst include forming a dual coating system. A surface of a particulate catalyst support contacts a first liquid precursor including a metal salt with an element selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), titanium (Ti), silicon (Si), magnesium (Mg), zinc (Zn), and combinations thereof. The first liquid precursor precipitates or is adsorbed as an ion on a portion of the surface forming a first coating including a porous metal oxide on the surface. The surface may be contacted with a second liquid precursor including a metal oxide sol including a metal selected from the group consisting of: aluminum (Al), cerium (Ce), zirconium (Zr), iron (Fe), titanium (Ti), silicon (Si), and combinations thereof. A second coating is formed from the second liquid precursor on a portion of the surface to create the sinter-resistant catalyst system.
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公开(公告)号:US20190371090A1
公开(公告)日:2019-12-05
申请号:US15995245
申请日:2018-06-01
发明人: Wen-Chiao Lin , Jingyan Wan , Jian Yao , Neeraj S. Shidore , Qiangfeng Xiao , Ming Yang , Paul E. Krajewski
摘要: Vehicles and methods are provided for monitoring the health of a substrate and a protective coating disposed on the substrate. A vehicle includes a substrate, a protective coating, a coating deformation sensor, and a controller. The protective coating is disposed overtop the substrate. The coating deformation sensor is operatively coupled with the protective coating and configured to measure a deformation value of the protective coating. The controller is configured to: determine a deformation recovery rate of the protective coating based on the deformation value; determine whether the deformation recovery rate corresponds with an expected recovery rate of the protective coating; and indicate that the protective coating may be impaired in response to determining that the deformation recovery rate does not correspond with the expected recovery rate.
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公开(公告)号:US10376872B2
公开(公告)日:2019-08-13
申请号:US15399179
申请日:2017-01-05
发明人: Xingcheng Xiao , Gongshin Qi , Ryan J. Day , Ming Yang
摘要: Catalyst systems that are resistant to high-temperature sintering and methods for preparing such catalyst systems that are resistant to sintering at high temperatures are provided. Methods of forming such catalyst systems include contacting a support having a surface including a catalyst particle with a solution comprising a metal salt and having an acidic pH. The metal salt is precipitated onto the surface of the support. Next, the metal salt is calcined to selectively generate a porous coating of metal oxide on the surface of the support distributed around the catalyst particle.
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公开(公告)号:US20180111111A1
公开(公告)日:2018-04-26
申请号:US15334164
申请日:2016-10-25
发明人: Ming Yang , Xingcheng Xiao , Ryan J. Day , Gongshin Qi
CPC分类号: B01J23/58 , B01D53/94 , B01J35/0006 , B01J35/0013 , B01J35/0086 , B01J37/0201 , B01J37/0236 , B01J37/024 , B01J37/08
摘要: A catalytic converter includes a catalyst. The catalyst includes a metal oxide support and platinum group metal (PGM) complexes atomically dispersed on the metal oxide support. The PGM complexes include a PGM species selected from the group consisting of an atom of a platinum group metal, a cluster including from 2 atoms to less than 10 atoms of the platinum group metal, a nanoparticle including 10 or more atoms of the platinum group metal, and combinations thereof. An alkali metal or an alkaline earth metal is bonded to the PGM species. The alkali or alkaline earth metal is part of a structure including oxygen atoms and hydrogen atoms. A barrier is disposed between a first PGM complex and a second PGM complex.
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公开(公告)号:US20180056276A1
公开(公告)日:2018-03-01
申请号:US15253039
申请日:2016-08-31
发明人: Xingcheng Xiao , Gongshin Qi , Ryan J. Day , Ming Yang
IPC分类号: B01J23/44 , B01J21/04 , B01J35/00 , B01J37/02 , B01J37/16 , B01J37/08 , F01N3/10 , B01D53/94 , F01N3/28
CPC分类号: B01J23/44 , B01D53/944 , B01D53/945 , B01D2255/1023 , B01D2255/9022 , B01J21/04 , B01J35/0006 , B01J35/0013 , B01J37/0201 , B01J37/0221 , B01J37/088 , B01J37/16 , F01N3/101 , F01N3/103 , F01N3/2825 , F01N2330/06 , F01N2370/02
摘要: A catalytic converter includes a catalyst. The catalyst includes a support, platinum group metal (PGM) particles dispersed on the support, and metal oxide nanoparticles formed on the support. The metal oxide nanoparticles are dispersed between a first set of the PGM particles and a second set of the PGM particles to suppress aging of the PGM particles.
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公开(公告)号:US10953366B2
公开(公告)日:2021-03-23
申请号:US15958020
申请日:2018-04-20
发明人: Ming Yang , Lei Wang , Shouxian Ren , Wei Li
IPC分类号: B01J23/02 , B01J29/068 , B01J37/00 , B01J37/02 , B01J37/08 , B01J37/30 , F01N3/08 , B01D53/94
摘要: A nitrogen oxides (NOx) and hydrocarbon (HC) storage catalyst for treating an exhaust gas flow is provided. The NOx and HC storage catalyst includes (a) a zeolite, (b) noble metal atoms, and (c) a metal oxide, a non-metal oxide, or a combination thereof. One or more of the noble metal atoms is present in a complex with the metal oxide, the non-metal oxide or a combination thereof. The complex is dispersed within a cage of the zeolite. Methods of preparing the NOx and HC storage catalyst and methods of using the NOx and HC storage catalyst for treating an exhaust gas stream flowing from a vehicle internal combustion engine during a period following a cold-start of the engine are also provided.
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公开(公告)号:US10926245B1
公开(公告)日:2021-02-23
申请号:US16547100
申请日:2019-08-21
发明人: Gongshin Qi , Wei Li , Se H. Oh , Ming Yang
摘要: The present disclosure provides a method for operating a three-way catalyst system at high temperatures. The method includes passing a high-temperature exhaust stream exiting an engine over a thermally stable three-way catalyst system including a metal oxide support; two or more catalytically active metals disposed on the support; and a porous metal oxide coating disposed on one or more exposed surfaces of the support. At least one of the catalytically active metals may be platinum (Pt). The method further includes reducing an amount of the nitrogen oxides (NOx), carbon monoxide (CO), and non-methane hydrocarbons (HCs) in an effluent stream exiting the thermally stable three-way catalyst system so that the effluent stream has a combined amount of nitrogen oxides (NOx) and non-methane hydrocarbons (HCs) of less than or equal to about 30 mg/mile and less than or equal to about 0.5 g/mile of carbon monoxide (CO).
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公开(公告)号:US20200047160A1
公开(公告)日:2020-02-13
申请号:US16056894
申请日:2018-08-07
发明人: Xingcheng Xiao , Ming Yang , Gongshin Qi , Wei Li
摘要: Methods for preparing a catalyst system, include providing a catalytic substrate comprising a catalyst support having a surface with a plurality of metal catalytic nanoparticles bound thereto and physically mixing and/or electrostatically combining the catalytic substrate with a plurality of oxide coating nanoparticles to provide a coating of oxide coating nanoparticles on the surface of the catalytic nanoparticles. The metal catalytic nanoparticles can be one or more of ruthenium, rhodium, palladium, osmium, iridium, and platinum, rhenium, copper, silver, and gold. Physically combining can include combining via ball milling, blending, acoustic mixing, or theta composition, and the oxide coating nanoparticles can include one or more oxides of aluminum, cerium, zirconium, titanium, silicon, magnesium, zinc, barium, lanthanum, iron, strontium, and calcium. The catalyst support can include one or more oxides of aluminum, cerium, zirconium, titanium, silicon, magnesium, zinc, barium, iron, strontium, and calcium.
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