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公开(公告)号：US11532832B2
公开(公告)日：2022-12-20
申请号：US16859142
申请日：2020-04-27
发明人： Zimin Nie , Wei Wang , Xiaoliang Wei , Bin Li , Jun Liu , Vincent L. Sprenkle
摘要： All-vanadium sulfate redox flow battery systems have a catholyte and an anolyte comprising an aqueous supporting solution including chloride ions and phosphate ions. The aqueous supporting solution stabilizes and increases the solubility of vanadium species in the electrolyte, allowing an increased vanadium concentration over a desired operating temperature range. According to one example, the chloride ions are provided by MgCl2, and the phosphate ions are provided by (NH4)2HPO4.
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公开(公告)号：US10673090B2
公开(公告)日：2020-06-02
申请号：US14875565
申请日：2015-10-05
发明人： Zimin Nie , Wei Wang , Xiaoliang Wei , Bin Li , Jun Liu , Vincent L. Sprenkle
摘要： All-vanadium sulfate redox flow battery systems have a catholyte and an anolyte comprising an aqueous supporting solution including chloride ions and phosphate ions. The aqueous supporting solution stabilizes and increases the solubility of vanadium species in the electrolyte, allowing an increased vanadium concentration over a desired operating temperature range. According to one example, the chloride ions are provided by MgCl2, and the phosphate ions are provided by (NH4)2HPO4.
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公开(公告)号：US10454124B2
公开(公告)日：2019-10-22
申请号：US15625750
申请日：2017-06-16
发明人： Xiaoliang Wei , Wei Wang , Aaron M. Hollas , Vincent L. Sprenkle , Zimin Nie , Bin Li
IPC分类号： H01M8/18 , H01M4/90 , C07D241/46 , H01M8/08 , H01M4/96
摘要： Embodiments of an aqueous electrolyte comprising a base and a phenazine derivative are disclosed. Redox flow batteries including the aqueous electrolyte are also disclosed. The phenazine derivative has a chemical structure according to formula I:
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4.发明授权公开(公告)号：US09236620B2
公开(公告)日：2016-01-12
申请号：US13668604
申请日：2012-11-05
发明人： Bin Li , Xiaoliang Wei , Qingtao Luo , Zimin Nie , Wei Wang , Vincent L. Sprenkle
CPC分类号： H01M8/0243 , H01M8/0289 , H01M8/04186 , H01M8/188 , H01M8/20 , Y02E60/528
摘要： Composite separators having a porous structure and including acid-stable, hydrophilic, inorganic particles enmeshed in a substantially fully fluorinated polyolefin matrix can be utilized in a number of applications. The inorganic particles can provide hydrophilic characteristics. The pores of the separator result in good selectivity and electrical conductivity. The fluorinated polymeric backbone can result in high chemical stability. Accordingly, one application of the composite separators is in redox flow batteries as low cost membranes. In such applications, the composite separator can also enable additional property-enhancing features compared to ion-exchange membranes. For example, simple capacity control can be achieved through hydraulic pressure by balancing the volumes of electrolyte on each side of the separator. While a porous separator can also allow for volume and pressure regulation, in RFBs that utilize corrosive and/or oxidizing compounds, the composite separators described herein are preferable for their robustness in the presence of such compounds.
摘要翻译： 具有多孔结构并且包含在基本上完全氟化的聚烯烃基质中的酸稳定的，亲水的无机颗粒的复合隔膜可用于许多应用中。 无机颗粒可以提供亲水性。 分离器的孔导致良好的选择性和导电性。 氟化聚合物骨架可导致高的化学稳定性。 因此，复合隔板的一个应用是作为低成本膜的氧化还原液流电池。 在这种应用中，与离子交换膜相比，复合分离器还可以实现额外的性能增强特征。 例如，通过平衡分离器两侧的电解液的体积，可以通过液压来实现简单的容量控制。 虽然多孔分离器还可以允许体积和压力调节，但是在使用腐蚀性和/或氧化性化合物的RFB中，本文所述的复合隔膜在其存在下的稳健性是优选的。
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公开(公告)号：US20160308233A1
公开(公告)日：2016-10-20
申请号：US14690224
申请日：2015-04-17
发明人： Tianbiao Liu , Bin Li , Xiaoliang Wei , Zimin Nie , Wei Wang , Jun Liu , Vincent L. Sprenkle
CPC分类号： H01M8/188 , H01M8/20 , H01M2300/0002 , Y02E60/528
摘要： An aqueous redox flow battery system includes an aqueous catholyte and an aqueous anolyte. The aqueous catholyte may comprise (i) an optionally substituted thiourea or a nitroxyl radical compound and (ii) a catholyte aqueous supporting solution. The aqueous anolyte may comprise (i) metal cations or a viologen compound and (ii) an anolyte aqueous supporting solution. The catholyte aqueous supporting solution and the anolyte aqueous supporting solution independently may comprise (i) a proton source, (ii) a halide source, or (iii) a proton source and a halide source.
摘要翻译： 水性氧化还原液流电池系统包括水性阴极电解液和阳极电解液。 含水阴极电解液可以包含（i）任选取代的硫脲或硝酰自由基化合物和（ii）阴极电解液水性支持溶液。 水性阳极电解液可以包含（i）金属阳离子或紫色化合物和（ii）阳极电解液水性支持溶液。 阴极电解液水性支持溶液和阳极电解液水性支持溶液独立地可以包括（i）质子源，（ii）卤素源，或（iii）质子源和卤素源。
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公开(公告)号：US20160099480A1
公开(公告)日：2016-04-07
申请号：US14875565
申请日：2015-10-05
发明人： Zimin Nie , Wei Wang , Xiaoliang Wei , Bin Li , Jun Liu , Vincent L. Sprenkle
摘要： All-vanadium sulfate redox flow battery systems have a catholyte and an anolyte comprising an aqueous supporting solution including chloride ions and phosphate ions. The aqueous supporting solution stabilizes and increases the solubility of vanadium species in the electrolyte, allowing an increased vanadium concentration over a desired operating temperature range. According to one example, the chloride ions are provided by MgCl2, and the phosphate ions are provided by (NH4)2HPO4.
摘要翻译： 全硫酸钒氧化还原液电池系统具有阴极电解液和阳极电解液，其包含含有氯离子和磷酸根离子的水性支持溶液。 含水载体溶液稳定并提高钒物质在电解质中的溶解度，允许在所需工作温度范围内提高钒浓度。 根据一个实例，氯离子由MgCl 2提供，磷酸根离子由（NH 4）2 HPO 4提供。
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7.发明申请公开(公告)号：US20140127542A1
公开(公告)日：2014-05-08
申请号：US13668604
申请日：2012-11-05
发明人： Bin Li , Xiaoliang Wei , Qingtao Luo , Zimin Nie , Wei Wang , Vincent L. Sprenkle
CPC分类号： H01M8/0243 , H01M8/0289 , H01M8/04186 , H01M8/188 , H01M8/20 , Y02E60/528
摘要： Composite separators having a porous structure and including acid-stable, hydrophilic, inorganic particles enmeshed in a substantially fully fluorinated polyolefin matrix can be utilized in a number of applications. The inorganic particles can provide hydrophilic characteristics. The pores of the separator result in good selectivity and electrical conductivity. The fluorinated polymeric backbone can result in high chemical stability. Accordingly, one application of the composite separators is in redox flow batteries as low cost membranes. In such applications, the composite separator can also enable additional property-enhancing features compared to ion-exchange membranes. For example, simple capacity control can be achieved through hydraulic pressure by balancing the volumes of electrolyte on each side of the separator. While a porous separator can also allow for volume and pressure regulation, in RFBs that utilize corrosive and/or oxidizing compounds, the composite separators described herein are preferable for their robustness in the presence of such compounds.
摘要翻译： 具有多孔结构并且包含在基本上完全氟化的聚烯烃基质中的酸稳定的，亲水的无机颗粒的复合隔膜可用于许多应用中。 无机颗粒可以提供亲水性。 分离器的孔导致良好的选择性和导电性。 氟化聚合物骨架可导致高的化学稳定性。 因此，复合隔板的一个应用是作为低成本膜的氧化还原液流电池。 在这种应用中，与离子交换膜相比，复合分离器还可以实现额外的性能增强特征。 例如，通过平衡分离器两侧的电解液的体积，可以通过液压来实现简单的容量控制。 虽然多孔分离器还可以允许体积和压力调节，但是在使用腐蚀性和/或氧化性化合物的RFB中，本文所述的复合隔膜在其存在下的稳健性是优选的。
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公开(公告)号：US09793566B2
公开(公告)日：2017-10-17
申请号：US14690224
申请日：2015-04-17
发明人： Tianbiao Liu , Bin Li , Xiaoliang Wei , Zimin Nie , Wei Wang , Jun Liu , Vincent L. Sprenkle
CPC分类号： H01M8/188 , H01M8/20 , H01M2300/0002 , Y02E60/528
摘要： An aqueous redox flow battery system includes an aqueous catholyte and an aqueous anolyte. The aqueous catholyte may comprise (i) an optionally substituted thiourea or a nitroxyl radical compound and (ii) a catholyte aqueous supporting solution. The aqueous anolyte may comprise (i) metal cations or a viologen compound and (ii) an anolyte aqueous supporting solution. The catholyte aqueous supporting solution and the anolyte aqueous supporting solution independently may comprise (i) a proton source, (ii) a halide source, or (iii) a proton source and a halide source.
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9.发明申请High-Energy-Density, Nonaqueous, Redox Flow Batteries Having Iodine-based Species 审中-公开高能密度，非水，氧化还原电池具有碘基物种公开(公告)号：US20150349369A1
公开(公告)日：2015-12-03
申请号：US14294391
申请日：2014-06-03
发明人： Bin Li , Xiaoliang Wei , Zimin Nie , Wei Wang , Jun Liu , Vincent L. Sprenkle
CPC分类号： H01M8/188 , H01M8/04186 , H01M8/1009 , H01M8/20 , H01M8/225 , H01M2300/0017 , H01M2300/0034 , H01M2300/0037 , Y02E60/528
摘要： Nonaqueous redox flow batteries (RFBs) can utilize a metal and a cation of the metal (Mn+) as an active redox couple for a first electrode and electrolyte, respectively, in a first half-cell. The RFBs can also utilize a second electrolyte having I-based species. The I-based species can be selected from the group consisting of I− anions, I2, anions of Ix (x≧3), or combinations thereof. Two different ones of the I-based species compose a second redox active couple in the second half cell.
摘要翻译： 非水氧化还原液流电池（RFB）可以在第一个半电池中分别利用金属（Mn +）的金属和阳离子作为第一电极和电解质的活性氧化还原对。 RFB还可以利用具有基于I的物质的第二电解质。 基于I的物质可以选自I-阴离子，I2，Ix（x≥3）的阴离子或其组合。 两种不同的基于I的物种在第二个半电池中组成第二个氧化还原活性偶。
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公开(公告)号：US20130273459A1
公开(公告)日：2013-10-17
申请号：US13912516
申请日：2013-06-07
发明人： Wu Xu , Lelia Cosimbescu , Xiaoliang Wei , Wei Wang , Vincent L. Sprenkle
CPC分类号： H01M8/188 , H01M8/20 , H01M12/08 , Y02E60/128
摘要： Ionic conductive chromophores can be used as the positive electrolytes for high-energy density, nonaqueous redox flow battery (NRFB) systems. The nonaqueous nature of the NRFB systems allow for high operation voltage (compared to aqueous systems). Furthermore, the structure modifications to chromophores described herein improve the solubility of the resultant ionic conductive chromophores, thereby allowing them to be used in flow cell configurations.
摘要翻译： 离子导电发色团可用作高能密度正电解质，非水氧化还原电池（NRFB）系统。 NRFB系统的非水性质允许高操作电压（与含水体系相比）。 此外，本文所述的对发色团的结构修饰改善了所得离子导电发色团的溶解度，从而允许它们用于流动池构型。
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