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    HYDROCARBON CONVERSION PROCESS IN THE PRESENCE OF AN ACIDIC IONIC LIQUID WITH UPSTREAM HYDROGENATION
    3.
    发明申请
    HYDROCARBON CONVERSION PROCESS IN THE PRESENCE OF AN ACIDIC IONIC LIQUID WITH UPSTREAM HYDROGENATION 审中-公开
    酸性离子液体与上海氢化氢存在时的碳氢转化过程

    公开(公告)号：US20140128648A1

    公开(公告)日：2014-05-08

    申请号：US14053672

    申请日：2013-10-15

    申请人： BASF SE

    发明人： Roman Prochazka ,  Martin Bock ,  Steffen Tschirschwitz ,  Gauthier Luc Maurice Averlant ,  Joni Joni ,  Markus Schmitt ,  Katharina Spuhl ,  Jochen Bürkle ,  Alois Kindler ,  Daniela Malkowsky ,  Stefan Bitterlich ,  Michael Hübner

    IPC分类号： C07C5/13

    CPC分类号： C07C5/13 ,  C07C5/10 ,  C07C5/29 ,  C07C2527/125 ,  C07C13/18

    摘要： The present invention relates to a process for hydrocarbon conversion in the presence of an acidic ionic liquid. The hydrocarbon conversion is preferably an isomerization, especially an isomerization of methylcyclopentane (MOP) to cyclohexane. Prior to the hydrocarbon conversion, a hydrogenation is performed, preference being given to hydrogenating benzene to cyclohexane. The cyclohexane obtained in the hydrogenation and/or isomerization is preferably isolated from the process. In a preferred embodiment of the present invention, the hydrogenation is followed and the hydrocarbon conversion, especially the isomerization, is preceded by distillative removal of low boilers, especially C5-C6-alkanes such as cyclopentane or isohexanes, from the hydrocarbon mixture used for hydrocarbon conversion.

    摘要翻译： 本发明涉及在酸性离子液体存在下烃转化的方法。 烃转化率优选为异构化，特别是甲基环戊烷（MOP）异构化为环己烷。 在烃转化之前，进行氢化，优选将苯氢化成环己烷。 在氢化和/或异构化中获得的环己烷优选与该方法分离。 在本发明的一个优选实施方案中，遵循氢化并且烃转化，特别是异构化之前是从用于烃的烃混合物中蒸馏除去低锅炉，特别是C 5 -C 6烷烃如环戊烷或异己烷 转换。

    NOVEL PROCESS FOR PREPARING CYCLOHEXANE FROM METHYLCYCLOPENTANE AND BENZENE
    5.
    发明申请
    NOVEL PROCESS FOR PREPARING CYCLOHEXANE FROM METHYLCYCLOPENTANE AND BENZENE 审中-公开
    从甲基环戊烷和苯甲腈制备环己烷的新工艺

    公开(公告)号：US20140114100A1

    公开(公告)日：2014-04-24

    申请号：US14053647

    申请日：2013-10-15

    申请人： BASF SE

    发明人： Steffen Tschirschwitz ,  Nicole Holub ,  Jochen Burkle ,  Oliver Christian Gobin ,  Markus Schmitt ,  Martin Bock ,  Aisha Ahmad Naddaf ,  Katharina SpuhI ,  Stefan Bitterlich ,  Daniel Pfeiffer

    IPC分类号： C07C5/29

    CPC分类号： C07C5/29 ,  C07C5/10 ,  C07C7/163 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2527/06 ,  C07C2527/11 ,  C07C2527/1206 ,  C07C2527/1213 ,  C07C2527/126 ,  C07C2527/135 ,  C07C2601/14 ,  C07C13/18 ,  C07C13/10

    摘要： The present invention relates to a process for preparing cyclohexane from methylcyclopentane (MCP) and benzene. In the context of the present invention, MCP and benzene are constituents of a hydrocarbon mixture (HM1) additionally comprising dimethylpentanes (DMP), possibly cyclohexane and at least one compound (low boiler) selected from acyclic C5-C6-alkanes and cyclopentane. First of all, benzene is converted in a hydrogenation step to cyclohexane, while MCP is isomerized in the presence of a catalyst, preferably of an acidic ionic liquid, to cyclohexane. The hydrogenation is preceded by a prior removal of the dimethylpentanes (DMP), with initial removal of any cyclohexane present in the hydrocarbon mixture (HM1) together with DMP. This cyclohexane already present can be separated again from DMP in a downstream rectification step and recycled into the process for cyclohexane preparation. Between hydrogenation and isomerization, low boilers are removed and, after the isomerization, the cyclohexane is isolated with return of unisomerized MCP and optionally of low boilers.

    摘要翻译： 本发明涉及从甲基环戊烷（MCP）和苯制备环己烷的方法。 在本发明的上下文中，MCP和苯是另外包含二甲基戊烷（DMP），可能的环己烷和至少一种选自无环C5-C6烷烃和环戊烷的化合物（低沸点）的烃混合物（HM1）的组分。 首先，将苯在氢化步骤中转化为环己烷，而MCP在催化剂，优选酸性离子液体存在下异构化为环己烷。 之前先氢化二甲基戊烷（DMP），然后与DMP一起初始除去烃混合物（HM1）中存在的任何环己烷。 已经存在的环己烷可以在下游精馏步骤中再次从DMP分离并再循环到环己烷制备方法中。 在氢化和异构化之间，除去低锅炉，在异构化之后，环己烷被分离出来，分离出未异构化的MCP和任选的低锅炉。

    PROCESS FOR PREPARING CYCLOHEXANE COMPRISING A PRIOR REMOVAL OF DIMETHYLPENTANES
    6.
    发明申请
    PROCESS FOR PREPARING CYCLOHEXANE COMPRISING A PRIOR REMOVAL OF DIMETHYLPENTANES 审中-公开
    制备环己烷的方法，包括去除二甲基氨基甲酸酯

    公开(公告)号：US20140114103A1

    公开(公告)日：2014-04-24

    申请号：US14053659

    申请日：2013-10-15

    申请人： BASF SE

    发明人： Markus Schmitt ,  Katharina Spuhl ,  Jochen Bürkle ,  Stefan Bitterlich ,  Steffen Tschirschwitz ,  Michael Hübner ,  Pawel Czajka

    IPC分类号： C07C5/31 ,  C07C5/10

    CPC分类号： C07C5/31 ,  C07C5/10 ,  C07C5/29 ,  C07C2523/755 ,  C07C2527/125 ,  C07C2601/14 ,  C07C13/18

    摘要： The present invention relates to a process for preparing cyclohexane from benzene and/or methylcyclopentane (MCP) by hydrogenation or isomerization. Prior to the cyclohexane preparation, the dimethylpentanes (DMP) are removed in a distillation apparatus (D1) from a hydrocarbon mixture (HM1) comprising not only benzene and/or MCP but also DMP. If cyclohexane is already present in the hydrocarbon mixture (HM1), this cyclohexane is first removed together with DMP from benzene and/or MCP. This cyclohexane already present can be separated again from DMP in a downstream distillation step and recycled into the process for cyclohexane preparation.

    摘要翻译： 本发明涉及通过氢化或异构化由苯和/或甲基环戊烷（MCP）制备环己烷的方法。 在环己烷制备之前，在不仅包含苯和/或MCP而且还包含DMP的烃混合物（HM1）的蒸馏装置（D1）中除去二甲基戊烷（DMP）。 如果烃混合物（HM1）中已经存在环己烷，则首先从苯和/或MCP与DMP一起除去该环己烷。 已经存在的环己烷可以在下游蒸馏步骤中再次从DMP分离并再循环到环己烷制备方法中。