公开(公告)号：US20170158902A1

公开(公告)日：2017-06-08

申请号：US15366100

申请日：2016-12-01

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Brian R. Einsla ,  Valeriy V. Ginzburg ,  Lanfang Li ,  John A. Roper, III ,  Rebecca Smith ,  Jian Yang

IPC: C09D125/14 ,  D21H19/58 ,  C09D7/12

CPC classification number: C09D125/14 ,  B41M5/44 ,  B41M2205/04 ,  B41M2205/38 ,  C08L2207/53 ,  C09D7/65 ,  C09D7/68 ,  C09D7/69 ,  C09D7/70 ,  D21H15/10 ,  D21H19/58 ,  G03C1/79

Abstract: The present invention relates to a coating composition comprising an aqueous dispersion of a binder and first and second core-shell polymer particles having aqueous neutralized acid cores, wherein the first core-shell polymer particles have a diameter in the range of from 1.0 μm to 1.8 μm; the second core-shell polymer particles have a diameter in the range of from 0.25 μm to 1.0 μm; the number ratio of the second to the first core-shell polymer particles is in the range of from 1:1 to 20:1; the diameter of the second core-shell polymer particles is in the range of from 15 to 65% of the diameter of the first core-shell polymer particles; the dry bulk density of the first core-shell polymer particles is in the range of 0.25 to 0.5 g/mL; and the dry bulk density of the second core-shell polymer particles is in the range of 0.30 to 0.90 g/mL. The composition of the present invention is useful as an undercoat layer for a thermosensitive recording material.

公开(公告)号：US20240271367A1

公开(公告)日：2024-08-15

申请号：US18569755

申请日：2022-06-21

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Xiangyi Zhang ,  John A. Roper, III ,  Andrew Hejl ,  Brian R. Einsla ,  Matthew Carter

IPC: D21H19/12 ,  C08F218/08 ,  C09D5/02 ,  C09D131/04 ,  D21H19/60

CPC classification number: D21H19/12 ,  C08F218/08 ,  C09D5/022 ,  C09D131/04 ,  D21H19/60 ,  C08F2800/20

Abstract: The present invention relates to an article comprising a paper or paperboard substrate superposed with a film having a dry coat weight in the range of from 1 g/m2 to 20 g/m2; wherein the film comprising a copolymer which comprises structural units of a vinyl ester, vinyl alcohol, and an acrylate monomer. The coating provides oil and grease resistance, mineral oil barrier performance, and heat sealability.

公开(公告)号：US10968284B2

公开(公告)日：2021-04-06

申请号：US15422925

申请日：2017-02-02

Applicant: The Regents of the University of California ,  Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Joseph Jankolovits ,  Alexander S. Katz ,  Oz M. Gazit ,  James C. Bohling ,  John A. Roper, III

IPC: C08B37/00 ,  C09D105/00 ,  C09C1/36 ,  C09C3/10 ,  C09C1/30 ,  B01J20/32 ,  C08B11/20 ,  C09C1/40 ,  C09D101/28

Abstract: The present invention is a multilayered composite comprising porous metal oxide particles that are covalently bonded by way of inorganic ether groups to one or more sites of a first polyhydroxyl-functionalized polymer. This first polymer is in turn covalently bonded by way of inorganic ether groups to one or more sites of a second polyhydroxyl-functionalized polymer. The multilayered composites can be prepared by contacting porous inorganic-oxide particles with a sufficient amount of OH-reactive crosslinking agent to form metal oxide particles imbibed with the crosslinking agent, and then contacting the inorganic-oxide particles with a solution of polyhydroxyl-functionalized polymer under reactive conditions.

公开(公告)号：US09957403B2

公开(公告)日：2018-05-01

申请号：US15216413

申请日：2016-07-21

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  THE REGENTS OF THE UNIVERSITY OF CALIFORNIA ,  Rohm and Haas Company

Inventor： Joseph Jankolovits ,  Alexander Katz ,  James C. Bohling ,  Clayton J. Radke ,  Antony K. Van Dyk ,  John A. Roper, III

IPC: C09D17/00 ,  C09C1/36 ,  C09C1/40 ,  C09C3/12 ,  C09C1/02 ,  C09C1/04 ,  C09C1/24 ,  C09C1/30 ,  C09D101/28 ,  C09D133/02

CPC classification number: C09D17/003 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/22 ,  C09C1/02 ,  C09C1/028 ,  C09C1/043 ,  C09C1/24 ,  C09C1/3081 ,  C09C1/3684 ,  C09C1/407 ,  C09C3/12 ,  C09D17/001 ,  C09D101/286 ,  C09D133/02

Abstract: The present invention relates to a composition comprising a) a stable aqueous dispersion of inorganic pigment particles hydrophobically modified with covalently bonded polysiloxane or silyl groups; and b) a polymeric anionic dispersant; wherein the hydrophobically modified inorganic pigment particles have an average particle size in the range of from 200 nm to 10 μm, and the solids content of the hydrophobically modified inorganic pigment particles is from 10 to 80 weight percent, based on the weight of inorganic pigment particles and water. The composition of the present invention provides a way to improve water resistance in coatings formulations.

公开(公告)号：US20140272389A1

公开(公告)日：2014-09-18

申请号：US14207810

申请日：2014-03-13

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Robert B. Frey ,  Wei Gao ,  John A. Roper, III ,  James Watson

IPC: D21H19/64 ,  C09D7/12 ,  C08K13/02

CPC classification number: D21H19/64 ,  C08K13/02 ,  C09D7/60 ,  D21H19/385 ,  D21H19/44 ,  D21H19/58 ,  Y02P20/582 ,  Y10T428/264

Abstract: The present invention is a composition comprising an aqueous dispersion of polymeric binder particles containing a substantial absence of phosphate and phosphonate groups; rutile TiO2 having a purity of at least 98% and a substantial absence of inorganic silica; and a dispersant which is a class of low molecular weight polyphosphates. The composition of the present invention is useful as a coating for paper or paperboard.

Abstract translation: 本发明是一种组合物，其包含含有基本上不存在磷酸酯和膦酸酯基团的聚合物粘合剂颗粒的水性分散体; 纯度至少为98％且基本上不存在无机二氧化硅的金红石TiO 2; 和一种分子量低分子量聚磷酸酯的分散剂。 本发明的组合物可用作纸或纸板的涂料。

公开(公告)号：US20190185674A1

公开(公告)日：2019-06-20

申请号：US16225067

申请日：2018-12-19

Applicant: Rohm and Haas Company ,  The Regents of the University of California ,  Dow Global Technologies LLC

Inventor： James C. Bohling ,  Yijun Guo ,  Alexander Katz ,  Manish Mishra ,  Clayton J. Radke ,  John A. Roper, III ,  Antony K. Van Dyk

IPC: C09C1/36 ,  C09C3/12

CPC classification number: C09C1/3684 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/22 ,  C01P2006/90 ,  C08K9/08 ,  C09C3/12 ,  C09D5/028 ,  C09D7/62

Abstract: The present invention is a composition comprising an aqueous dispersion of metal oxide pigment particles coated with a polymer comprising structural units of an alkyltrihydroxysilane or a salt thereof. The composition of the present invention provides hydrophobicity to pigment particles, thereby imparting water resistance, and allows for high loadings of pigment in water without increased viscosity.

公开(公告)号：US09932487B2

公开(公告)日：2018-04-03

申请号：US15366102

申请日：2016-12-01

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Brian R. Einsla ,  Valeriy V. Ginzburg ,  Lanfang Li ,  John A. Roper, III ,  Rebecca Smith ,  Jian Yang

IPC: B41M5/44 ,  C09D7/12 ,  C09D125/14

CPC classification number: C09D7/70 ,  B41M5/44 ,  B41M2205/04 ,  B41M2205/38 ,  C09D7/68 ,  C09D7/69 ,  C09D125/14

Abstract: The present invention relates to a thermosensitive recording material comprising paper, an undercoat layer disposed on the paper, and a thermosensitive recording layer disposed on the undercoat layer, wherein the undercoat layer comprises a binder and first and second hollow sphere polymer particles, wherein the first hollow sphere polymer particles have a diameter in the range of from 1.2 μm to 1.8 μm; the second hollow sphere polymer particles have a diameter in the range of from 0.25 μm to 1.0 μm; the number ratio of the second to the first hollow sphere polymer particles is in the range of from 1:1 to 20:1; the diameter of the second hollow sphere polymer particles is in the range of from 15 to 65% of the diameter of the first hollow sphere polymer particles; the dry bulk density of the first hollow sphere polymer particles is in the range of 0.25 to 0.5 g/mL; and the dry bulk density of the second hollow sphere polymer particles is in the range of 0.30 to 0.90 g/mL.

公开(公告)号：US20150073134A1

公开(公告)日：2015-03-12

申请号：US14479113

申请日：2014-09-05

Applicant: The Regents of the University of California ,  Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Joseph Jankolovits ,  Alexander S. Katz ,  Oz M. Gazit ,  James C. Bohling ,  John A. Roper, III

IPC: C08B37/00

CPC classification number: C08B37/0024 ,  B01J20/3204 ,  B01J20/3272 ,  B01J20/3274 ,  B01J20/3278 ,  B01J20/3289 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/04 ,  C08B11/20 ,  C09C1/3054 ,  C09C1/3072 ,  C09C1/3081 ,  C09C1/309 ,  C09C1/3661 ,  C09C1/3676 ,  C09C1/3684 ,  C09C1/3692 ,  C09C1/407 ,  C09C3/10 ,  C09D101/28 ,  C09D105/00

Abstract: The present invention is a multilayered composite comprising porous metal oxide particles that are covalently bonded by way of inorganic ether groups to one or more sites of a first polyhydroxyl-functionalized polymer. This first polymer is in turn covalently bonded by way of inorganic ether groups to one or more sites of a second polyhydroxyl-functionalized polymer. The multilayered composites can be prepared by contacting porous inorganic-oxide particles with a sufficient amount of OH-reactive crosslinking agent to form metal oxide particles imbibed with the crosslinking agent, and then contacting the inorganic-oxide particles with a solution of polyhydroxyl-functionalized polymer under reactive conditions.

Abstract translation: 本发明是一种多层复合材料，其包含多孔金属氧化物颗粒，其通过无机醚基团与第一多羟基官能化聚合物的一个或多个位点共价键合。 该第一聚合物又通过无机醚基团共价键合到第二多羟基官能化聚合物的一个或多个位点。 多层复合材料可以通过使多孔无机氧化物颗粒与足够量的OH-反应性交联剂接触以形成吸附有交联剂的金属氧化物颗粒，然后使无机氧化物颗粒与多羟基官能化聚合物 在反应条件下。

公开(公告)号：US20140295173A1

公开(公告)日：2014-10-02

申请号：US14226872

申请日：2014-03-27

Applicant: Dow Global Technologies LLC

Inventor： Vivek Kalihari ,  John A. Roper, III

IPC: D21H19/64 ,  D21H19/38

CPC classification number: D21H19/64 ,  B32B5/16 ,  B32B2260/046 ,  D21H19/385 ,  D21H19/44 ,  D21H21/08 ,  Y10T428/264

Abstract: The present invention relates to a laminate comprising coated or uncoated paperboard coated with a film that comprises a polymeric binder, TiO2, and tetrapotassium pyrophosphate. Paper or paperboard coated with a film containing tetrapotassium pyrophosphate shows excellent optical properties.

Abstract translation: 本发明涉及一种包含涂覆有薄膜的涂布或未涂布纸板的层压板，该薄膜包含聚合物粘合剂，TiO 2和焦磷酸四钾。 涂有含有焦磷酸四钾的薄膜的纸或纸板显示出优异的光学性能。

公开(公告)号：US10184062B2

公开(公告)日：2019-01-22

申请号：US15366100

申请日：2016-12-01

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Brian R. Einsla ,  Valeriy V. Ginzburg ,  Lanfang Li ,  John A. Roper, III ,  Rebecca Smith ,  Jian Yang

IPC: C09B67/00 ,  C08G61/04 ,  C09D125/14 ,  D21H19/58 ,  D21H15/10 ,  G03C1/79 ,  C09D7/65 ,  C09D7/40 ,  B41M5/44

Abstract: The present invention relates to a coating composition comprising an aqueous dispersion of a binder and first and second core-shell polymer particles having aqueous neutralized acid cores, wherein the dry bulk density of the first core-shell polymer particles is in the range of 0.25 to 0.5 g/mL; and the dry bulk density of the second core-shell polymer particles is in the range of 0.30 to 0.90 g/mL. The composition of the present invention is useful as an undercoat layer for a thermosensitive recording material.