Abstract:
An adhesive label is described comprising a backing material, a pressure-sensitive adhesive layer attached to the backing material and either a release liner attached to the adhesive layer or a release coating on the other side of the backing material. The backing material is made of paper or home compostable and biodegradable polymer film, and the pressure-sensitive adhesive layer is made from an aqueous polyurethane dispersion pressure-sensitive adhesive. At least 60% by weight of the polyurethane is composed of diisocyanates, polyesterdiols, and at least one bifunctional carboxylic acid selected from di hydroxy carboxylic acids and diamino carboxylic acids, wherein the polyurethane has no melting point above 20° C. or wherein the polyurethane has a melting point above 20° C. with an enthalpy of fusion lower than 10 J/g, and wherein a film of the polyurethane adhesive preferably decomposes at home compost conditions to more than 90% by weight into CO2 and water within 360 days.
Abstract:
Plasticizer migration-resistant, UV-curable hotmelt adhesive for graphics films and labels made of plasticized PVCDescribed here is a UV-curable hotmelt adhesive largely resistant to plasticizer migration and comprising a UV-crosslinkable poly(meth)acrylate formed from methyl acrylate, C4-18 alkyl (meth)acrylate, monomer with acid groups, copolymerized photoinitiator and optionally further monomers. The hotmelt adhesive further comprises an aliphatic polyester polymer. The use of the hotmelt adhesive on graphics films and self-adhesive labels made of plasticized PVC is also described.
Abstract:
A description is given of a nonaqueous sound deadener composition comprising (a) a nonpulverulent polyacrylate binder having a K value in the range from 10 to 35, measured as a 1% strength solution in tetrahydrofuran; (b) inorganic fillers; and a radically polymerizable compound which has at least one radically polymerizable C—C double bond and possesses a boiling point at atmospheric pressure of greater than 160° C. Also described is a method for damping oscillations or vibrations of components of vehicles and machines, using the sound deadener composition of the invention.
Abstract:
A process for continuously preparing a polymer by free-radical polymerization, the process includes: continuously feeding to a reactor a mixture including about 20 wt % to about 96 wt % of a vinylic monomer, the vinylic monomer comprising a styrenic monomer, a (meth)acrylic monomer, or a mixture thereof, greater than 0 wt % to about 0.25 wt % of a polymerization initiator, and about 4 wt % to about 80 wt % of a reaction solvent; maintaining the reactor at a temperature from about 120° C. to about 190° C.; and collecting the polymer; where the polymer has a weight average molecular weight (Mw) from 20,000 g/mol to about 300,000 g/mol.
Abstract:
What are described are copolymers formed from (a) at least one monomer M1 of the formula in which R1 is an organic radical having a (meth)acryloyl group, R2, R3 and R4 are each independently a hydrogen atom or a C1- to C10-alkyl group; and (b) at least one ethylenically unsaturated, free-radically copolymerizable monomer M2 other than the monomers M1. What are also described are two-pack adhesives comprising the copolymers and a polyfunctional hardener. The copolymers and the two-pack adhesives can be used as laminating adhesives.
Abstract:
A description is given of a photoreactive polymer preparable by radical polymerization using at least one photoreactive monomer, where the photoreactive monomer has at least one radically polymerizable C—C double bond, at least one hydrophilic group selected from an ethylene glycol group and polyethylene glycol groups having at least 2 ethylene glycol units, and at least one photoreactive group, the photoreactive group being a photoenolizable carbonyl group.
Abstract:
Described are polyurethane-vinyl hybrid polymers, methods of making them and their use. The hybrid polymers are made from an anionic polyurethane and a polymerizable vinyl compound, wherein the polymerizable vinyl compound is selected from methylene malonates, methylene beta-ketoesters and methylene beta-diketones. The hybrid polymers can be used as binder in structural adhesives, as binder in pressure-sensitive adhesives, as binder in laminating adhesives, as binder in contact adhesives, as binder in ink, as binder in paints, as binder in coatings, as binder for fiber bonding, as binder for particle bonding or as binder in high cohesion adhesive tapes.
Abstract:
What are described are compounds having two or more exovinylene cyclocarbonate units, wherein the exovinylene cyclocarbonate units are bonded to one another via at least one organic, siloxane-free connecting group which is not bonded directly to the exovinylene double bonds, excluding connecting groups formed by polymerization of (meth)acrylic monomers. The connecting group preferably has at least one acetal group. Also described are a process for preparing the compounds, two-component binders comprising the compounds, and uses of the compounds.
Abstract:
Disclose herein are aqueous polymer dispersions for pressure-sensitive adhesives, as well as processes for the preparation of the aqueous polymer dispersions, and use of the aqueous polymer dispersions.
Abstract:
Photoreactive monomer which has (i) at least one free-radically polymerizable C—C double bond, (ii) at least one hydrophilic group selected from an ethylene glycol group and a polyethylene glycol group having at least 2 ethylene glycol units and (iii) at least one photoreactive group, the photoreactive group being a photoenolizable carbonyl group, and also a method for preparing the photoreactive monomers.