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    Magnesium Energy Storage Device Having a Semi-Solid Positive Electrode
    2.
    发明申请
    Magnesium Energy Storage Device Having a Semi-Solid Positive Electrode 审中-公开
    具有半固体正极的镁储能装置

    公开(公告)号：US20140302422A1

    公开(公告)日：2014-10-09

    申请号：US13937515

    申请日：2013-07-09

    申请人： BATTELLE MEMORIAL INSTITUTE

    发明人： Yuyan Shao ,  Jun Liu ,  Guosheng Li ,  Tianbiao Liu

    IPC分类号： H01M8/02 ,  H01M8/18 ,  H01M8/20

    CPC分类号： H01M8/20 ,  H01M8/188 ,  H01M8/225 ,  Y02E60/528

    摘要： Magnesium energy storage devices that take advantage of magnesium-based anodes while maintaining practical energy densities can be useful for large-scale energy storage as well as other applications. One such device can include a negative electrode having magnesium and a positive electrode material that can flow in a batch or continuous manner. The flowable positive electrode material can result in an increased practical energy density because the fresh active material can be flowed to the positive electrode, and as a result can be theoretically infinite in size. The positive electrode can include a cathode suspension contacting a positive current collector and having particulates of a cathode magnesium intercalation compound, a cathode magnesium conversion compound, a redox active species, or combinations thereof.

    摘要翻译： 利用镁基阳极同时保持实际能量密度的镁储能装置对于大规模储能以及其它应用是有用的。 一种这样的装置可以包括具有镁的负极和可以分批或连续流动的正电极材料。 可流动的正极材料可以导致增加的实际能量密度，因为新鲜的活性材料可以流到正极，结果在理论上可以是无限大小的。 正极可以包括与正极集电器接触并具有阴极镁插入化合物，阴极镁转化化合物，氧化还原活性物质或其组合的微粒的阴极悬浮液。

    Magnesium-Based Energy Storage Systems and Methods Having Improved Electrolytes
    3.
    发明申请
    Magnesium-Based Energy Storage Systems and Methods Having Improved Electrolytes 有权
    具有改进电解质的镁基储能系统和方法

    公开(公告)号：US20140302404A1

    公开(公告)日：2014-10-09

    申请号：US14084075

    申请日：2013-11-19

    申请人： BATTELLE MEMORIAL INSTITUTE

    发明人： Tianbiao Liu ,  Guosheng Li ,  Jun Liu ,  Yuan Shao

    IPC分类号： H01M10/0568 ,  H01M10/054

    CPC分类号： H01M10/0568 ,  H01M10/054

    摘要： Electrolytes for Mg-based energy storage devices can be formed from non-nucleophilic Mg2+ sources to provide outstanding electrochemical performance and improved electrophilic susceptibility compared to electrolytes employing nucleophilic sources. The instant electrolytes are characterized by high oxidation stability (up to 3.4 V vs Mg), improved electrophile compatibility and electrochemical reversibility (up to 100% coulombic efficiency). Synthesis of the Mg2+ electrolytes utilizes inexpensive and safe magnesium dihalides as non-nucleophilic Mg2+ sources in combination with Lewis acids, MRaX3-a (for 3≧a≧1). Furthermore, addition of free-halide-anion donors can improve the coulombic efficiency of Mg electrolytes from nucleophilic or non-nucleophilic Mg2+ sources.

    摘要翻译： 用于Mg基能量储存装置的电解质可以由非亲核Mg 2+源形成，以提供与使用亲核源的电解质相比优异的电化学性能和改善的亲电子敏感性。 瞬时电解质的特征在于高氧化稳定性（高达3.4V对Mg），改善的亲电子相容性和电化学可逆性（高达100％的库仑效率）。 Mg2 +电解质的合成使用廉价和安全的二卤化镁作为非路易斯酸MRaX3-a（对于3≥a≥1）的非亲核Mg 2+源。 此外，添加游离卤化物 - 阴离子供体可以提高Mg电解质从亲核或非亲核Mg2 +来源的库仑效率。

    Magnesium-based energy storage systems and methods having improved electrolytes
    7.
    发明授权
    Magnesium-based energy storage systems and methods having improved electrolytes 有权
    镁基能量储存系统和方法具有改进的电解质

    公开(公告)号：US09525191B2

    公开(公告)日：2016-12-20

    申请号：US14084075

    申请日：2013-11-19

    申请人： BATTELLE MEMORIAL INSTITUTE

    发明人： Tianbiao Liu ,  Guosheng Li ,  Jun Liu ,  Yuyan Shao

    IPC分类号： H01M10/054 ,  H01M10/0568

    CPC分类号： H01M10/0568 ,  H01M10/054

    摘要： Electrolytes for Mg-based energy storage devices can be formed from non-nucleophilic Mg2+ sources to provide outstanding electrochemical performance and improved electrophilic susceptibility compared to electrolytes employing nucleophilic sources. The instant electrolytes are characterized by high oxidation stability (up to 3.4 V vs Mg), improved electrophile compatibility and electrochemical reversibility (up to 100% coulombic efficiency). Synthesis of the Mg2+ electrolytes utilizes inexpensive and safe magnesium dihalides as non-nucleophilic Mg2+ sources in combination with Lewis acids, MRaX3-a (for 3≧a≧1). Furthermore, addition of free-halide-anion donors can improve the coulombic efficiency of Mg electrolytes from nucleophilic or non-nucleophilic Mg2+ sources.

    摘要翻译： 用于Mg基能量储存装置的电解质可以由非亲核Mg 2+源形成，以提供与使用亲核源的电解质相比优异的电化学性能和改善的亲电子敏感性。 瞬时电解质的特征在于高氧化稳定性（高达3.4V对Mg），改善的亲电子相容性和电化学可逆性（高达100％的库仑效率）。 Mg2 +电解质的合成使用廉价和安全的二卤化镁作为非路易斯酸MRaX3-a（对于3≥a≥1）的非亲核Mg 2+源。 此外，添加游离卤化物 - 阴离子供体可以提高Mg电解质从亲核或非亲核Mg2 +来源的库仑效率。

    AQUEOUS ELECTROLYTES FOR REDOX FLOW BATTERY SYSTEMS
    8.
    发明申请
    AQUEOUS ELECTROLYTES FOR REDOX FLOW BATTERY SYSTEMS 有权
    用于REDOX流量电池系统的水溶性电解质

    公开(公告)号：US20160308233A1

    公开(公告)日：2016-10-20

    申请号：US14690224

    申请日：2015-04-17

    申请人： Battelle Memorial Institute

    发明人： Tianbiao Liu ,  Bin Li ,  Xiaoliang Wei ,  Zimin Nie ,  Wei Wang ,  Jun Liu ,  Vincent L. Sprenkle

    IPC分类号： H01M8/18 ,  H01M8/20

    CPC分类号： H01M8/188 ,  H01M8/20 ,  H01M2300/0002 ,  Y02E60/528

    摘要： An aqueous redox flow battery system includes an aqueous catholyte and an aqueous anolyte. The aqueous catholyte may comprise (i) an optionally substituted thiourea or a nitroxyl radical compound and (ii) a catholyte aqueous supporting solution. The aqueous anolyte may comprise (i) metal cations or a viologen compound and (ii) an anolyte aqueous supporting solution. The catholyte aqueous supporting solution and the anolyte aqueous supporting solution independently may comprise (i) a proton source, (ii) a halide source, or (iii) a proton source and a halide source.

    摘要翻译： 水性氧化还原液流电池系统包括水性阴极电解液和阳极电解液。 含水阴极电解液可以包含（i）任选取代的硫脲或硝酰自由基化合物和（ii）阴极电解液水性支持溶液。 水性阳极电解液可以包含（i）金属阳离子或紫色化合物和（ii）阳极电解液水性支持溶液。 阴极电解液水性支持溶液和阳极电解液水性支持溶液独立地可以包括（i）质子源，（ii）卤素源，或（iii）质子源和卤素源。