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公开(公告)号:US20220282091A1
公开(公告)日:2022-09-08
申请号:US17632702
申请日:2020-08-10
Applicant: ExxonMobil Research and Engineering Company
Inventor: Yunlong Zhang , Jordan N. Metz , Huaxing Zhou , August W. Bosse , Suzzy C. Ho , Timothy D. Shaffer , Ozcan Altintas
Abstract: Processes for chemically treating polyaromatic feedstock to form aromatic-containing oligomers or polymers are provided. The processes are characterized by treatment of a plurality of different polyaromatic hydrocarbon molecules and/or polyheterocyclic molecules present in polyaromatic feedstock with a first reagent so as to functionalize the molecules. Further treatment in a second step affords oligomeric or polymeric products which may be crosslinked. The products may be thermoplastic or thermoset materials and may find use in, for example, infrastructure applications, composites, fillers, fire retardants and 3-D printing materials.
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公开(公告)号:US10926226B2
公开(公告)日:2021-02-23
申请号:US16295918
申请日:2019-03-07
Inventor: Nicholas Bruno , Ronita Mathias , Yao Ma , Kirstie Thompson , Breanne Hamlett , Ryan P. Lively , Huaxing Zhou , M. G. Finn , Dhaval Bhandari , Craig McKay , Melinda Jue
IPC: B01D67/00 , B01D71/82 , B01J31/04 , C08J3/24 , B01D69/08 , C07D221/20 , C07D311/96 , C07D471/10 , C07D487/10 , C08G65/26
Abstract: The present invention is directed to methods of fabricating novel cross-linked membranes and to cross-linked membranes produced by the disclosed methods. Specifically, methods of fabricating cross-linked membranes according to the present invention may comprise direct crosslinking, crosslinking by addition of a small molecule, interfacial crosslinking of free-standing film, and interfacial crosslinking on a solid support.
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3.
公开(公告)号:US20200346196A1
公开(公告)日:2020-11-05
申请号:US16848536
申请日:2020-04-14
Applicant: ExxonMobil Research and Engineering Company
Inventor: Huaxing Zhou , Victor DeFlorio
Abstract: The present disclosure relates to catalysts for making sulfur-containing polymeric materials. In particular, the disclosure provides catalysts, and the method of using the same, for making sulfur-containing polymeric materials through inverse vulcanization at a temperature that is lower than 150° C.
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公开(公告)号:US20190275469A1
公开(公告)日:2019-09-12
申请号:US16295918
申请日:2019-03-07
Inventor: Nicholas Bruno , Ronita Mathias, VIII , Yao Ma , Kirstie Thompson , Breanne Hamlett , Ryan P. Lively , Huaxing Zhou , M.G. Finn , Dhaval Bhandari , Craig McKay , Melinda Jue
Abstract: The present invention is directed to methods of fabricating novel cross-linked membranes and to cross-linked membranes produced by the disclosed methods. Specifically, methods of fabricating cross-linked membranes according to the present invention may comprise direct crosslinking, crosslinking by addition of a small molecule, interfacial crosslinking of free-standing film, and interfacial crosslinking on a solid support.
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公开(公告)号:US20190315912A1
公开(公告)日:2019-10-17
申请号:US16362984
申请日:2019-03-25
Applicant: ExxonMobil Research and Engineering Company
Inventor: Huaxing Zhou , Arnold Lustiger , Victor DeFlorio , Srinivasan Rajagopalan , Timothy D. Shaffer , Donald N. Schulz
Abstract: The present disclosure relates to methods for preparing materials from heavy feedstocks. In particular, the disclosure provides a chemical process to convert heavy feedstocks with predominant polyaromatic hydrocarbon molecules or species, including the residues of petrochemical refining or extraction, into thermoset or thermoplastic materials that can be used alone or as a component in a composite material.
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6.
公开(公告)号:US20190276952A1
公开(公告)日:2019-09-12
申请号:US16295690
申请日:2019-03-07
Applicant: ExxonMobil Research and Engineering Company
Inventor: David O. Marler , Srinivasan Rajagopalan , Dhaval Bhandari , Huaxing Zhou , M. G. Finn
Abstract: The present disclosure relates to methods for using functional molecules and other structural carbon-based molecules with rigid backbones and kinked segments to alter the interactions between molecules, and consequently improve/modify the properties of materials. In particular, the disclosure provides methods for using functional molecules and other structural carbon-based molecules with rigid backbones and kinked segments as (1) precursors for carbon fiber, (2) “molecular agents” to separate and/or link π-π stacked aromatic systems, 3) stabilizers in composite materials to achieve better blending of matrix with fiber reinforcement, and/or (4) one of the components in carbon fibers to achieve better mechanical properties.
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公开(公告)号:US20190194414A1
公开(公告)日:2019-06-27
申请号:US16190433
申请日:2018-11-14
Applicant: ExxonMobil Research and Engineering Company
Inventor: Huaxing Zhou , Quanchang Li , David C. Calabro
CPC classification number: C08J9/28 , B01J20/103 , B01J20/262 , B01J20/28045 , B01J20/28057 , B01J20/28059 , B01J20/28061 , B01J20/28064 , B01J20/28066 , B01J20/28071 , B01J20/28073 , B01J20/28076 , B01J20/28083 , B01J20/28092 , B01J20/305 , B01J20/3085 , B01J31/127 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/109 , B01J37/04 , B01J37/10 , B01J2231/005 , B01J2531/002 , C01B33/12 , C01B37/02 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C08J2201/0504 , C08J2383/04
Abstract: Methods of preparing organosilica materials using a starting material mixture comprising at least one compound of Formula [(RO)2SiCH2]3 (Ia) and at least one compound of Formula [R′ROSiCH2]3 (Ib), wherein each R′ independently represents an RO—, an R group, or an (RO)3Si—CH2— group, at least one R′ being (RO)3Si—CH2—; and R represents a C1-C4 alkyl group, in the absence of a structure directing agent and/or porogen are provided herein. Processes of using the organosilica materials, e.g., for gas separation, etc., are also provided herein.
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公开(公告)号:US11111352B2
公开(公告)日:2021-09-07
申请号:US16190433
申请日:2018-11-14
Applicant: ExxonMobil Research and Engineering Company
Inventor: Huaxing Zhou , Quanchang Li , David C. Calabro
IPC: B01J20/10 , C08J9/28 , B01J20/28 , B01J20/30 , B01J31/12 , B01J35/10 , B01J37/04 , B01J37/10 , B01J20/26 , C01B33/12 , C01B37/02
Abstract: Methods of preparing organosilica materials using a starting material mixture comprising at least one compound of Formula [(RO)2SiCH2]3 (Ia) and at least one compound of Formula [R′ROSiCH2]3 (Ib), wherein each R′ independently represents an RO—, an R group, or an (RO)3Si—CH2— group, at least one R′ being (RO)3Si—CH2—; and R represents a C1-C4 alkyl group, in the absence of a structure directing agent and/or porogen are provided herein. Processes of using the organosilica materials, e.g., for gas separation, etc., are also provided herein.
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公开(公告)号:US11059941B2
公开(公告)日:2021-07-13
申请号:US16362984
申请日:2019-03-25
Applicant: ExxonMobil Research and Engineering Company
Inventor: Huaxing Zhou , Arnold Lustiger , Victor DeFlorio , Srinivasan Rajagopalan , Timothy D. Shaffer , Donald N. Schulz
Abstract: The present disclosure relates to methods for preparing materials from heavy feedstocks. In particular, the disclosure provides a chemical process to convert heavy feedstocks with predominant polyaromatic hydrocarbon molecules or species, including the residues of petrochemical refining or extraction, into thermoset or thermoplastic materials that can be used alone or as a component in a composite material.
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公开(公告)号:US10953369B2
公开(公告)日:2021-03-23
申请号:US16295910
申请日:2019-03-07
Inventor: M. G. Finn , Craig McKay , Nicholas Bruno , Kirstie Thompson , Huaxing Zhou
IPC: C07D221/20 , C07D311/96 , C07D471/10 , C07D487/10 , B01D67/00 , B01D71/82 , C08J3/24 , C08G65/26 , B01D69/08 , B01J31/04
Abstract: The present invention is directed to novel functionalized spirocentric compounds and polymers thereof that produce hyper-rigid cross-linked membranes.
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