公开(公告)号：US20060052510A1

公开(公告)日：2006-03-09

申请号：US10532058

申请日：2003-10-16

申请人： Bo Haggman ,  Hakan Bjornberg ,  Birger Midelf ,  David James

发明人： Bo Haggman ,  Hakan Bjornberg ,  Birger Midelf ,  David James

IPC分类号： C08G18/42

CPC分类号： C08L101/005 ,  C09D201/005 ,  C08L2666/14

摘要： An air drying waterborne resin composition is disclosed. Said resin composition comprises at least one amphiphlic air drying dendritic polymer, at least one non-amphiphilic air drying alkyd resin, at least one drier initiating and/or promoting autoxidation, and water, and optionally at least one anionic and/or nonionic surfactant, and/or at least one coalescent agent. Said at least one amphiphilic air drying dendritic polymer is built up from a polyhydric dendritic core polymer having terminal hydroxyl groups and at least one unsaturated carboxylic acid and at least one adduct, obtainable by addition of a monoalkylated polyethylene glycol to a dicarboxylic acid or anhydride and/or a diisocyanate, each bonded to at least one terminal hydroxyl group in said polyhydric dendritic core polymer.

摘要翻译： 公开了一种空气干燥水性树脂组合物。 所述树脂组合物包含至少一种两亲空气干燥树枝状聚合物，至少一种非两亲空气干燥醇酸树脂，至少一种引发和/或促进自动氧化的干燥剂，以及任选至少一种阴离子和/或非离子表面活性剂， 和/或至少一种聚结剂。 所述至少一种两亲空气干燥树枝状聚合物由具有末端羟基和至少一种不饱和羧酸的多元树枝状核聚合物和至少一种加合物构成，所述加成物可通过将二烷基化聚乙二醇加入到二羧酸或酸酐中而得到， /或二异氰酸酯，各自与所述多羟基树枝状核聚合物中的至少一个末端羟基键合。

公开(公告)号：US07186771B2

公开(公告)日：2007-03-06

申请号：US10532058

申请日：2003-10-16

申请人： Bo Haggman ,  Hakan Bjornberg ,  Birger Midelf ,  David James

发明人： Bo Haggman ,  Hakan Bjornberg ,  Birger Midelf ,  David James

IPC分类号： C08J3/00 ,  C08K5/00 ,  C08L67/00 ,  C08L75/00 ,  C08G18/42

CPC分类号： C08L101/005 ,  C09D201/005 ,  C08L2666/14

摘要： An air drying waterborne resin composition is disclosed. Said resin composition comprises at least one amphiphlic air drying dendritic polymer, at least one non-amphiphilic air drying alkyd resin, at least one drier initiating and/or promoting autoxidation, and water, and optionally at least one anionic and/or nonionic surfactant, and/or at least one coalescent agent. Said at least one amphiphilic air drying dendritic polymer is built up from a polyhydric dendritic core polymer having terminal hydroxyl groups and at least one unsaturated carboxylic acid and at least one adduct, obtainable by addition of a monoalkylated polyethylene glycol to a dicarboxylic acid or anhydride and/or a diisocyanate, each bonded to at least one terminal hydroxyl group in said polyhydric dendritic core polymer.

摘要翻译： 公开了一种空气干燥水性树脂组合物。 所述树脂组合物包含至少一种两亲空气干燥树枝状聚合物，至少一种非两亲空气干燥醇酸树脂，至少一种引发和/或促进自动氧化的干燥剂，以及任选至少一种阴离子和/或非离子表面活性剂， 和/或至少一种聚结剂。 所述至少一种两亲空气干燥树枝状聚合物由具有末端羟基和至少一种不饱和羧酸的多元树枝状核聚合物和至少一种加合物构成，所述加成物可通过将二烷基化聚乙二醇加入到二羧酸或酸酐中而得到， /或二异氰酸酯，各自与所述多羟基树枝状核聚合物中的至少一个末端羟基键合。

公开(公告)号：US07091308B2

公开(公告)日：2006-08-15

申请号：US10501024

申请日：2003-01-22

申请人： Bo Haggman ,  David James ,  Hakan Bjornberg ,  Birger Midelf

发明人： Bo Haggman ,  David James ,  Hakan Bjornberg ,  Birger Midelf

IPC分类号： C08G59/06 ,  C08G65/14

CPC分类号： C08G83/003 ,  C08G65/2609

摘要： A chain extended dendritic polyether comprising a dendritic core polymer and a chain extension bonded to said core polymer, which chain extended dendritic polyether optionally is at least partially chain terminated and/or partially functionalised. The core polymer is a polyhydric dendritic polyether and the chain extension is obtained by addition of at least one alkylene oxide to at least one hydroxyl group in said core polymer.

摘要翻译： 一种链延长的树枝状聚醚，其包含树枝状核聚合物和与所述芯聚合物结合的链延伸，所述链延长树枝状聚醚任选地至少部分链终止和/或部分官能化。 核心聚合物是多羟基树枝状聚醚，并且通过在所述芯聚合物中的至少一个羟基上加入至少一种烯化氧来获得链延伸。

公开(公告)号：US07176264B2

公开(公告)日：2007-02-13

申请号：US10416712

申请日：2001-11-12

申请人： Bo Pettersson ,  David James ,  Birger Midelf ,  Hakan Bjornberg ,  Nicola Rehnberg

发明人： Bo Pettersson ,  David James ,  Birger Midelf ,  Hakan Bjornberg ,  Nicola Rehnberg

IPC分类号： C08G65/18

CPC分类号： C08G83/003 ,  C08G65/18 ,  C08G65/22

摘要： A process for manufacture of a dendritic polyether comprising a core, derived from a compound having two or more hydroxyl groups, and at least one branching generation being built up from at least one hydroxyoxetane having one oxetane group and at least one hydroxyl group is disclosed. The process comprises ring opening addition to said core and ring opening polymerization of said hydroxyoxetane. A mixture of the core compound and at least one cationic initiator is prepared and said hydroxyoxetane is fed to said mixture at a rate resulting in and/or maintaining a reaction temperature below onset at thermal degradation and in an amount resulting in at least one branching generation. The initiator is present in an amount of 0.1–0.5% by weight calculated on said core and said oxetane, preferably in an amount giving a ratio hydroxyl groups to initiator of between 1:0.01 and 1:0.05. Yielded dendritic polyether is sebsequently neutralised by addition of at least one alkaline compound and optionally purified.

摘要翻译： 公开了一种制备树枝状聚醚的方法，该树枝状聚醚包含衍生自具有两个或多个羟基的化合物的核心，以及由至少一种具有一个氧杂环丁烷基团和至少一个羟基的羟基氧杂环丁烷构成的至少一种支链产物。 该方法包括加入所述核心的开环和所述羟基氧杂环丁烷的开环聚合。 制备核心化合物和至少一种阳离子引发剂的混合物，并且所述羟基氧杂环丁烷以导致和/或保持反应温度低于起始时的热降解速率并以导致至少一个分支生成的量加入所述混合物 。 引发剂的存在量为所述核和所述氧杂环丁烷计算的0.1-0.5重量％，优选以使得羟基与引发剂的比例在1:0.01至1:0.05之间。 随后通过加入至少一种碱性化合物中和得到的树枝状聚醚并任选地进行纯化。

公开(公告)号：US20050131205A1

公开(公告)日：2005-06-16

申请号：US10501024

申请日：2003-01-22

申请人： Bo Häggman ,  David James ,  Hakan Bjornberg ,  Birger Midelf

发明人： Bo Häggman ,  David James ,  Hakan Bjornberg ,  Birger Midelf

IPC分类号： C08G65/28 ,  C08G65/18 ,  C08G65/26 ,  C08G83/00 ,  C09D11/10 ,  C09D171/00 ,  C09J171/00 ,  C08G59/00

CPC分类号： C08G83/003 ,  C08G65/2609

摘要： A chain extended dendritic polyether comprising a dendritic core polymer and a chain extension bonded to said core polymer, which chain extended dendritic polyether optionally is at least partially chain terminated and/or partially functionalised. The core polymer is a polyhydric dendritic polyether and the chain extension is obtained by addition of at least one alkylene oxide to at least one hydroxyl group in said core polymer.

摘要翻译： 一种链延长的树枝状聚醚，其包含树枝状核聚合物和与所述芯聚合物结合的链延伸，所述链延长树枝状聚醚任选地至少部分链终止和/或部分官能化。 核心聚合物是多羟基树枝状聚醚，并且通过在所述芯聚合物中的至少一个羟基上加入至少一种烯化氧来获得链延伸。

公开(公告)号：US20050240000A1

公开(公告)日：2005-10-27

申请号：US11158062

申请日：2005-06-22

申请人： Bo Haggman ,  Hakan Bjornberg

发明人： Bo Haggman ,  Hakan Bjornberg

IPC分类号： C08G63/06 ,  C08G18/40 ,  C08G18/42 ,  C08G18/46 ,  C08G18/65 ,  C08G63/91 ,  C08G69/26 ,  C08G83/00

CPC分类号： C08G83/003 ,  C08G18/4072 ,  C08G18/4283 ,  C08G18/4623 ,  C08G18/4669 ,  C08G18/4804 ,  C08G18/4887 ,  C08G18/5024 ,  C08G18/6552 ,  C08G18/657 ,  C08G69/26 ,  C08G2101/0008 ,  C08G2101/0083 ,  C08L101/005

摘要： A dendritic macromolecule having the following characteristics (i) an active hydrogen content of a least 3.8 mmoles/g and (ii) an active hydrogen functionality of at least 16 and which macromolecule is mixable at a ratio of at least 15% by weight with a polyether polyol having a hydroxyl value of at most 40 mg KOH/g to form a stable liquid at 23 ° C. The subject dendritic macromolecule confer significant load building properties to isocyanate based foams and elastomers such as polyurethane foams and elastomers and may be used for this purpose to partially or fully displace current relatively expensive chemical systems which are used to confer load building characteristics to such foams and elastomers.

摘要翻译： 具有以下特征的树枝状高分子（i）至少3.8mmoles / g的活性氢含量和（ii）至少16的活性氢官能团，并且该大分子可以以至少15重量％的比例与 羟基值至多为40mg KOH / g的聚醚多元醇，以在23℃下形成稳定的液体。目标树枝状高分子赋予基于异氰酸酯的泡沫和弹性体如聚氨酯泡沫和弹性体显着的负荷建筑性能，并且可用于 这个目的是部分地或完全地替代当前相对昂贵的化学体系，这些化学体系用于赋予这种泡沫和弹性体负荷建筑特性。

公开(公告)号：US20150203657A1

公开(公告)日：2015-07-23

申请号：US13818036

申请日：2011-07-26

申请人： Karin Ohgren Gredegard ,  Anders Magnuesson ,  Hakan Bjornberg ,  Niklas Persson ,  Maria Peterson ,  Kent Sorensen

发明人： Karin Ohgren Gredegard ,  Anders Magnuesson ,  Hakan Bjornberg ,  Niklas Persson ,  Maria Peterson ,  Kent Sorensen

IPC分类号： C08K5/103 ,  C08K5/11 ,  C07C69/34 ,  C08K5/1535

摘要： The present invention refers to a plasticiser, said plasticiser being an ester formed by reaction of a pentaerythritol and a monocarboxylic acid, having 4-5 carbon atoms. In a further aspect the present invention refers to the use of said plasticiser in blends and in a PVC resin. The plasticiser of the present invention is a non-phthalic plasticiser that has proven to have shorter fusion time and higher plasticising efficiency compared to commercial non-phthalic PVC plasticisers.

摘要翻译： 本发明涉及一种增塑剂，所述增塑剂是通过具有4-5个碳原子的季戊四醇和一元羧酸的反应形成的酯。 在另一方面，本发明涉及所述增塑剂在共混物和PVC树脂中的用途。 本发明的增塑剂是一种非邻苯二甲酸增塑剂，其与商业非邻苯二甲酸PVC增塑剂相比具有较短的聚合时间和较高的增塑效果。

公开(公告)号：US20130225875A1

公开(公告)日：2013-08-29

申请号：US13809132

申请日：2011-07-11

申请人： Christoffer Paulsson ,  Katri Nikkila ,  Hakan Bjornberg

发明人： Christoffer Paulsson ,  Katri Nikkila ,  Hakan Bjornberg

IPC分类号： C07C29/147

CPC分类号： C07C29/147 ,  C07C29/149 ,  C07C31/20

摘要： The present invention refers to a process for hydrogenation of caprolactone and/or its oligomers or polymers to 1,6-hexanediol. The process is performed in liquid phase at a pressure between 100 and 350 bar and is performed in the presence of a catalytically effective amount of at least one catalyst comprising Cu, Mn, Al, Cr, Zn, Ba and/or Zr.

摘要翻译： 本发明涉及将己内酯和/或其低聚物或聚合物氢化成1,6-己二醇的方法。 该方法在100-350巴的压力下在液相中进行，并且在催化有效量的至少一种包含Cu，Mn，Al，Cr，Zn，Ba和/或Zr的催化剂的存在下进行。

公开(公告)号：US08692033B2

公开(公告)日：2014-04-08

申请号：US13809132

申请日：2011-07-11

申请人： Christoffer Paulsson ,  Katri Nikkila ,  Hakan Bjornberg

发明人： Christoffer Paulsson ,  Katri Nikkila ,  Hakan Bjornberg

IPC分类号： C07C27/04

CPC分类号： C07C29/147 ,  C07C29/149 ,  C07C31/20

摘要： The present invention refers to a process for hydrogenation of caprolactone and/or its oligomers or polymers to 1,6-hexanediol. The process is performed in liquid phase at a pressure between 100 and 350 bar and is performed in the presence of a catalytically effective amount of at least one catalyst comprising Cu, Mn, Al, Cr, Zn, Ba and/or Zr.

摘要翻译： 本发明涉及将己内酯和/或其低聚物或聚合物氢化成1,6-己二醇的方法。 该方法在100-350巴的压力下在液相中进行，并且在催化有效量的至少一种包含Cu，Mn，Al，Cr，Zn，Ba和/或Zr的催化剂的存在下进行。