公开(公告)号：US20150025291A1

公开(公告)日：2015-01-22

申请号：US14371386

申请日：2012-12-27

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Simon C. Weston ,  Karl G. Strohmaier ,  Hilda B. Vroman

IPC: B01J29/70 ,  C07C5/22 ,  C07C4/06 ,  C07C2/00 ,  C01B39/48 ,  C07C6/00

CPC classification number: C01B39/48 ,  B01J29/70 ,  B01J37/0018 ,  C01B37/007 ,  C01B37/02 ,  C01B39/08 ,  C01P2002/72 ,  C07C2/00 ,  C07C4/06 ,  C07C5/222 ,  C07C6/00 ,  C07C2529/70 ,  C10G11/05 ,  C10G47/04 ,  C10G47/16

Abstract: A molecular sieve material, EMM-17, has in its as-calcined form an X-ray diffraction pattern including the following peaks in Table 11: TABLE 11 d-spacingRelative Intensity (Å)[100 × I/I(o)] % 17.4-16.41-10 12.6-12.11-20 11.8-11.460-100 11.2-10.85-30 10.7-10.330-80  8.62-8.3810-40  6.09-5.961-20 5.71-5.611-20 4.23-4.171-20 4.09-4.031-10 3.952-3.90110-40  3.857-3.8095-30 3.751-3.7051-20 3.727-3.6821-20 3.689-3.6441-10 3.547-3.5061-20

Abstract translation: 分子筛材料EMM-17具有其煅烧形式的X射线衍射图，其包括表11中的以下峰：表11 d-间隔相对强度（）[100×I / I（o）] ％17.4-16.4 1-10 12.6-12.1 1-20 11.8-11.4 60-100 11.2-10.8 5-30 10.7-10.3 30-80 8.62-8.38 10-40 6.09-5.96 1-20 5.71-5.61 1-20 4.23 -4.17 1-20 4.09-4.03 1-10 3.952-3.901 10-40 3.857-3.809 5-30 3.751-3.705 1-20 3.727-3.682 1-20 3.689-3.644 1-10 3.547-3.506 1-20

公开(公告)号：US20160368778A1

公开(公告)日：2016-12-22

申请号：US15251454

申请日：2016-08-30

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Simon C. Weston ,  Karl G. Strohmaier ,  Hilda B. Vroman

IPC: C01B39/48 ,  B01J37/00 ,  C10G47/04 ,  C07C6/00 ,  C07C2/00 ,  C07C4/06 ,  C07C5/22 ,  B01J29/70 ,  C10G11/05

CPC classification number: C01B39/48 ,  B01J29/70 ,  B01J37/0018 ,  C01B37/007 ,  C01B37/02 ,  C01B39/08 ,  C01P2002/72 ,  C07C2/00 ,  C07C4/06 ,  C07C5/222 ,  C07C6/00 ,  C07C2529/70 ,  C10G11/05 ,  C10G47/04 ,  C10G47/16

Abstract: A molecular sieve material, EMM-17, has in its as-calcined form an X-ray diffraction pattern including the following peaks in Table 11: TABLE 11 Relative Intensity d-spacing (Å)[100 × I/I(ο)] %  17.4-16.4 1-10  12.6-12.1 1-20  11.8-11.460-100  11.2-10.8 5-30  10.7-10.330-80  8.62-8.3810-40  6.09-5.96 1-20  5.71-5.61 1-20  4.23-4.17 1-20  4.09-4.03 1-10 3.952-3.90110-40 3.857-3.809 5-30 3.751-3.705 1-20 3.727-3.682 1-20 3.689-3.644 1-10 3.547-3.506 1-20

公开(公告)号：US20150137392A1

公开(公告)日：2015-05-21

申请号：US14391498

申请日：2013-04-05

Applicant: Exxonmobil Chemical Patents Inc.

Inventor： Allen W. Burton ,  Hilda B. Vroman

IPC: B01J37/08 ,  B01J29/70 ,  C01B39/48

CPC classification number: B01J29/70 ,  B01J35/002 ,  B01J35/023 ,  B01J37/082 ,  C01B39/48

Abstract: ZSM-18 is synthesized from a mixture comprising water, a source of an oxide of a tetravalent element (Y), a source of an oxide of a trivalent element (X), a source of a first cation Q selected from either butamethonium cations or N,N,N,-trimethyl-N-butylammonium cations and a source of at least one second cation M, wherein the second cation M is selected from lithium, strontium, sodium, tetraalkylammonium and mixtures thereof when the first cation, Q is butamethonium cations, and wherein the second cation M is tetramethylammonium when the first cation Q is N,N,N,-trimethyl-N-butylammonium cations.

Abstract translation: ZSM-18由包含水，四价元素（Y）的氧化物源，三价元素（X）的氧化物源，选自丁酸铵阳离子的第一阳离子Q的源或 N，N，N， - 三甲基-N-丁基铵阳离子和至少一个第二阳离子M的源，其中当第一阳离子Q是对甲基铵时，第二阳离子M选自锂，锶，钠，四烷基铵及其混合物 阳离子，当第一阳离子Q为N，N，N'-三甲基-N-丁基铵阳离子时，第二阳离子M为四甲基铵。

公开(公告)号：US09452424B2

公开(公告)日：2016-09-27

申请号：US14931347

申请日：2015-11-03

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Allen W. Burton ,  Hilda B. Vroman

IPC: B01J29/70 ,  C01B39/48 ,  B01J35/00 ,  B01J35/02 ,  B01J37/08

CPC classification number: B01J29/70 ,  B01J35/002 ,  B01J35/023 ,  B01J37/082 ,  C01B39/48

Abstract: ZSM-18 is synthesized from a mixture comprising water, a source of an oxide of a tetravalent element (Y), a source of an oxide of a trivalent element (X), a source of a first cation Q selected from either butamethonium cations or N,N,N,-trimethyl-N-butylammonium cations and a source of at least one second cation M, wherein the second cation M is selected from lithium, strontium, sodium, tetraalkylammonium and mixtures thereof when the first cation, Q is butamethonium cations, and wherein the second cation M is tetramethylammonium when the first cation Q is N,N,N,-trimethyl-N-butylammonium cations.

公开(公告)号：US20160051973A1

公开(公告)日：2016-02-25

申请号：US14931347

申请日：2015-11-03

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Allen W. Burton ,  Hilda B. Vroman

IPC: B01J29/70

CPC classification number: B01J29/70 ,  B01J35/002 ,  B01J35/023 ,  B01J37/082 ,  C01B39/48

Abstract: ZSM-18 is synthesized from a mixture comprising water, a source of an oxide of a tetravalent element (Y), a source of an oxide of a trivalent element (X), a source of a first cation Q selected from either butamethonium cations or N,N,N,-trimethyl-N-butylammonium cations and a source of at least one second cation M, wherein the second cation M is selected from lithium, strontium, sodium, tetraalkylammonium and mixtures thereof when the first cation, Q is butamethonium cations, and wherein the second cation M is tetramethylammonium when the first cation Q is N,N,N,-trimethyl-N-butylammonium cations.

公开(公告)号：US09682945B2

公开(公告)日：2017-06-20

申请号：US14918968

申请日：2015-10-21

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Allen W. Burton ,  Karl G. Strohmaier ,  Hilda B. Vroman

IPC: C07D295/037 ,  B01J29/86 ,  B01J29/87 ,  B01J29/89 ,  C01B37/00 ,  C01B37/02 ,  C01B39/48 ,  B01J29/70 ,  B01J35/00

CPC classification number: C07D295/037 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/86 ,  B01J29/87 ,  B01J29/89 ,  B01J35/002 ,  C01B37/00 ,  C01B37/02 ,  C01B39/48

Abstract: A new molecular sieve material is designated as EMM-23 and has, in its as-calcined form, an X-ray diffraction pattern including the following peaks in Table 1: TABLE 1 d-spacing (Å)Relative Intensity [100 × I/I(o)] 17.5-16.360-100 10.6-10.15-50 9.99-9.5620-70  6.23-6.061-10 5.84-5.691-10 5.54-5.401-10 4.29-4.211-10 3.932-3.8641-10 3.766-3.7045-40 3.735-3.6741-10 3.657-3.5981-10 3.595-3.5391-20

公开(公告)号：US20160090308A1

公开(公告)日：2016-03-31

申请号：US14891537

申请日：2014-05-05

Applicant: EXXONMOBIL CHEMICAL PATENTS INC.

Inventor： Simon C. Weston ,  Hilda B. Vroman ,  Karl G. Strohmaier

IPC: C01B39/04 ,  C07C2/02 ,  C01B39/48

CPC classification number: C01B39/04 ,  B01J29/7026 ,  B01J35/002 ,  C01B39/48 ,  C07C2/02 ,  C07C2529/70 ,  C10G50/00

Abstract: The invention relates to a process for preparing molecular sieves, such as ZSM-57, using one or more structure directing agents selected from the group consisting of N1,N1,N5,N5-tetraethyl-N1,N5-dimethylpentane-1,5-diamininum, 1-ethyl-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)piperidin-1-ium, 1,1′-(hexane-1,6-diyl)bis(1-ethylpiperidin-1-ium), and 1,1-diethylpyrrolidin-1-ium.

Abstract translation: 本发明涉及一种使用一种或多种选自N1，N1，N5，N5-四乙基-N1，N5-二甲基戊烷-1,5-二醇的结构定向剂制备分子筛的方法，例如ZSM-57， 二胺，1-乙基-1-（5-（1-甲基哌啶-1-基）-1-戊基）哌啶-1-基，1,1' - （己烷-1,6-二基）双（1- 乙基哌啶-1-基）和1,1-二乙基吡咯烷-1-酮。

公开(公告)号：US20160039779A1

公开(公告)日：2016-02-11

申请号：US14918968

申请日：2015-10-21

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Allen W. Burton ,  Karl G. Strohmaier ,  Hilda B. Vroman

IPC: C07D295/037 ,  C01B39/48

CPC classification number: C07D295/037 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/86 ,  B01J29/87 ,  B01J29/89 ,  B01J35/002 ,  C01B37/00 ,  C01B37/02 ,  C01B39/48

Abstract: A new molecular sieve material is designated as EMM-23 and has, in its as-calcined form, an X-ray diffraction pattern including the following peaks in Table 1: TABLE 1 d-spacing (Å)Relative Intensity [100 × I/I(o)] 17.5-16.360-100 10.6-10.15-50 9.99-9.5620-70  6.23-6.061-10 5.84-5.691-10 5.54-5.401-10 4.29-4.211-10 3.932-3.8641-10 3.766-3.7045-40 3.735-3.6741-10 3.657-3.5981-10 3.595-3.5391-20

Abstract translation: 一种新的分子筛材料被命名为EMM-23，并以其煅烧形式具有包括表1中以下峰的X射线衍射图：表1 d-间距（Å）相对强度[100×I / I（o）] 17.5-16.3 60-100 10.6-10.1 5-50 9.99-9.56 20-70 6.23-6.06 1-10 5.84-5.69 1-10 5.54-5.40 1-10 4.29-4.21 1-10 3.932-3.864 1-10 3.766-3.704 5-40 3.735-3.674 1-10 3.657-3.598 1-10 3.595-3.539 1-20

公开(公告)号：US09205421B2

公开(公告)日：2015-12-08

申请号：US14391498

申请日：2013-04-05

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Allen W. Burton ,  Hilda B. Vroman

IPC: B01J37/08 ,  B01J29/70 ,  C01B39/48 ,  B01J35/00 ,  B01J35/02

CPC classification number: B01J29/70 ,  B01J35/002 ,  B01J35/023 ,  B01J37/082 ,  C01B39/48

Abstract: ZSM-18 is synthesized from a mixture comprising water, a source of an oxide of a tetravalent element (Y), a source of an oxide of a trivalent element (X), a source of a first cation Q selected from either butamethonium cations or N,N,N,-trimethyl-N-butylammonium cations and a source of at least one second cation M, wherein the second cation M is selected from lithium, strontium, sodium, tetraalkylammonium and mixtures thereof when the first cation, Q is butamethonium cations, and wherein the second cation M is tetramethylammonium when the first cation Q is N,N,N,-trimethyl-N-butylammonium cations.

Abstract translation: ZSM-18由包含水，四价元素（Y）的氧化物源，三价元素（X）的氧化物源，选自丁酸铵阳离子的第一阳离子Q的源或 N，N，N， - 三甲基-N-丁基铵阳离子和至少一个第二阳离子M的源，其中当第一阳离子Q是对甲基铵时，第二阳离子M选自锂，锶，钠，四烷基铵及其混合物 阳离子，当第一阳离子Q为N，N，N'-三甲基-N-丁基铵阳离子时，第二阳离子M为四甲基铵。

公开(公告)号：US09890050B2

公开(公告)日：2018-02-13

申请号：US15251454

申请日：2016-08-30

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Simon C. Weston ,  Karl G. Strohmaier ,  Hilda B. Vroman

IPC: C01B39/48 ,  B01J29/70 ,  C07C6/00 ,  C07C4/06 ,  C07C2/00 ,  C01B37/00 ,  C01B37/02 ,  C01B39/08 ,  C07C5/22 ,  B01J37/00 ,  C10G11/05 ,  C10G47/04 ,  C10G47/16

CPC classification number: C01B39/48 ,  B01J29/70 ,  B01J37/0018 ,  C01B37/007 ,  C01B37/02 ,  C01B39/08 ,  C01P2002/72 ,  C07C2/00 ,  C07C4/06 ,  C07C5/222 ,  C07C6/00 ,  C07C2529/70 ,  C10G11/05 ,  C10G47/04 ,  C10G47/16

Abstract: A molecular sieve material, EMM-17, has in its as-calcined form an X-ray diffraction pattern including the following peaks in Table 11: TABLE 11 Relative Intensity d-spacing (Å)[100 × I/I(ο)] % 17.4-16.41-10 12.6-12.11-20 11.8-11.460-100 11.2-10.85-30 10.7-10.330-80  8.62-8.3810-40  6.09-5.961-20 5.71-5.611-20 4.23-4.171-20 4.09-4.031-10 3.952-3.90110-40  3.857-3.8095-30 3.751-3.7051-20 3.727-3.6821-20 3.689-3.6441-10 3.547-3.506 1-20.