公开(公告)号：US11189806B2

公开(公告)日：2021-11-30

申请号：US16294403

申请日：2019-03-06

Applicant: BASF SE ,  OLEDWORKS GMBH ,  OSRAM OLED GMBH

Inventor： Evelyn Fuchs ,  Oliver Molt ,  Korinna Dormann ,  Thomas Gessner ,  Nicolle Langer ,  Ingo Muenster ,  JianQiang Qu ,  Christian Lennartz ,  Christian Schildknecht ,  Soichi Watanabe ,  Gerhard Wagenblast ,  Guenter Schmid ,  Herbert Friedrich Boerner ,  Volker van Elsbergen

IPC: H01L51/00 ,  C07F15/00 ,  H01L51/50

Abstract: The present invention relates to heteroleptic complexes comprising a phenylimidazole or phenyltriazole unit bonded via a carbene bond to a central metal atom, and phenylimidazole ligands attached via a nitrogen-metal bond to the central atom, to OLEDs which comprise such heteroleptic complexes, to light-emitting layers comprising at least one such heteroleptic complex, to a device selected from the group consisting of illuminating elements, stationary visual display units and mobile visual display units comprising such an OLED, to the use of such a heteroleptic complex in OLEDs, for example as emitter, matrix material, charge transport material and/or charge blocker.

公开(公告)号：US11871654B2

公开(公告)日：2024-01-09

申请号：US17526503

申请日：2021-11-15

Applicant: BASF SE ,  OLEDWORKS GMBH ,  OSRAM OLEO GMBH

Inventor： Evelyn Fuchs ,  Oliver Molt ,  Korinna Dormann ,  Thomas Gessner ,  Nicolle Langer ,  Ingo Muenster ,  JianQiang Qu ,  Christian Lennartz ,  Christian Schildknecht ,  Soichi Watanabe ,  Gerhard Wagenblast ,  Guenter Schmid ,  Herbert Friedrich Boerner ,  Volker van Elsbergen

IPC: H01L51/50 ,  H10K85/30 ,  C07F15/00 ,  H10K50/11 ,  H10K50/14 ,  H10K85/40 ,  H10K85/60

CPC classification number: H10K85/342 ,  C07F15/0033 ,  C07F15/0086 ,  H10K85/361 ,  H10K50/11 ,  H10K50/14 ,  H10K85/40 ,  H10K85/6572

Abstract: The present invention relates to heteroleptic complexes comprising a phenylimidazole or phenyltriazole unit bonded via a carbene bond to a central metal atom, and phenylimidazole ligands attached via a nitrogen-metal bond to the central atom, to OLEDs which comprise such heteroleptic complexes, to light-emitting layers comprising at least one such heteroleptic complex, to a device selected from the group consisting of illuminating elements, stationary visual display units and mobile visual display units comprising such an OLED, to the use of such a heteroleptic complex in OLEDs, for example as emitter, matrix material, charge transport material and/or charge blocker.

公开(公告)号：US20150243907A1

公开(公告)日：2015-08-27

申请号：US14427134

申请日：2013-09-18

Applicant: BASF SE

Inventor： Annemarie Wolleb ,  Thomas Schaefer ,  Heinz Wolleb ,  Ute Heinemeyer ,  Nicolle Langer ,  Christian Lennartz ,  Gerhard Wagenblast ,  Soichi Watanabe ,  Flavio Luiz Benedito ,  Heinz Hottinger ,  Oliver Dosenbach

IPC: H01L51/00 ,  C09K11/06 ,  C09K11/02 ,  C07D519/00

CPC classification number: H01L51/0072 ,  C07D209/86 ,  C07D405/04 ,  C07D405/14 ,  C07D487/04 ,  C07D491/048 ,  C07D491/147 ,  C07D519/00 ,  C07F7/0814 ,  C09B57/00 ,  C09B57/008 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1048 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/185 ,  H01L51/0054 ,  H01L51/0058 ,  H01L51/0071 ,  H01L51/0073 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5056 ,  H01L51/5088 ,  H01L51/5092 ,  H01L51/5206 ,  H01L2251/308 ,  Y02E10/549 ,  Y02P70/521

Abstract: The present invention relates to compounds of formula (I), which are characterized in that they substituted by benzimidazo[1,2-a]benzimidazo-5-yl and/or benzimidazo[1,2-a]benzimidazo-2,5-ylene groups and in that at least one of the substituents B1, B2, B3, B4, B5, B6, B7 and B8 represents N; a process for their production and their use in electronic devices, especially electroluminescent devices. When used as host material for phosphorescent emitters in electroluminescent devices, the compounds of formula I may provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.

Abstract translation: 本发明涉及式（I）化合物，其特征在于它们被苯并咪唑并[1,2-a]苯并咪唑-5-基和/或苯并咪唑并[1,2-a]苯并咪唑-2-基 并且取代基B1，B2，B3，B4，B5，B6，B7和B8中的至少一个表示N; 它们的制造方法及其在电子器件中的应用，特别是电致发光器件。 当用作电致发光器件中的磷光发射体的主体材料时，式I化合物可以提供电致发光器件的改进的效率，稳定性，可制造性或光谱特性。

公开(公告)号：US20140252280A1

公开(公告)日：2014-09-11

申请号：US14352861

申请日：2012-11-07

Applicant: BASF SE

Inventor： Thomas Schaefer ,  Ute Heinemeyer ,  Nicolle Langer ,  Annemarie Wolleb ,  Christian Lennartz ,  Soichi Watanabe ,  Teresa Marina Figueira Duarte ,  Gerhard Wagenblast ,  Didier Bauer ,  Ingo Muenster ,  Christian Schildknecht ,  Heinz Wolleb

IPC: H01L51/00

CPC classification number: H01L51/0067 ,  C07D487/04 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  H01L51/0072 ,  H05B33/10 ,  H05B33/14

Abstract: The present invention relates to compounds of formula (I), a process for their production and their use in electronic devices, especially electroluminescent devices. When used as electron transport and/or host material for phosphorescent emitters in electroluminescent devices, the compounds of formula I may provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.

Abstract translation: 本发明涉及式（I）化合物，其制备方法及其在电子器件，特别是电致发光器件中的应用。 当用作电致发光器件中的磷光发射体的电子传输和/或主体材料时，式I化合物可以提供电致发光器件的改进的效率，稳定性，可制造性或光谱特性。

公开(公告)号：US09502664B2

公开(公告)日：2016-11-22

申请号：US14352861

申请日：2012-11-07

Applicant: BASF SE

Inventor： Thomas Schaefer ,  Ute Heinemeyer ,  Nicolle Langer ,  Annemarie Wolleb ,  Christian Lennartz ,  Soichi Watanabe ,  Teresa Marina Figueira Duarte ,  Gerhard Wagenblast ,  Didier Bauer ,  Ingo Muenster ,  Christian Schildknecht ,  Heinz Wolleb

IPC: H01L51/50 ,  H01L51/00 ,  C07D487/04 ,  C09K11/06 ,  C09B57/00 ,  H05B33/10 ,  H05B33/14

CPC classification number: H01L51/0067 ,  C07D487/04 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  H01L51/0072 ,  H05B33/10 ,  H05B33/14

Abstract: The present invention relates to compounds of formula (I), a process for their production and their use in electronic devices, especially electroluminescent devices. When used as electron transport and/or host material for phosphorescent emitters in electroluminescent devices, the compounds of formula I may provide improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices.

公开(公告)号：US20150318501A1

公开(公告)日：2015-11-05

申请号：US14440637

申请日：2013-11-06

Applicant: BASF SE

Inventor： Soichi Watanabe ,  Christian Lennartz ,  Gerhard Wagenblast ,  Nicolle Langer ,  Junji Kido ,  Hisahiro Sasabe ,  Masato Kimura

IPC: H01L51/00 ,  C07F9/6596 ,  C07F7/08

CPC classification number: H01L51/0069 ,  C07F7/0816 ,  C07F9/6596 ,  H01L51/0058 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0085 ,  H01L51/0094 ,  H01L51/5012 ,  H01L51/5024 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5088 ,  H01L51/5092 ,  H01L51/5096 ,  H01L51/5206 ,  H01L51/5221 ,  H01L2251/5384 ,  Y02E10/549 ,  Y02P20/582

Abstract: Organic electronics applications, especially an organic light-emitting diode (OLED), an organic solar cell (organic photovoltaics) or a switching element such as an organic transistor, for example an organic FET (Field Effect Transistor) and an organic TFT (Thin Film Transistor), comprising at least one substituted phenoxasiline derivative, a organic semiconductor layer, a host material, electron/hole/exciton blocking material or electron/hole injection material comprising at least one substituted phenoxasiline derivative, the use of a substituted phenoxasiline derivative in organic electronics applications, an organic light-emitting diode, wherein at least one substituted phenoxasiline derivative is present in the electron/hole/exciton blocking layer, the electron/hole injection layer and/or the light-emitting layer, a light-emitting layer, an electron/hole/exciton blocking layer and an electron/hole injection layer comprising at least one substituted phenoxasiline derivative and a device selected from the group consisting of stationary visual display units, mobile visual display units; illumination units; keyboards; garments; furniture and wallpaper comprising at least one organic light-emitting diode, at least one light-emitting layer, at least one electron/hole/exciton blocking layer and/or at least one electron/hole injection layer according to the present invention.

Abstract translation: 有机电子应用，特别是有机发光二极管（OLED），有机太阳能电池（有机光伏））或诸如有机晶体管的开关元件，例如有机FET（场效应晶体管）和有机TFT（薄膜 晶体管），其包含至少一种取代的苯氧苯胺衍生物，有机半导体层，主体材料，电子/空穴/激子阻挡材料或包含至少一种取代的苯氧苯胺衍生物的电子/空穴注入材料，使用取代的苯氧苯胺衍生物在有机 电子应用，有机发光二极管，其中至少一种取代的苯氧苯胺衍生物存在于电子/空穴/激子阻挡层，电子/空穴注入层和/或发光层中，发光层， 电子/空穴/激子阻挡层和包含至少一种取代的苯氧苯胺衍生物和电子/空穴注入层的电子/空穴注入层 选自静态视觉显示单元，移动视觉显示单元; 照明单位 键盘; 服装; 包括至少一个有机发光二极管，至少一个发光层，至少一个电子/空穴/激子阻挡层和/或至少一个电子/空穴注入层的家具和壁纸。

公开(公告)号：US20150207083A1

公开(公告)日：2015-07-23

申请号：US14413736

申请日：2013-07-08

Applicant: BASF SE

Inventor： Thomas Schaefer ,  Flavio Luiz Benedito ,  Ute Heinemeyer ,  Nicolle Langer ,  Heinz Wolleb ,  Teresa Figueira Duarte ,  Soichi Watanabe ,  Christian Lennartz ,  Gerhard Wagenblast ,  Annemarie Wolleb ,  Kristina Bardon

IPC: H01L51/00 ,  G03G5/06 ,  C07D487/04

CPC classification number: H01L51/0072 ,  C07D487/04 ,  C07D519/00 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1074 ,  C09K2211/185 ,  G03G5/0661 ,  H01L51/00 ,  H01L51/0054 ,  H01L51/0073 ,  H01L51/0077 ,  H01L51/0085 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5056 ,  H01L51/5096 ,  H05B33/00 ,  Y02E10/549 ,  Y02P70/521

Abstract: A compound of the general formula a process for the production of the compound and its use in electronic devices, especially electroluminescent devices. Improved efficiency, stability, manufacturability, or spectral characteristics of electroluminescent devices are provided when the compound of formula I is used as host material for phosphorescent emitters in electroluminescent devices.

Abstract translation: 通式的化合物是用于生产化合物的方法及其在电子器件中的用途，特别是电致发光器件。 当式I的化合物用作电致发光器件中的磷光发射体的主体材料时，提供电致发光器件的效率，稳定性，可制造性或光谱特性的改进。