Abstract:
An article for high temperature service is presented herein. One embodiment is an article including a substrate having a silicon-bearing ceramic matrix composite; and a layer disposed over the substrate, wherein the layer includes silicon and a dopant, the dopant including aluminum. In another embodiment, the article includes a ceramic matrix composite substrate, wherein the composite includes a silicon-bearing ceramic and a dopant, the dopant including aluminum; a bond coat disposed over the substrate, where the bond coat includes elemental silicon, a silicon alloy, a silicide, or combinations including any of the aforementioned; and a coating disposed over the bond coat, the coating including a silicate (such as an aluminosilicate or rare earth silicate), yttria-stabilized zirconia, or a combination including any of the aforementioned.
Abstract:
Articles suitable for use as high-temperature machine components include a substrate and an environmental barrier coating disposed over the substrate, where the environmental barrier coating includes at least one hermetic self-sealing layer formed from a mixture including an alkaline earth metal aluminosilicate and a rare-earth silicate, and where the at least one hermetic self-sealing layer exhibits substantially no net remnant or residual expansion when subjected to high temperature heat treatment. The environmental barrier coating can further include a bondcoat disposed between the substrate and the hermetic self-sealing layer, a topcoat disposed over the hermetic self-sealing layer, and/or an intermediate layer disposed between the hermetic self-sealing layer and the bondcoat. The intermediate layer can include a barrier material that is substantially inert with respect to silica.
Abstract:
Article includes a substrate, a bond coat disposed on the substrate, an environmental barrier coating disposed on the bond coat, and a patterned abradable coating disposed on the second top coat. The environmental barrier coating includes an intermediate layer disposed on the bond coat, a sealing layer disposed on the intermediate layer, a first top coat disposed on the sealing layer, and a second top coat disposed on the first top coat. The first top coat is different from the second top coat.
Abstract:
The present application provides for ceramic collars and metal rings for active brazing in sodium-based thermal batteries. The ceramic collar may be an alpha-alumina collar configured for active brazing, and thereby sealing, to outer and inner Ni rings for use in NaMx cells. The portions of the alpha-alumina collar active brazed to the outer and inner Ni rings may be outwardly facing and include inwardly extending recesses. The portions of the outer and inner Ni rings active brazed to the outwardly facing portions of the collar may be inwardly facing. The alpha-alumina collar may include a greater coefficient of thermal expansion than each of the outer and inner Ni rings, and the alpha-alumina collar and outer and inner Ni rings may be configured such that a portion of the outer and inner Ni rings is deformed into the inwardly extending recesses of the alpha-alumina collar after active brazing thereof.