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公开(公告)号:US20150329476A1
公开(公告)日:2015-11-19
申请号:US14710845
申请日:2015-05-13
申请人: BASF SE
发明人: Sophia Ebert , Bjorn Ludolph , Christof Wilhelm Wigbers , Dieter Boeckh , Frank Huelskoetter , Stefano Scialla , Kevin Christmas , Darren Rees , Brian J. Loughnane
IPC分类号: C07C217/46 , C11D3/30 , A61Q5/02 , A61Q19/10 , C07C213/04 , A61K8/41
CPC分类号: A61Q19/10 , A61K8/41 , A61K8/45 , A61Q5/02 , C07C213/04 , C07C217/46 , C11D3/30 , C11D3/3723 , C07C217/50
摘要: The invention relates to etheramines of formula (I) or formula (II) or a mixture of etheramines of formula (I) and formula (II) based on 1,2-dialcohols, wherein R1 is a linear or branched alkyl group with 2 to 16 carbon atoms, R2 is a hydrogen or an alkyl group with 1 to 16 carbon atoms, x≧1 and y≧1 and the sum of x+y is between 2 and 10, and A1, A2, A3 and A4 are independently selected from the group consisting of linear and/or branched alkylenes having 2 to 18 carbon atoms and wherein Z1-Z4 are independently selected from OH, NH2, NHR′ or NR′R″, wherein at least one of Z1-Z2 and at least one of Z3-Z4 is NH2, NHR′ or NR′R″, wherein R′ and R″ are independently selected from alkylenes having 2 to 6 carbon atoms. The invention further relates to etheramines obtainable by the alkoxylation and amination of 1,2-dialcohols.
摘要翻译: 本发明涉及基于1,2-二醇的式(I)或式(II)的醚胺或式(I)和式(II)的醚胺的混合物,其中R 1是直链或支链烷基, 16个碳原子,R2是氢或具有1至16个碳原子的烷基,x≥1和y≥1,x + y之和在2和10之间,并且A1,A2,A3和A4被独立地选择 由具有2至18个碳原子的直链和/或支链亚烷基组成的组,其中Z1-Z4独立地选自OH,NH2,NHR'或NR'R“,其中Z1-Z2和至少一个 的Z 3 -Z 4是NH 2,NHR'或NR'R“,其中R'和R”独立地选自具有2至6个碳原子的亚烷基。 本发明还涉及通过1,2-二醇的烷氧基化和胺化获得的醚胺。
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公开(公告)号:US20190112256A1
公开(公告)日:2019-04-18
申请号:US16087732
申请日:2017-03-14
申请人: BASF SE
发明人: Bjoern Ludolph , Sophia Ebert , Christian Eidamshaus , Stefano Scialla , Brian Joseph Loughnane , Karie Marie Henke , Gayle Marie Frankenbach , Jay Frank Nash , Michael Patrick Hayes , Manuel G. Venegas
IPC分类号: C07C217/08 , C07C217/12 , C08G65/333
摘要: Described herein is an etheramine mixture including at least 90% by weight, based on the total weight of the etheramine mixture, of an amine of Formula (I) and/or (II), wherein R1-R12 are independently selected from H, alkyl, cycloalkyl, aryl, alkylaryl, or arylalkyl, wherein at least one of R1-R6 and at least one of R7-R12 is different from H, wherein A1-A9 are independently selected from linear or branched alkanediyl groups having 2 to 18 carbon atoms, wherein Z1-Z4 are independently selected from —OH and linear —OCH2CH2CH2NH2, wherein the degree of amination of each of the etheramines of Formula (I) and Formula (II) is at least 50%, and wherein the sum of x+y is in the range of from 2 to 200, wherein x≥1 and y≥1; and x1+y1 is in the range of from 2 to 200, wherein x1≥1 and y1≥1.
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公开(公告)号:US20190062264A1
公开(公告)日:2019-02-28
申请号:US16087236
申请日:2017-03-14
申请人: BASF SE
发明人: Bjoern Ludolph , Sophia Ebert , Christian Eidamshaus , Stefano Scialla , Brian Joseph Loughnane , Karie Marie Henke , Jay Frank Nash , Michael Patrick Hayes
IPC分类号: C07C217/08 , C07C213/02
摘要: An etheramine mixture comprising of at least one amine selected from the group consisting of amine of Formula (I) and amine of Formula (II) wherein R1-R12 are independently selected from H, alkyl, cycloalkyi, aryl, alkylaryl, or arylalkyi, wherein at least one of R1-R6 and at least one of R7-R12 is different from H, and wherein Z1-Z3 are linear CH2CH2CH2NH2.
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公开(公告)号:US09974985B2
公开(公告)日:2018-05-22
申请号:US14710845
申请日:2015-05-13
申请人: BASF SE
发明人: Sophia Ebert , Björn Ludolph , Christof Wilhelm Wigbers , Dieter Boeckh , Frank Huelskoetter , Stefano Scialla , Kevin Christmas , Darren Rees , Brian J. Loughnane
IPC分类号: C11D3/32 , C11D3/37 , C11D7/32 , A61Q19/10 , C07C217/46 , A61K8/41 , C11D3/30 , A61Q5/02 , C07C213/04 , A61K8/45
CPC分类号: A61Q19/10 , A61K8/41 , A61K8/45 , A61Q5/02 , C07C213/04 , C07C217/46 , C11D3/30 , C11D3/3723 , C07C217/50
摘要: The invention relates to etheramines of formula (I) or formula (II) or a mixture of etheramines of formula (I) and formula (II) based on 1,2-dialcohols, wherein R1 is a linear or branched alkyl group with 2 to 16 carbon atoms, R2 is a hydrogen or an alkyl group with 1 to 16 carbon atoms, x≥1 and y≥1 and the sum of x+y is between 2 and 10, and A1, A2, A3 and A4 are independently selected from the group consisting of linear and/or branched alkylenes having 2 to 18 carbon atoms and wherein Z1-Z4 are independently selected from OH, NH2, NHR′ or NR′R″, wherein at least one of Z1-Z2 and at least one of Z3-Z4 is NH2, NHR′ or NR′R″, wherein R′ and R″ are independently selected from alkylenes having 2 to 6 carbon atoms. The invention further relates to etheramines obtainable by the alkoxylation and amination of 1,2-dialcohols.
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公开(公告)号:US20170298174A1
公开(公告)日:2017-10-19
申请号:US15513637
申请日:2015-09-10
申请人: BASF SE
发明人: Sophia Ebert , Bjoern Ludolph , Christian Eidamshaus , Stefano Scialla , Kevin Christmas , Amy Eichstadt Waun , Brian J. Loughnane , Darren Rees , Frank Huelskoetter
IPC分类号: C08G59/50 , C09J177/00 , C09J163/00 , A61Q19/10 , A61Q5/02 , C11D3/37 , A61K8/86
CPC分类号: C08G59/50 , A61K8/86 , A61Q5/02 , A61Q19/10 , B29C33/56 , B29C35/00 , C07C213/02 , C08G18/3819 , C08G18/5024 , C08G59/504 , C08G65/26 , C08G65/2609 , C08G65/3255 , C08G65/33365 , C08G69/40 , C08G2650/50 , C08L73/00 , C09J163/00 , C09J175/02 , C09J175/04 , C09J177/00 , C09J177/06 , C11D1/44 , C11D3/225 , C11D3/30 , C11D3/3707 , C11D3/3723 , C07C217/08 , C07C217/42
摘要: This invention relates to polyetheramines based on 1,3-dialcohols, in particular to an etheramine mixture comprising at least 90% by weight, based on the total weight of the etheramine mixture, of an amine of Formula (I) and/or (II), wherein R1-R12 are independently selected from H, alkyl, cycloalkyl, aryl, alkylaryl, or arylalkyl, wherein at least one of R1-R6 and at least one of R7-R12 is different from H, wherein A1-A9 are independently selected from linear or branched alkylenes having 2 to 18 carbon atoms, wherein Z1-Z4 are independently selected OH, CH2CH2CH2NH2, NH2, NHR′ or NR′R″, wherein the degree of amination is
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公开(公告)号:US11739052B2
公开(公告)日:2023-08-29
申请号:US17421288
申请日:2019-12-18
申请人: BASF SE
发明人: Sophia Ebert , Dieter Boeckh , Dawid Marczewski , Stefano Scialla , Brian Joseph Loughnane , Frank Huelskoetter
IPC分类号: C07C227/22 , C07C303/24
CPC分类号: C07C227/22 , C07C303/24 , C07C227/22 , C07C229/08 , C07C303/24 , C07C305/04
摘要: The present invention relates to a process for the synthesis of organosulfate salts of amino acid esters comprising the steps of reacting at least one lactam with at least 3 carbon atoms in the lactam ring with sulfuric acid in an aqueous solution followed by esterification of the reaction product of the previous step with at least 200 mol-% of at least one alcohol selected from the group consisting of linear alkyl alcohol containing one hydroxy group, branched alkyl alcohol containing one hydroxy group, linear alkylether alcohol containing one hydroxy group, branched alkylether alcohol containing one hydroxy group, phenoxyalkanols containing one hydroxy group, and mixtures thereof; followed optionally removal of water and/or removal of excess alcohol.
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公开(公告)号:US10414719B2
公开(公告)日:2019-09-17
申请号:US15129169
申请日:2015-03-11
申请人: BASF SE
发明人: Sophia Ebert , Björn Ludolph , Christof W. Wigbers , Christian Eidamshaus , Dieter Boeckh , Frank Huelskoetter , Brian J. Loughnane , Amy Eichstadt Waun , Kevin Christmas , Darren Rees , Stefano Scialla
IPC分类号: C07C217/08 , B29C35/00 , B29C33/56 , C07C213/02 , C08G18/32 , C07C213/04 , A61K8/45 , A61Q5/02 , A61K8/86 , A61Q19/10 , C11D1/44 , C11D3/37 , C11D3/30
摘要: This invention relates to etheramines based on dialcohols, wherein the etheramines comprise at least three linear or branched C4-alkylene groups and a process for the manufacture of these etheramines.
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公开(公告)号:US09738754B2
公开(公告)日:2017-08-22
申请号:US14914027
申请日:2014-07-11
申请人: BASF SE
发明人: Sophia Ebert , Björn Ludolph , Frank Huelskoetter , Kevin Christmas , Stefano Scialla , Brian J. Loughnane , Amy Eichstadt Waun , Darren Rees
IPC分类号: C08G65/26 , C08G73/02 , C08G65/334
CPC分类号: C08G65/2624 , C08G65/3344 , C08G73/024 , C08G2650/24
摘要: The present invention relates to water-soluble alkoxylated polyalkyleneimines having an inner block of polyethylene oxide comprising 5 to 18 polyethylene oxide units, a middle block of polyalkylene oxide comprising 1 to 5 polyalkylene oxide units and an outer block of polyethylene oxide comprising 2 to 14 polyethylene oxide units. The middle block is formed from polypropylene oxide units, polybutylene oxide units and/or polypentene oxide units.In addition, the present invention relates to water-soluble alkoxylated polyamines.
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公开(公告)号:US10815327B2
公开(公告)日:2020-10-27
申请号:US16091133
申请日:2017-03-31
申请人: BASF SE
发明人: Aaron Flores-Figueroa , Martin Ruebenacker , Rainer Dobrawa , Markus Brym , Dieter Boeckh , Frank Huelskoetter , Glenn Ward , James Goodwin , Melissa Cuthbertson , Stefano Scialla
IPC分类号: C08F220/28 , C11D3/37 , C11D11/00 , C11D17/04
摘要: A copolymer which comprises, in copolymerized form, (A) 60 to 99% by weight of at least one monoethylenically unsaturated polyalkylene oxide monomer of the formula I (I) in which the variables have the following meanings: X is —CH2— or —CO—, if Y is —O—; is —CO—, if Y is —NH—; Y is —O— or —NH—; R1 is hydrogen or methyl; R2 are identical or different C2-C6-alkylene radicals, which may be arranged blockwise or randomly; R3 is hydrogen or C1-C4-alkyl; n is an integer from 25 to 75, (B) 1 to 40% by weight of at least one quaternized nitrogen-containing monoethylenically unsaturated monomer selected from the group consisting of monomers of formula Ha to IId (Ha-IId) in which the variables have the following meanings: R is C1-C4-alkyl or benzyl; R′ is hydrogen or methyl; Y is —O— or —NH—; A is C1-C6-alkylene; X— is halide, C1-C4-alkyl sulfate, C1-C4-alkylsulfonate and Ci-C4-alkyl carbonate, (C) 0 to 10% by weight of anionic monoethylenically unsaturated monomers, and (D) 0 to 30% by weight of other nonionic monoethylenically unsaturated monomers and has an average molecular weight Mw of >100,000.
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公开(公告)号:US10414856B2
公开(公告)日:2019-09-17
申请号:US15513637
申请日:2015-09-10
申请人: BASF SE
发明人: Sophia Ebert , Bjoern Ludolph , Christian Eidamshaus , Stefano Scialla , Kevin Christmas , Amy Eichstadt Waun , Brian J. Loughnane , Darren Rees , Frank Huelskoetter
IPC分类号: C11D1/00 , C11D3/26 , C11D3/37 , C08G59/50 , B29C33/56 , B29C35/00 , C11D3/30 , C07C213/02 , C08G65/26 , C11D1/44 , C09J177/06 , C08G18/50 , C08G18/38 , C08G65/325 , C08G65/333 , C08G69/40 , A61K8/86 , A61Q5/02 , A61Q19/10 , C09J163/00 , C09J177/00 , C11D3/22 , C09J175/02 , C09J175/04 , C08L73/00
摘要: This invention relates to polyetheramines based on 1,3-dialcohols, in particular to an etheramine mixture comprising at least 90% by weight, based on the total weight of the etheramine mixture, of an amine of Formula (I) and/or (II), wherein R1-R12 are independently selected from H, alkyl, cycloalkyl, aryl, alkylaryl, or arylalkyl, wherein at least one of R1-R6 and at least one of R7-R12 is different from H, wherein A1-A9 are independently selected from linear or branched alkylenes having 2 to 18 carbon atoms, wherein Z1-Z4 are independently selected OH, CH2CH2CH2NH2, NH2, NHR′ or NR′R″, wherein the degree of amination is
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