Silicon-oxygen composite negative electrode material and method for preparation thereof and lithium-ion battery

    公开(公告)号:US12183919B2

    公开(公告)日:2024-12-31

    申请号:US17420570

    申请日:2020-10-28

    Abstract: The present application provides a silicon-oxygen composite negative electrode material and method for preparation thereof and lithium-ion battery. The silicon-oxygen composite negative electrode material comprises a silicon-oxygen composite negative electrode material comprising SiOx, non-Li2Si2O5 lithium-containing compound, and Li2Si2O5; said Li2Si2O5 is coated on the surface of the non-Li2Si2O5 lithium-containing compound; 0≤x≤1.2. The preparation method comprises: mixing a first silicon source with a reducing lithium source and roasting, to obtain a composite material containing a non-Li2Si2O5 lithium-containing compound; the composite material containing the non-Li2Si2O5 lithium-containing compound is fused with a second silicon source and then subjected to heat treatment to obtain a silicon-oxygen composite negative electrode material. The silicon-oxygen composite anode material provided by the present application is coated with Li2Si2O5, solving the problem in the prior art of a negative electrode material producing strong alkaline or easily soluble by-products in water after pre-lithiation and affecting subsequent processing.

    GRAPHITE NEGATIVE ELECTRODE MATERIAL AND PREPARATION METHOD THEREOF AND LITHIUM ION BATTERY

    公开(公告)号:US20240021821A1

    公开(公告)日:2024-01-18

    申请号:US18372200

    申请日:2023-09-25

    CPC classification number: H01M4/583 H01M4/0471 H01M2004/021

    Abstract: The present disclosure relates to a graphite negative electrode material and a preparation method thereof and a lithium ion battery, wherein the graphite negative electrode material includes spherical graphite and a carbon coating layer, the carbon coating layer includes an M element-containing modifying group, where M is at least one selected from the group consisting of B, N, and P. The preparation method of a graphite negative electrode material includes performing a thermal polymerization treatment on a mixture containing spherical graphite, a coating agent, and a modifying additive, to obtain a precursor, wherein modifying additive includes an element M-containing compound, and M is at least one selected from the group consisting of B, N, and P; and performing a carbonization treatment on the precursor under a protective atmosphere, to obtain the graphite negative electrode material.

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