摘要:
The use of endgroup-capped fatty amide alkoxylates I R.sup.1 --CO--NH--(CH.sub.2).sub.n --O--(AO).sub.x --R.sup.2(I) where R.sup.1 is C.sub.5 -C.sub.21 -alkyl or -alkenyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl, A is C.sub.2 -C.sub.4 -alkylene, n is 2 or 3, and x has a value from 1 to 6, as nonionic surfactants or emulsifiers in detergents, cleaners or body care compositions, as surface-active substances for industrial applications in electroplating, in the photographic industry, in petroleum production, in the pharmaceutical industry, in plant feeding and in crop protection formulations, and as surface-active substances in the production of emulsions and pigment and plastic dispersions.
摘要:
Hydroxamic acids and hydroxamic acid ethers I and II ##STR1## where Z.sup.1 and Z.sup.2 are --NH --OY, --NR.sup.1 --OY or --OX, where in the case of (I) at least one of Z.sup.1 or Z.sup.2, and in the case of (II) Z.sup.1 is --NH --OY or --NR.sup.1 --OY, and R.sup.1 is C.sub.1 -C.sub.18 -alkyl, X is hydrogen, alkali metal, ammonium or substituted ammonium, and Y is hydrogen, alkali metal, ammonium, substituted ammonium or C.sub.1 -C.sub.18 -alkyl, and L is a C.sub.1 -C.sub.100 linker which can also carry oxygen and nitrogen functional groups, with the exception of N,N-bis(carboxymethyl)-2-aminoacetohydroxamic acid.
摘要:
Esters of citric acid or acetylcitric anhydride with compounds of at least 3 OH groups selected from the group consisting of polyglycerol, sugarcarboxylic acids, alkyl glucosides, derivatives of oligosaccharides, aminosorbitol, aminodisorbitol, glucosamine, triethanolamine and trishydroxyethylmelamine, each OH group of the alcohol component of the esters being esterified on average with from 0.15 to 1 molecule of citric acid or acetylcitric anhydride, are useful as additives in low-phosphate or phosphate-free detergents.
摘要:
Copolymers of hydroxyalkyl vinyl ethers are obtainable by cationic or free radical copolymerization of(a) from 99 to 1% by weight of a hydroxyalkyl vinyl ether,(b) from 1 to 99% by weight of an adduct of a C.sub.2 -C.sub.4 -alkylene oxide with a hydroxyalkyl vinyl ether and(c) from 0 to 98% by weight of other copolymerizable monomers,and the stated copolymer and hydroxyalkyl vinyl ethers polymerized by cationic or free radical polymerization, which contain the monomers (a) or (b) as sole monomers or as a mixture with other copolymerizable monomers in the form of polymerized units, are used as additives for detergents and cleaning agents in amounts of from 0.1 to 50% by weight.
摘要:
Polyacetals useful as reduced-phosphate or phosphate-free detergent and cleaner additives are obtainable by cationically initiated polyaddition of(a) divinyl ethers and(b) dihydroxy compounds and also, optionally,(c) monohydroxy compoundsand have K values of from 8 to 100.
摘要:
Soluble polyacetals containing acetaldehyde acetal units are obtainable by cationically initiated addition polymerization of(a) compounds containing at least 3 hydroxyl groups, and(b) divinyl ethers containing terminal vinyl ether groups, or mixtures of such divinyl ethers and monovinyl ethers, in the presence or absence of(c) dihydroxy compounds and/or monohydroxy compounds, and are useful as admixture in phosphate-reduced and phosphate-free detergents and cleaners and as dispersant for finely divided minerals.
摘要:
Polyacetals useful as reduced-phosphate or phosphate-free detergent and cleaner additives are obtainable by cationically initiated polyaddition of(a) divinyl ethers and(b) dihydroxy compounds and also, optionally,(c) monohydroxy compoundsand have K values of from 8 to 100.
摘要:
Nickelized shaped articles are produced by electrodeposition of nickel from aqueous acidic baths containing as essential constituents one or more nickel salts, one or more inorganic acids and at least two brighteners by using as brighteners a mixture ofA) from 2 to 98% by weight of one or more cyclic N-allylammonium or N-vinylammonium compounds I ##STR1## where the nitrogen atom is part of a pyridine, quinoline or isoquinoline ring system which may additionally carry one or two C.sub.1 - to C.sub.4 -alkyl substituents or halogen atoms,R.sup.1, R.sup.3 and R.sup.4 are each hydrogen or C.sub.1 - to C.sub.4 -alkyl,R.sup.2 is hydrogen or methyl,m is from 0 to 4,n is from 1 to 4, andX.sup..crclbar. is an n-valent inorganic or organic anion which promotes solubility in water, andB) from 98 to 2% by weight of one or more acetylenically unsaturated compounds IIR.sup.4 --C.tbd.C--R.sup.5 (II) where R.sup.4 and R.sup.5 are identical or different and each is C.sub.1 - to C.sub.4 -alkyl substituted by hydroxyl, sulfo, amino, C.sub.1 - to C.sub.4 -alkylamino or di(C.sub.1 - to C.sub.4 -alkyl)amino, although hydroxyl groups may have been reacted with from 1 to 10 mol of a C.sub.2 - to C.sub.4 -alkylene oxide or a mixture of such alkylene oxides and one of the radicals R.sup.4 and R.sup.5 may also be hydrogen or C.sub.1 - to C.sub.4 -alkyl.
摘要:
Nickel-plated shaped parts are produced by galvanic precipitation of nickel from aqueous-acid baths which contain as essential constituents one or several nickel salts, one or several inorganic acids and one or several brighteners. As brighteners are used thiourea salts having general formula (I), in which R.sup.1 to R.sup.4 stand for hydrogen, C.sub.1 to C.sub.18 -alkyl, which may be substituted by carboxyl groups, C.sub.1 to C.sub.4 -alkoxycarbonyl groups or cyano groups, C.sub.2 to C.sub.12 -alkenyl, C.sub.2 to C.sub.12 -alkinyl, C.sub.5 to C.sub.8 -cycloalkyl, C.sub.7 to C.sub.12 -phenylalkyl or phenyl, which may be substituted by one or two C.sub.1 to C.sub.4 -alkyl residues, C.sub.1 to C.sub.4 -alkoxy residues, halogen atoms, hydroxyl groups, phenyl groups, phenyl residues or C.sub.1 to C.sub.4 alkoxycarbonyl groups; Y sands for a chemical bond or for linear or branched alkylene, alkenylene or alkinylene having each up to 20 C. atoms; A stands for hydrogen or a group having the formulae: --CO--H, --CO--R.sup.5, --CO--OH, --CO--OR.sup.5, --CO--NR.sup.6 R.sup.7, --CO--CH.sub.2 --CO--OR.sup.5, --O--CO--H, --O--CO--R.sup.5, --NR.sup.6 --CO--R.sup.5, --NR.sup.6 --CO--R.sup.5, --OR.sup.5, --SO.sub.2 --R.sup.5, --SO.sub.2 --OH, --SO.sub.2 --OR.sup.5, --PO(PH).sub.2, --PO(OH)(OR.sup.5), --PO(OR.sup.5).sub.2, OPO(OH).sub.2, --OPO(PH)(PR.sup.5) or --OPO(OR.sup.5).sub.2 in which R.sup.5 stands for C.sub.1 to C.sub.12 -alkyl, C.sub.2 to C.sub.12 -alkenyl, C.sub.2 to C.sub.12 -alkinyl, C.sub.5 to C.sub.8 -cycloalkyl, C.sub.7 to C.sub.12 -phenylalkyl or phenyl, which may be substituted by one or two C.sub.1 to C.sub.4 -alkyl residues, halogen atoms, hydroxyl groups, phenyl residues or C.sub.1 to C.sub.4 -alkoxycarbonyl groups; and R.sup.6 and R.sup.7 stand for hydrogen or C.sub.1 to C.sub.4 -alkyl; n is a number from 1 to 4 and X.sub.(--) stands for s water solubility-promoting, n-valent inorganic or organic anion.
摘要:
Nickelized shaped articles are produced by electrodeposition of nickel from aqueous acidic baths containing as essential constituents one or more nickel salts, one or more inorganic acids and one or more brighteners by a procedure in which the brighteners used are phosphonium salts I ##STR1## where R.sup.1 to R.sup.3 are each C.sub.1 -C.sub.18 -alkyl, which may be carboxyl-, C.sub.1 -C.sub.4 -alkoxycarbonyl- or cyano-substituted, C.sub.2 -C.sub.12 -alkenyl, C.sub.2 -C.sub.12 -alkynyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.12 -phenylalkyl, phenyl, which may be substituted by one or two substituents selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogen, hydroxyl, phenyl and C.sub.1 -C.sub.4 -alkoxycarbonyl, or mono- or di(C.sub.1 -C.sub.4 -alkyl)amino,R.sup.4 and R.sup.5 are each hydrogen or C.sub.1 -C.sub.4 -alkyl,A is hydrogen or a group of the formula --CO--H, --CO--R.sup.6, --CO--OH, --CO--OR.sup.6, --CO--CH.sub.2 --CO--OR.sup.6, --O--CO--H, --O--CO--R.sup.6, --OR.sup.6, --SO.sub.2 --R.sup.6, --SO.sub.2 --OH, --SO.sub.2 --OR.sup.6, --PO(OH).sub.2, --PO(OH)(OR.sup.6), --PO(OR.sup.6).sub.2, --OPO(OH).sub.2, --OPO(OH)(OR.sup.6) or --OPO(OR.sup.6).sub.2, whereR.sup.6 is C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.12 -alkenyl, C.sub.2 -C.sub.12 -alkynyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.12 -phenylalkyl or phenyl, which may be substituted by one or two substituents selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogen, hydroxyl, phenyl and C.sub.1 -C.sub.4 -alkoxycarbonyl,Y is --CH.dbd.CH-- or --C.dbd.C--,m is from 0 to 10,n is from 1 to 4,p is 0 or 1,q is from 0 to 10, andX.sup..crclbar. is an n-valent inorganic or organic anion that promotes solubility in water.