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公开(公告)号：US10829862B2
公开(公告)日：2020-11-10
申请号：US15122568
申请日：2015-02-25
发明人： Tatsunori Murata , Hirotaka Kotani , Hideki Endo , Akira Sugawara , Yuta Sonoda , Tetsuo Kato , Hideki Ohsumi , Jyun Toyoizumi
IPC分类号： C25D5/50 , B32B15/01 , C25D5/34 , C25D5/12 , C25D7/00 , C25D3/12 , C25D3/32 , C25D3/38 , C25F1/00
摘要： In a tin-plated product wherein a surface of a substrate 10 of copper or a copper alloy is plated with tin, an underlying layer 12 of at least one of nickel and a copper-nickel alloy is formed on the surface of the substrate 10, and an outermost layer formed on the surface of the underlying layer 12 is composed of a copper-tin alloy layer 14 and tin layers 16, the copper-tin alloy 14 being formed of a large number of crystal grains of a copper-tin alloy, each of the tin layers 16 being arranged in a corresponding one of recessed portions, each of which is formed between adjacent crystal grains of the large number of crystal grains of the copper-tin alloy, the adjacent crystal grains being adjacent to each other on the outermost surface of the outer most layer, the area ratio occupied by the tin layers 16 on the outermost surface being 20 to 80%, and the maximum thickness of the tin layers 16 being smaller than the average particle diameter of the crystal grains of the copper-tin alloy.
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公开(公告)号：US20180080135A1
公开(公告)日：2018-03-22
申请号：US15564538
申请日：2016-04-20
发明人： Hirotaka Kotani , Hiroto Narieda , Hideki Endo , Akira Sugawara , Yuta Sonoda , Takaya Kondo , Jyun Toyoizumi , Yuya Kishibata
摘要： There is provided a tin-plated product having an excellent minute sliding abrasion resistance property when it is used as the material of insertable and extractable connecting terminals, and a method for producing the same. After a nickel layer 16 is formed on a substrate 10 of copper or a copper alloy so as to have a thickness of 0.1 to 1.5 μm by electroplating, a tin-copper plating layer 12 containing tin 12b mixed with a copper-tin alloy 12a is formed thereon so as to have a thickness of 0.6 to 10 μm by electroplating using a tin-copper plating bath which contains 5 to 35% by weight of copper with respect to the total amount of tin and copper, and then, a tin layer 14 is formed thereon so as to have a thickness of 1 μm or less by electroplating if necessary.
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公开(公告)号：US20190136398A1
公开(公告)日：2019-05-09
申请号：US16099791
申请日：2017-04-18
发明人： Hirotaka Kotani , Hiroto Narieda , Akira Sugawara , Yuta Sonoda , Yoshitaka Ito
摘要： After drying the surface of a tin plating layer having a thickness of 0.4 to 3 μm which is formed on a base material of copper or a copper alloy by electroplating at a current density of 5 to 13 A/dm2 in a tin plating solution consisting of water, tin sulfate, sulfuric acid and a surfactant, the surface of the tin plating layer is heated to melt tin, and then, cooled to cause a layer of the tin plating layer on the side of the outermost surface to be a tin layer, which has a structure obtained by solidification after melting, while causing a layer of the tin plating layer between the tin layer and the base material to be a copper-tin alloy layer, to produce a tin-plated product wherein a tin layer, which has a structure obtained by solidification after melting, is formed on a copper-tin alloy layer formed on a base material of copper or a copper alloy and wherein the tin-plated product has a glossiness of 0.3 to 0.7.
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公开(公告)号：US11078587B2
公开(公告)日：2021-08-03
申请号：US15752996
申请日：2016-08-23
发明人： Yuta Sonoda , Hiroto Narieda , Hideki Endo , Akira Sugawara , Hirotaka Kotani , Jyun Toyoizumi , Takaya Kondo , Yuya Kishibata
摘要： A tin-plated product contains: a substrate 10 of copper or a copper alloy; an underlying layer 12 of nickel which is formed on the surface of the substrate 10; and an outermost layer 14 containing tin, the outermost layer 14 being formed on the surface of the underlying layer 12, the outermost layer 14 being composed of a copper-tin alloy layer 14a of a large number of crystal grains of a copper-tin alloy, tin layers 14b of tin having an average thickness of 0.01 to 0.20 micrometers, and a plurality of copper-nickel-tin alloy layers 14c of a copper-nickel-tin alloy, each of the tin layers 14b being formed in a corresponding one of recessed portions between adjacent two of the crystal grains of the copper-tin alloy on the outermost surface of the copper-tin alloy layer, the copper-nickel-tin alloy layers 14c being arranged on the side of the underlying layer 12 in the copper-tin alloy layer 14a so as to be apart from each other.
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公开(公告)号：US10982345B2
公开(公告)日：2021-04-20
申请号：US16099791
申请日：2017-04-18
发明人： Hirotaka Kotani , Hiroto Narieda , Akira Sugawara , Yuta Sonoda , Yoshitaka Ito
摘要： After drying the surface of a tin plating layer having a thickness of 0.4 to 3 μm which is formed on a base material of copper or a copper alloy by electroplating at a current density of 5 to 13 A/dm2 in a tin plating solution consisting of water, tin sulfate, sulfuric acid and a surfactant, the surface of the tin plating layer is heated to melt tin, and then, cooled to cause a layer of the tin plating layer on the side of the outermost surface to be a tin layer, which has a structure obtained by solidification after melting, while causing a layer of the tin plating layer between the tin layer and the base material to be a copper-tin alloy layer, to produce a tin-plated product wherein a tin layer, which has a structure obtained by solidification after melting, is formed on a copper-tin alloy layer formed on a base material of copper or a copper alloy and wherein the tin-plated product has a glossiness of 0.3 to 0.7.
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公开(公告)号：US10676835B2
公开(公告)日：2020-06-09
申请号：US15564538
申请日：2016-04-20
发明人： Hirotaka Kotani , Hiroto Narieda , Hideki Endo , Akira Sugawara , Yuta Sonoda , Takaya Kondo , Jyun Toyoizumi , Yuya Kishibata
IPC分类号： B32B15/00 , C25D3/60 , C25D5/10 , C25D5/12 , H01R13/03 , C25D7/00 , C25D3/58 , C25D3/38 , C25D3/12 , C25D3/30
摘要： There is provided a tin-plated product having an excellent minute sliding abrasion resistance property when it is used as the material of insertable and extractable connecting terminals, and a method for producing the same. After a nickel layer 16 is formed on a substrate 10 of copper or a copper alloy so as to have a thickness of 0.1 to 1.5 μm by electroplating, a tin-copper plating layer 12 containing tin 12b mixed with a copper-tin alloy 12a is formed thereon so as to have a thickness of 0.6 to 10 μm by electroplating using a tin-copper plating bath which contains 5 to 35% by weight of copper with respect to the total amount of tin and copper, and then, a tin layer 14 is formed thereon so as to have a thickness of 1 μm or less by electroplating if necessary.
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公开(公告)号：US20170088965A1
公开(公告)日：2017-03-30
申请号：US15122568
申请日：2015-02-25
发明人： Tatsunori Murata , Hirotaka Kotani , Hideki Endo , Akira Sugawara , Yuta Sonoda , Tetsuo Kato , Hideki Ohsumi , Jyun Toyoizumi
摘要： In a tin-plated product wherein a surface of a substrate 10 of copper or a copper alloy is plated with tin, an underlying layer 12 of at least one of nickel and a copper-nickel alloy is formed on the surface of the substrate 10, and an outermost layer formed on the surface of the underlying layer 12 is composed of a copper-tin alloy layer 14 and tin layers 16, the copper-tin alloy 14 being formed of a large number of crystal grains of a copper-tin alloy, each of the tin layers 16 being arranged in a corresponding one of recessed portions, each of which is formed between adjacent crystal grains of the large number of crystal grains of the copper-tin alloy, the adjacent crystal grains being adjacent to each other on the outermost surface of the outer most layer, the area ratio occupied by the tin layers 16 on the outermost surface being 20 to 80%, and the maximum thickness of the tin layers 16 being smaller than the average particle diameter of the crystal grains of the copper-tin alloy.
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公开(公告)号：US11208730B2
公开(公告)日：2021-12-28
申请号：US16810963
申请日：2020-03-06
发明人： Yuta Sonoda , Yukiya Kato , Hiroto Narieda
摘要： There are provided a composite plated product, which has little uneven appearance and good wear resistance, and a method for producing the same without the need of any cyanide-containing silver-plating solutions and any silver-plating solutions containing silver nitrate as a silver salt. A sulfonic-acid-containing silver-plating solution, to which a carbon particle dispersing solution (preferably containing a silicate) is added, is used for electroplating a base material (preferably made of copper or a copper alloy) to form a composite plating film of a composite material, which contains the carbon particles in a silver layer, on the base material to produce a composite plated product.
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公开(公告)号：US11225726B2
公开(公告)日：2022-01-18
申请号：US16749140
申请日：2020-01-22
发明人： Tsuyoshi Ito , Yuta Sonoda , Yukiya Kato , Hiroto Narieda
摘要： There are provided a composite plated product, which has little uneven appearance, a low contact resistance and good wear resistance, and a method for producing the same without the need of any silver-plating solutions containing cyanides and any silver-plating solutions containing silver nitrate as a silver salt. After carbon particles are caused to be suspended in water, an oxidizing agent is added thereto for carrying out a wet oxidation treatment of the carbon particles, and a silver-plating solution, which contains at least one sulfonic acid and the carbon particles treated by the wet oxidation treatment, is used for electroplating a base material to form a coating film of a composite material, which contains the carbon particles in a silver layer, on the base material to produce a composite plated product.
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公开(公告)号：US10985485B2
公开(公告)日：2021-04-20
申请号：US16462695
申请日：2017-11-21
发明人： Hiroto Narieda , Yuta Sonoda , Tatsuhiro Doi , Takao Tomiya
摘要： There are provided a tin-plated product which has a zinc plating layer on the surface thereof and which has good corrosion resistance and good adhesion of the zinc plating even if the connecting portion of a terminal of the tin-plated product to an electric wire of aluminum or an aluminum alloy is not processed during press fitting such as swaging (or caulking) when the tin-plated product is used as the material of the terminal which is to be connected to the electric wire by press fitting, and a method for producing the same.
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