公开(公告)号：US09714191B2

公开(公告)日：2017-07-25

申请号：US14394304

申请日：2013-04-02

申请人： Arkema Inc.

发明人： Min Zheng ,  Mei Wen ,  Scott R. Gaboury ,  Kurt A. Wood ,  Ronald H. Partridge

IPC分类号： B05D1/38 ,  B05D3/02 ,  C03C17/34 ,  C09D175/04 ,  C08G18/62 ,  C08G18/70 ,  C08G18/75 ,  C08G18/28 ,  C08G18/48 ,  B05D3/00 ,  C08G18/80 ,  C08G18/10 ,  C08G18/32 ,  C03C25/50

CPC分类号： C03C17/3405 ,  B05D1/38 ,  B05D3/007 ,  B05D3/0254 ,  B05D3/0272 ,  C03C25/50 ,  C03C2217/78 ,  C08G18/10 ,  C08G18/2885 ,  C08G18/289 ,  C08G18/3206 ,  C08G18/48 ,  C08G18/6279 ,  C08G18/706 ,  C08G18/758 ,  C08G18/80 ,  C09D5/002 ,  C09D127/16 ,  C09D175/04 ,  Y10T428/3154 ,  C08L75/04

摘要： The invention relates to an process for coating a glass substrate with an environmentally friendly aqueous, fluoropolymer coating composition. The process involves applying a polyurethane primer to the glass substrate, and partially, but not completely crosslinking this primer coating. An aqueous hydroxyl-functional fluoropolymer coating is then applied to the partially crosslinked primer coating, and the coating allowed to fully cure. The invention also relates to the intertwined multilayer primer/fluoropolymer coating on the glass substrate. The final coating has excellent wet adhesion to glass, good weathering, durability, chalking resistance, chemical resistance, and dirt pickup resistance.

公开(公告)号：USRE50063E1

公开(公告)日：2024-07-30

申请号：US17901938

申请日：2022-09-02

申请人： Arkema Inc.

发明人： Roice A. Wille ,  Kurt A. Wood

IPC分类号： C09D127/16 ,  C08F259/08 ,  C08F285/00 ,  C09D5/02 ,  C09D151/00

CPC分类号： C09D127/16 ,  C08F259/08 ,  C08F285/00 ,  C09D5/022 ,  C09D151/003 ,  C08L2205/02 ,  C08L2205/03 ,  C08F259/08 ,  C08F220/14 ,  C08F259/08 ,  C08F220/20 ,  C08F259/08 ,  C08F220/06 ,  C08F259/08 ,  C08F220/1804 ,  C08F259/08 ,  C08F222/102 ,  C08F285/00 ,  C08F220/14 ,  C08F285/00 ,  C08F220/20 ,  C08F285/00 ,  C08F220/06 ,  C09D127/16 ,  C08L33/066 ,  C08L33/12 ,  C08F285/00 ,  C08F220/1802 ,  C08F220/20 ,  C08F220/14 ,  C08F220/06 ,  C08F259/08 ,  C08F220/1808 ,  C08F220/14 ,  C08F259/08 ,  C08F220/1808 ,  C08F220/14 ,  C08F222/102

摘要： The invention relates to an aqueous fluoropolymer hybrid composition having superior weathering resistance while maintaining excellent mechanical properties in coatings, paints, caulks and adhesives. The composition is comprised of: a) a vinylidene fluoride polymer, such as KYNAR® polymers from Arkema, b) a first vinyl polymer immiscible with the vinylidene fluoride polymer and having a Tg of less than 0° C., and c) a second vinyl polymer of a different composition, also having a Tg of less than 0° C., and containing groups capable of crosslinking. The invention also relates to waterborne coatings or paints containing the aqueous fluoropolymer hybrid composition, and an article, object, or structure coated with the fluoropolymer hybrid composition on at least one surface, either in a factory or in the field, to confer protection and decorative properties. Free films made from the waterborne compositions of the invention have a dynamic mechanical analysis loss tangent, tan (δ), of greater than 0.22 at a temperature of 0° C.

公开(公告)号：US10920088B2

公开(公告)日：2021-02-16

申请号：US16098176

申请日：2017-05-12

申请人： Arkema Inc.

发明人： Kurt A. Wood ,  Jeffrey Klang

IPC分类号： C09D4/06 ,  C09D127/16 ,  C08F259/08 ,  C09D7/20 ,  C09D127/20 ,  C09D175/04 ,  C08F222/10

摘要： Compositions useful for forming high gloss, transparent, hard, flexible, weather- and dirt-resistant coatings on substrate surfaces are prepared using a) fluoropolymer, such as KYNAR® resins and KYNAR Aquatec® resins from Arkema Inc, b) fluoropolymer-miscible polymer and c) one or more ethylenically unsaturated compounds capable of being cured by free radical means, such as urethane acrylate oligomers and monomer reactive diluents from Sartomer USA, LLC. The compositions are capable of being cured by free radical polymerization induced by, for example, irradiation or heating.

公开(公告)号：US10399892B2

公开(公告)日：2019-09-03

申请号：US14394286

申请日：2013-04-02

申请人： Arkema Inc.

发明人： Min Zheng ,  Mei Wen ,  Scott R. Gaboury ,  Kurt A. Wood ,  Ronald H. Partridge

IPC分类号： C03C17/30 ,  C09D175/04 ,  C03C17/00 ,  C09D127/16 ,  C09D151/00 ,  C08G18/62 ,  C08G18/73 ,  C08G18/75 ,  C08G18/10 ,  C08G18/28

摘要： The invention relates to an aqueous fluoropolymer coating composition for direct application to glass without the need for pre-treatment of the glass surface. The coating composition can also be used with other non-porous and porous substrates. The fluoropolymer coating contains a hydroxyl-functional fluoropolymer, and polyisocyanates. Preferably the coating composition also contains a water-dispersible hydroxyl functional polyurethane. The coating composition may exist as a 1-pack or a multi-pack coating system. The coating has excellent wet adhesion to glass, good weathering, chalking resistance, chemical resistance, and dirt pickup resistance.

公开(公告)号：US20150079403A1

公开(公告)日：2015-03-19

申请号：US14394286

申请日：2013-04-02

申请人： Arkema Inc.

发明人： Min Zheng ,  Mei Wen ,  Scott R. Gaboury ,  Kurt A. Wood ,  Ronald H. Partridge

IPC分类号： C03C17/30 ,  C03C17/00

CPC分类号： C03C17/30 ,  C03C17/001 ,  C03C2217/29 ,  C03C2218/32 ,  C08G18/10 ,  C08G18/289 ,  C08G18/6279 ,  C08G18/73 ,  C08G18/758 ,  C08L2205/04 ,  C09D127/16 ,  C09D151/003 ,  C09D175/04 ,  Y10T428/3154 ,  C08K5/29 ,  C08K5/54 ,  C08L75/04

摘要： The invention relates to an aqueous fluoropolymer coating composition for direct application to glass without the need for pre-treatment of the glass surface. The coating composition can also be used with other non-porous and porous substrates. The fluoropolymer coating contains a hydroxyl-functional fluoropolymer, and polyisocyanates. Preferably the coating composition also contains a water-dispersible hydroxyl functional polyurethane. The coating composition may exist as a 1-pack or a multi-pack coating system. The coating has excellent wet adhesion to glass, good weathering, chalking resistance, chemical resistance, and dirt pickup resistance.

摘要翻译： 本发明涉及直接应用于玻璃而不需要预处理玻璃表面的含氟聚合物水性涂料组合物。 涂料组合物也可以与其它无孔和多孔的基材一起使用。 含氟聚合物涂层含有羟基官能的含氟聚合物和多异氰酸酯。 优选地，涂料组合物还含有水分散性羟基官能聚氨酯。 涂料组合物可以以1包或多包装涂料体系的形式存在。 该涂层对玻璃具有优异的湿粘附性，良好的耐候性，抗粉化性，耐化学性和耐污垢性。

公开(公告)号：US20190144683A1

公开(公告)日：2019-05-16

申请号：US16098176

申请日：2017-05-12

申请人： Arkema Inc.

发明人： Kurt A. Wood ,  Jeffrey KLANG

IPC分类号： C09D4/06 ,  C09D127/16 ,  C09D127/20 ,  C09D7/20 ,  C09D175/04

摘要： Compositions useful for forming high gloss, transparent, hard, flexible, weather- and dirt-resistant coatings on substrate surfaces are prepared using a) fluoropolymer, such as KYNAR® resins and KYNAR Aquatec® resins from Arkema Inc, b) fluoropolymer-miscible polymer and c) one or more ethylenically unsaturated compounds capable of being cured by free radical means, such as urethane acrylate oligomers and monomer reactive diluents from Sartomer USA, LLC. The compositions are capable of being cured by free radical polymerization induced by, for example, irradiation or heating.

公开(公告)号：US20150086792A1

公开(公告)日：2015-03-26

申请号：US14394304

申请日：2013-04-02

申请人： Arkema Inc.

发明人： Min Zheng ,  Mei Wen ,  Scott R. Gaboury ,  Kurt A. Wood ,  Ronald H. Partridge

IPC分类号： C03C17/34 ,  B05D3/02 ,  B05D3/00

CPC分类号： C03C17/3405 ,  B05D1/38 ,  B05D3/007 ,  B05D3/0254 ,  B05D3/0272 ,  C03C25/50 ,  C03C2217/78 ,  C08G18/10 ,  C08G18/2885 ,  C08G18/289 ,  C08G18/3206 ,  C08G18/48 ,  C08G18/6279 ,  C08G18/706 ,  C08G18/758 ,  C08G18/80 ,  C09D5/002 ,  C09D127/16 ,  C09D175/04 ,  Y10T428/3154 ,  C08L75/04

摘要： The invention relates to an process for coating a glass substrate with an environmentally friendly aqueous, fluoropolymer coating composition. The process involves applying a polyurethane primer to the glass substrate, and partially, but not completely crosslinking this primer coating. An aqueous hydroxyl-functional fluoropolymer coating is then applied to the partially crosslinked primer coating, and the coating allowed to fully cure. The invention also relates to the intertwined multilayer primer/fluoropolymer coating on the glass substrate. The final coating has excellent wet adhesion to glass, good weathering, durability, chalking resistance, chemical resistance, and dirt pickup resistance.

摘要翻译： 本发明涉及用环保的含氟聚合物涂料组合物涂覆玻璃基材的方法。 该方法包括将聚氨酯底漆涂布在玻璃基材上，部分但不完全交联该底涂层。 然后将羟基官能的含氟聚合物水溶液涂覆到部分交联的底漆涂层上，使涂层完全固化。 本发明还涉及玻璃基板上相互缠绕的多层底漆/含氟聚合物涂层。 最终的涂层具有优异的与玻璃的湿粘合性，良好的耐候性，耐久性，抗粉化性，耐化学性和耐污垢性。

公开(公告)号：US11725071B2

公开(公告)日：2023-08-15

申请号：US16651391

申请日：2018-09-25

申请人： Arkema Inc.

发明人： Benjamin Bin Chen ,  Caiping Lin ,  Craig A. Polsz ,  Kurt A. Wood ,  Brian T. Wood ,  Lucy Clarkson

IPC分类号： C08F214/18 ,  C08F214/20 ,  C08F214/22 ,  C08F214/24 ,  C08F214/26 ,  H01M4/62 ,  C08F220/22

CPC分类号： C08F214/184 ,  C08F214/202 ,  C08F214/222 ,  C08F214/242 ,  C08F214/262 ,  C08F220/22 ,  H01M4/623 ,  C08F214/22 ,  C08F216/1408 ,  C08F214/22 ,  C08F216/1416 ,  C08F214/22 ,  C08F220/22 ,  C08F214/22 ,  C08F218/04

摘要： Copolymers of one or more halogenated olefins and one or more halogenated co-monomers selected from the group consisting of halogenated alkenyl ethers, halogenated alkenyl esters, and halogenated (meth)acrylates are useful in various end-use applications wherein the presence of halogen (e.g., fluorine) in the copolymer imparts one or more desirable properties, as compared to analogous copolymers not containing halogen.

公开(公告)号：US10774233B2

公开(公告)日：2020-09-15

申请号：US15778407

申请日：2016-11-16

申请人： Arkema Inc.

发明人： Roice A. Wille ,  Kurt A. Wood

IPC分类号： C08F259/08 ,  C09D127/16 ,  C09D151/00 ,  C08L27/16 ,  C08F285/00 ,  C09D5/02

摘要： The invention relates to an aqueous fluoropolymer hybrid composition having superior weathering resistance while maintaining excellent mechanical properties in coatings, paints, caulks and adhesives. The composition is comprised of: a) a vinylidene fluoride polymer, such as KYNAR® polymers from Arkema, b) a first vinyl polymer immiscible with the vinylidene fluoride polymer and having a Tg of less than 0° C., and c) a second vinyl polymer of a different composition, also having a Tg of less than 0° C., and containing groups capable of crosslinking. The invention also relates to waterborne coatings or paints containing the aqueous fluoropolymer hybrid composition, and an article, object, or structure coated with the fluoropolymer hybrid composition on at least one surface, either in a factory or in the field, to confer protection and decorative properties. Free films made from the waterborne compositions of the invention have a dynamic mechanical analysis loss tangent, tan (δ), of greater than 0.22 at a temperature of 0° C.

公开(公告)号：US10392298B2

公开(公告)日：2019-08-27

申请号：US15635727

申请日：2017-06-28

申请人： Arkema Inc.

发明人： Min Zheng ,  Mei Wen ,  Scott R. Gaboury ,  Kurt A. Wood ,  Ronald H. Partridge

IPC分类号： C03C17/34 ,  C09D127/12 ,  C09D175/04 ,  B05D1/38 ,  C08G18/62 ,  C08G18/70 ,  C08G18/75 ,  C08G18/28 ,  C08G18/48 ,  B05D3/00 ,  B05D3/02 ,  C08G18/80 ,  C08G18/10 ,  C08G18/32 ,  C03C25/50 ,  C09D5/00 ,  C09D127/16

摘要： The invention relates to an intertwined multilayer primer/fluoropolymer coating on the glass substrate. The final coating has excellent wet adhesion to glass, good weathering, durability, chalking resistance, chemical resistance, and dirt pickup resistance. The coating is an environmentally friendly aqueous, fluoropolymer coating composition. The coating process involves applying a polyurethane primer to the glass substrate, and partially, but not completely crosslinking this primer coating. An aqueous hydroxyl-functional fluoropolymer coating is then applied to the partially cross-linked primer coating, and the coating allowed to fully cure. The invention also relates to the intertwined multilayer primer/fluoropolymer coating on the glass substrate. The final coating has excellent wet adhesion to glass, good weathering, durability, chalking resistance, chemical resistance, and dirt pickup resistance.