公开(公告)号：US4935580A

公开(公告)日：1990-06-19

申请号：US206280

申请日：1988-06-14

Applicant: Chien C. Chao ,  Henry Rastelli

Inventor： Chien C. Chao ,  Henry Rastelli

IPC: B01J20/18 ,  C07C7/13

CPC classification number: B01J20/186 ,  C07C7/13 ,  Y02C10/08

Abstract: Clinoptilolites, including both natural clinoptilolites and those which have been ion-exchanged with metal cations such as lithium, sodium, potassium, calcium, magnesium, barium, strontium, zinc, copper, cobalt, iron and manganese, are useful for the removal of traces of carbon dioxide and water from streams of hydrocarbons having kinetic diameters of not more than about 5 .ANG..

Abstract translation: 包括天然斜发沸石和与金属阳离子例如锂，钠，钾，钙，镁，钡，锶，锌，铜，钴，铁和锰进行离子交换的斜发沸石可用于去除痕迹 的二氧化碳和水，其动力学直径不大于约5 ANGSTROM。

公开(公告)号：US5045515A

公开(公告)日：1991-09-03

申请号：US465855

申请日：1990-01-18

Applicant: Chien C. Chao ,  Henry Rastelli

Inventor： Chien C. Chao ,  Henry Rastelli

IPC: B01J20/18 ,  C07C7/13

CPC classification number: C07C7/13 ,  B01J20/186

Abstract: Natural clinoptilolites which have been ion-exchanged with particular proportions of metal cations such as lithium, sodium, potassium, calcium, magnesium, barium, strontium, zinc, copper, cobalt, iron and manganese, are novel and useful for the removal of traces of carbon dioxide and water from streams of hydrocarbons having kinetic diameters of not more than about 5.

Abstract translation: 已经与特定比例的金属阳离子如锂，钠，钾，钙，镁，钡，锶，锌，铜，钴，铁和锰进行离子交换的天然斜发沸石是新颖的，可用于去除痕迹 二氧化碳和水，其动力学直径不超过约5。

公开(公告)号：US4775396A

公开(公告)日：1988-10-04

申请号：US117688

申请日：1987-11-05

Applicant: Henry Rastelli ,  Chien C. Chao ,  Desh R. Garg

Inventor： Henry Rastelli ,  Chien C. Chao ,  Desh R. Garg

IPC: B01D53/02 ,  B01D53/04 ,  B01J20/18 ,  C01B3/56 ,  C01B21/04 ,  C01B32/50

CPC classification number: B01D53/047 ,  C01B21/0466 ,  C01B3/56 ,  C01B31/20 ,  B01D2253/108 ,  B01D2253/1085 ,  B01D2253/30 ,  B01D2257/504 ,  C01B2210/0051 ,  Y02C10/08 ,  Y02E50/346 ,  Y02P20/152 ,  Y10S95/902

Abstract: Carbon dioxide is selectively adsorbed and separated from non-acidic gases such as nitrogen, hydrogen and methane using a pressure swing adsorption process in a fixed adsorption bed containing a faujasite type of zeolitic aluminosilicate containing at least 20 equivalent percent of at least one cation species selected from the group consisting of zinc, rare earth, hydrogen and ammonium and containing not more than 80 equivalent percent of alkali metal or alkaline earth metal cations.

公开(公告)号：US5116793A

公开(公告)日：1992-05-26

申请号：US690238

申请日：1991-04-24

Applicant: Chien C. Chao ,  Henry Rastelli

Inventor： Chien C. Chao ,  Henry Rastelli

IPC: B01J20/18 ,  C07C7/13

CPC classification number: C07C7/13 ,  B01J20/186

Abstract: Clinoptilolites, including both natural and synthetic clinoptilolites which have been ion-exchanged with metal cations such as lithium, sodium, potassium, calcium, magnesium, barium, strontiun, zinc, copper, cobalt, iron and manganese, are useful for the removal of traces of ammonia from streams of hydrocarbons having kinetic diameters of not more than about 5 .ANG.. This invention relates to the process of producing the modified clinoptilolite adsorbent.

Abstract translation: 斜发沸石包括与金属阳离子如锂，钠，钾，钙，镁，钡，锶，锌，铜，钴，铁和锰进行离子交换的天然和合成斜发沸石，可用于去除痕量 的来自具有不大于约5 ANGSTROM的动力学的烃流。 本发明涉及生产改性斜发沸石吸附剂的方法。

公开(公告)号：US5019667A

公开(公告)日：1991-05-28

申请号：US509651

申请日：1990-04-16

Applicant: Chien C. Chao ,  Henry Rastelli

Inventor： Chien C. Chao ,  Henry Rastelli

IPC: B01J20/18 ,  C07C7/13

CPC classification number: B01J20/186 ,  C07C7/13

Abstract: Clinoptilolites, including both natural and synthetic clinopilolites which have been ion-exchanged with metal cations such as lithium, sodium, potassium, calcium, magnesium, barium, strontium, zinc, copper, cobalt, iron and manganese, are useful for the removal of traces of ammonia from streams of hydrocarbons having kinetic diameters of not more than about 5.ANG.. The purified hydrocarbons are useful for producing polyolefins.

Abstract translation: 斜发沸石，包括与金属阳离子如锂，钠，钾，钙，镁，钡，锶，锌，铜，钴，铁和锰进行离子交换的天然和合成的叠氮石，可用于去除痕量 的来自具有不大于约5 ANGSTROM的动力学的烃流。 纯化的烃可用于生产聚烯烃。

公开(公告)号：US5336834A

公开(公告)日：1994-08-09

申请号：US63801

申请日：1993-05-20

Applicant: Andrew S. Zarchy ,  Chien C. Chao

Inventor： Andrew S. Zarchy ,  Chien C. Chao

IPC: C10G25/00 ,  C10G67/06 ,  C07C5/22

CPC classification number: C10G25/00 ,  C10G67/06

Abstract: An adsorption arrangement in combination with a catalytic hydrocarbon conversion process suspends non-hydrocarbon materials that act to enhance the operation of the conversion zone by using an adsorption zone arrangement to keep the compounds in recirculation about the reaction zone. The process of this invention is particularly useful for the isomerization of hydrocarbons wherein the adsorption zone arrangement operates to maintain chloride compounds in the reaction zone and to prevent contamination of product streams with the chloride compounds. This invention can be used in combination with traditional adsorptive methods of removing contaminant from feedstreams that enter reaction zones. The invention is also useful for sulfided catalysts where it is desirable to maintain sulfur within the reaction zone and keep sulfur contamination from entering product streams.

Abstract translation: 与催化烃转化过程组合的吸附装置悬浮非烃材料，其通过使用吸附区排列来增强转化区的操作，以保持化合物在反应区周围再循环。 本发明的方法对于烃的异构化特别有用，其中吸附区布置用于维持反应区中的氯化物化合物并防止氯化物化合物产物流的污染。 本发明可以与从进料反应区的进料流中除去污染物的传统吸附方法组合使用。 本发明也可用于硫化催化剂，其中希望在反应区内保持硫并保持硫污染物进入产物流。

公开(公告)号：US4516566A

公开(公告)日：1985-05-14

申请号：US454655

申请日：1982-12-30

Applicant: Chien C. Chao ,  John D. Sherman

Inventor： Chien C. Chao ,  John D. Sherman

IPC: C12P19/02 ,  C07H1/06 ,  C07H3/00 ,  C07H3/02 ,  C07H13/02 ,  C13K13/00

CPC classification number: C13K13/007

Abstract: A process for the separation of arabinose is disclosed which comprises the selective adsorption of same on BaX zeolitic molecular sieves. The process is especially useful for separating arabinose from mixtures of sugars containing arabinose.

公开(公告)号：US4283560A

公开(公告)日：1981-08-11

申请号：US098714

申请日：1979-11-30

Applicant: Chien C. Chao ,  John D. Sherman

Inventor： Chien C. Chao ,  John D. Sherman

IPC: C07C29/76 ,  C07C29/88 ,  C07C45/79 ,  C07C49/303

CPC classification number: C07C29/88 ,  C07C29/76 ,  C07C45/79 ,  C07C2101/14

Abstract: Cyclohexanone is selectively adsorbed from admixture with cyclohexanol using specific cationic forms of zeolite X and zeolite Y. The process utilizes the interaction of the electrostatic field of the zeolite with the slightly greater polarity of the cyclohexanone to enhance the adsorptive strength difference between the competing adsorbates.

Abstract translation: 使用特定阳离子形式的沸石X和沸石Y选择性地吸附环己酮与环己醇的混合物。该方法利用沸石的静电场与环己酮的极性极性的相互作用，以增强竞争性吸附物之间的吸附强度差异。

公开(公告)号：US5164076A

公开(公告)日：1992-11-17

申请号：US644796

申请日：1991-01-22

Applicant: Andrew S. Zarchy ,  Richard Correia ,  Chien C. Chao

Inventor： Andrew S. Zarchy ,  Richard Correia ,  Chien C. Chao

IPC: C10G25/05

CPC classification number: C10G25/05

Abstract: Processes are disclosed for the separation of hydrogen sulfide from feedstreams containing hydrogen sulfide and hydrocarbons by adsorption using a clinoptilolite adsorbent containing cations having ionic radii of from about 1.10 to 1.40 Angstroms. The processes can provide substantially enhanced adsorption capacities as compared with other adsorbents such as Zeolite 4A. As a result, a throughput of existing sulfur adsorption plants can be increased, e.g., by about 100%. The processes can be operated at elevated adsorption temperatures, e.g., greater than about 200.degree. F., and thus are particularly suitable when integrated with other processing steps such as hydrocarbon conversion reactions that utilize catalysts which are sulfur-sensitive. In addition, the clinoptilolite adsorbents of the present invention have a high tolerance to environments that comprise halides, e.g., HCl.

Abstract translation: 公开了通过使用含有离子半径为约1.10至1.40埃的阳离子的斜发沸石吸附剂通过吸附从含有硫化氢和烃的进料流中分离硫化氢的方法。 与其它吸附剂如沸石4A相比，该方法可提供显着增强的吸附能力。 结果，可以增加现有硫吸附装置的生产量，例如增加约100％。 该方法可以在升高的吸附温度（例如大于约200°F）下操作，因此当与其他加工步骤（例如利用硫敏感的催化剂的烃转化反应）结合时特别合适。 此外，本发明的斜发沸石吸附剂对包含卤化物例如HCl的环境具有高耐受性。

公开(公告)号：US4482761A

公开(公告)日：1984-11-13

申请号：US457427

申请日：1983-01-12

Applicant: Chien C. Chao ,  John D. Sherman

Inventor： Chien C. Chao ,  John D. Sherman

IPC: C07C35/16 ,  B01D15/08 ,  C07C27/00 ,  C07C29/76 ,  C07C31/26 ,  C07C67/00 ,  G01N30/88 ,  C13D3/12

CPC classification number: C07C29/76 ,  C07B2200/07 ,  C07C2101/14

Abstract: A process for the bulk separation of inositol and/or sorbitol is disclosed which comprises the selective adsorption of same on certain types of zeolitic molecular sieves. The process is especially useful for separating inositol from aqueous solutions containing same, using type X and type Y zeolite adsorbents whose cations are Na, Ca or Ba.

Abstract translation: 公开了一种用于大体分离肌醇和/或山梨糖醇的方法，其包括在某些类型的沸石分子筛上选择性吸附它们。 该方法特别适用于使用X和Y型沸石吸附剂，阳离子为Na，Ca或Ba的分离肌醇与含有其的溶液。