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    Process for desulfurization comprising a stage for selective hydrogenation of diolefins and a stage for extraction of sulfur-containing compounds
    1.
    发明授权
    Process for desulfurization comprising a stage for selective hydrogenation of diolefins and a stage for extraction of sulfur-containing compounds 有权
    脱硫方法，包括二烯烃的选择性氢化阶段和萃取含硫化合物的阶段

    公开(公告)号：US07270737B2

    公开(公告)日：2007-09-18

    申请号：US10705868

    申请日：2003-11-13

    申请人： Florent Picard ,  Raphaël Huyghe

    发明人： Florent Picard ,  Raphaël Huyghe

    IPC分类号： C10G67/04

    CPC分类号： C10G67/04

    摘要： For desulfurization of a hydrocarbon-containing feedstock, at least one stage for selective hydrogenation of diolefins present in the initial hydrocarbon feedstock, in the presence of a catalyst of group VIII of the period table, and a stage for extraction by a solvent of the resultant hydrogenated fraction under conditions that provide at least two fractions: a raffinate that comprises for the most part olefins, paraffins and naphthenes and a reduced amount of sulfur-containing compounds that are contained in the initial feedstock, a fraction that contains the majority of the aromatic hydrocarbons and the majority of the sulfur-containing compounds contained in the initial feedstock.

    摘要翻译： 对于含烃原料的脱硫，存在于初始烃原料中的二烯烃的选择性氢化的至少一个阶段，在周期表的VIII族催化剂存在下，以及由所得到的溶剂萃取的阶段 在提供至少两个馏分的条件下的氢化馏分：包含大部分烯烃，链烷烃和环烷烃的萃余液和包含在初始原料中的减少量的含硫化合物，含有大部分芳族烃的馏分 碳氢化合物和包含在初始原料中的大部分含硫化合物。

    Process for desulphurizing gasoline by converting sulphur-containing compounds to higher boiling point compounds
    2.
    发明授权
    Process for desulphurizing gasoline by converting sulphur-containing compounds to higher boiling point compounds 有权
    通过将含硫化合物转化为高沸点化合物来脱硫汽油的方法

    公开(公告)号：US07504022B2

    公开(公告)日：2009-03-17

    申请号：US11405676

    申请日：2006-04-18

    申请人： Florent Picard

    发明人： Florent Picard

    IPC分类号： C10G25/05 ,  C07C2/54

    CPC分类号： C10G17/095 ,  C10G25/05

    摘要： A process for desulphurizing a gasoline cut containing olefins, sulphur-containing compounds and optionally molecules belonging to C3 and C4 cuts comprises at least a first step A for contacting said gasoline cut with an acidic resin having an acid capacity of more than 4.7 equivalents per kg and a specific surface area of less than 55 m2/g, and a second step B for fractionation of the mixture from the first step.

    摘要翻译： 含有烯烃，含硫化合物和任选地分别属于C3和C4馏分的汽油馏分的脱硫方法包括至少第一步骤A，用于使所述汽油馏分与酸容量大于4.7当量/ kg的酸性树脂接触 比表面积小于55m2 / g，第二步骤B从第一步骤中分离出混合物。

    Integral method for desulphurization of a hydrocarbon cracking or stream cracking effluent
    4.
    发明授权
    Integral method for desulphurization of a hydrocarbon cracking or stream cracking effluent 失效
    烃裂化或流裂解流出物脱硫的整体方法

    公开(公告)号：US07344635B2

    公开(公告)日：2008-03-18

    申请号：US10503807

    申请日：2003-01-22

    申请人： Patrick Briot ,  Pierre Boucot ,  Alain Forestiere ,  Nathalie Marchal-George ,  Florent Picard

    发明人： Patrick Briot ,  Pierre Boucot ,  Alain Forestiere ,  Nathalie Marchal-George ,  Florent Picard

    IPC分类号： C10G45/02

    CPC分类号： C10G69/123 ,  C10G29/205

    摘要： Process for desulfurization of an effluent for cracking or steam-cracking hydrocarbons, more particularly a gasoline for example for catalytic cracking that comprises the elimination of thiophenic compounds by alkylation of these compounds, followed by a distillation, a hydrocracking of said alkyl-thiophenic compounds, then a hydrodesulfurization of the effluent that is obtained from the hydrocracking zone. In a preferred embodiment, this process comprises a preliminary stage for separating the cracking or steam-cracking effluent into three fractions, and proposes sending to the alkylation stage only the intermediate fraction that is low in heavy basic nitrogen-containing compounds that are initially present in the effluents that are to be alkylated.

    摘要翻译： 用于裂化或蒸汽裂解烃的流出物的脱硫方法，更具体地，例如用于催化裂解的汽油，其包括通过这些化合物的烷基化除去噻吩化合物，然后蒸馏，所述烷基 - 噻吩化合物的加氢裂化， 然后从加氢裂化区获得的流出物的加氢脱硫。 在优选的实施方案中，该方法包括用于将裂化或蒸汽裂解流出物分离成三个馏分的初步阶段，并且建议仅向最初存在于重质碱性含氮化合物中的低碱性含氮化合物的中间馏分 待烷基化的废水。

    Selective hydrogenation process employing a catalyst having a controlled porosity
    6.
    发明申请
    Selective hydrogenation process employing a catalyst having a controlled porosity 有权
    选择性氢化方法采用具有受控孔隙率的催化剂

    公开(公告)号：US20070170098A1

    公开(公告)日：2007-07-26

    申请号：US11642976

    申请日：2006-12-21

    申请人： Christophe Bouchy ,  Florent Picard ,  Nathalie Marchal

    发明人： Christophe Bouchy ,  Florent Picard ,  Nathalie Marchal

    IPC分类号： C10G29/00

    CPC分类号： B01J35/10 ,  B01J23/85 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/108 ,  B01J37/20 ,  C10G45/38 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/4018

    摘要： A process for jointly carrying out selective hydrogenation of polyunsaturated compounds into monounsaturated compounds contained in gasolines, and for transforming light sulphur-containing compounds into heavier compounds by reaction with unsaturated compounds employing a supported catalyst, comprising at least one metal from group VIB and at least one non-noble metal from group VIII used in the sulphurized form deposited on a support and having a controlled porosity, and comprising bringing the feed into contact with the catalyst at a temperature in the range of 80° C. to 220° C. at a liquid hourly space velocity in the range of 1 h−1 to 10 h−1 and at a pressure in the range of 0.5 to 5 MPa.

    摘要翻译： 一种将多不饱和化合物选择氢化成汽油中所含的单不饱和化合物的方法，以及使用负载型催化剂与不饱和化合物反应，将轻含硫化合物转化为较重的化合物的方法，所述催化剂包含至少一种来自VIB族的金属，至少 用于硫化形式的第VIII族的一种非贵金属沉积在载体上并具有受控的孔隙率，并且包括使进料在80℃至220℃的温度范围内与催化剂接触 在1小时-1小时至10小时-1的范围内的液时空速和0.5-5MPa的压力。

    Process for hydrodesulphurizing gasoline employing a catalyst with controlled porosity
    9.
    发明授权
    Process for hydrodesulphurizing gasoline employing a catalyst with controlled porosity 有权
    使用具有受控孔隙率的催化剂加氢脱硫汽油的方法

    公开(公告)号：US08926831B2

    公开(公告)日：2015-01-06

    申请号：US13305527

    申请日：2011-11-28

    申请人： Christophe Bouchy ,  Nathalie Marchal ,  Florent Picard

    发明人： Christophe Bouchy ,  Nathalie Marchal ,  Florent Picard

    IPC分类号： C10G65/04 ,  C10G45/04 ,  C10G45/08

    CPC分类号： C10G45/04 ,  C10G45/08 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2400/02

    摘要： A novel process is described which allows selective hydrodesulphurizing gasoline cuts containing sulphur-containing compounds and olefins. The process employs a catalyst comprising a support selected, for example, from refractory oxides such as aluminas, silicas, silica-aluminas or magnesia, used alone or as a mixture, a group VI metal, preferably Mo or W which may or may not be promoted by a group VIII metal, Co or Ni. The catalyst is characterized by a mean pore diameter of more than 22 nm. The process may comprise one or more steps.

    摘要翻译： 描述了允许选择性加氢脱硫含有含硫化合物和烯烃的汽油馏分的新方法。 该方法使用包含选自例如单独使用或作为混合物使用的难熔氧化物如氧化铝，二氧化硅，二氧化硅 - 氧化铝或氧化镁的载体的载体的催化剂，VI族金属，优选Mo或W，其可以是或可以不是 由VIII族金属，Co或Ni促进。 催化剂的特征在于平均孔径大于22nm。 该过程可以包括一个或多个步骤。

    Process for the hydrotreatment of an olefinic gasoline comprising a selective hydrogenation stage
    10.
    发明授权
    Process for the hydrotreatment of an olefinic gasoline comprising a selective hydrogenation stage 有权
    包含选择性氢化阶段的烯烃汽油的加氢处理方法

    公开(公告)号：US07550636B2

    公开(公告)日：2009-06-23

    申请号：US11286297

    申请日：2005-11-25

    申请人： Florent Picard ,  Sebastien Leplat

    发明人： Florent Picard ,  Sebastien Leplat

    IPC分类号： C07C7/163 ,  C10G45/00

    CPC分类号： C10G45/36 ,  C10G45/02 ,  C10G45/38 ,  C10G65/06 ,  C10G2300/104 ,  C10G2300/202 ,  C10G2300/4018

    摘要： The invention relates to a process for the hydrotreatment of an olefinic gasoline comprising at least one selective hydrogenation stage, and generally of simultaneous conversion of mercaptans by weight increase, in which the makeup hydrogen used in this stage or these stages has a reduced CO+CO2 content, preferably comprised between 5 and 200 ppmv. Most often, the CO content is comprised between 1 and 20 ppmv. The process typically makes it possible to hydrorefine an olefinic gasoline by more or less eliminating the diolefins and sulphur compounds.

    摘要翻译： 本发明涉及一种用于加氢处理烯烃汽油的方法，该方法包括至少一个选择性氢化阶段，通常同时通过重量增加转化硫醇，其中在该阶段或这些阶段中使用的补充氢具有减少的CO + CO 2 含量，优选在5和200ppmv之间。 通常，CO含量在1和20ppmv之间。 该方法通常使得可以通过或多或少地消除二烯烃和硫化合物来加氢精制烯烃汽油。