公开(公告)号：US20210189031A1

公开(公告)日：2021-06-24

申请号：US16756261

申请日：2018-10-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Kai Helmut Lochhaas ,  Jens Schrooten ,  Helmut Traunspurger ,  Tilman C. Zipplies

IPC: C08F214/26

Abstract: Described herein is a fluorothermoplast with long chain branching and a method of making such a polymer using a modifier of the formula: F2C═CF(CF2)a(O)RfH wherein a is 0 or 1 and Rf is a linear or branched fluorinated alkylene group comprising 1 to 5 carbon atoms and optionally comprising at least one ether linkage and optionally comprising 1 or 2 hydrogen atoms. This fluorothermoplast may be processed through polymer melt processes, such as blow molding, injection molding, film extrusion, and wire extrusion. Preferably, said polymer contains structural units derived from tetrafluoroethylene and a perfluorinated olefin or ether, and comprises chain branching.

公开(公告)号：US20180030182A1

公开(公告)日：2018-02-01

申请号：US15553101

申请日：2016-02-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Florian D. Jochum ,  Klaus Hintzer ,  Kai Helmut Lochhaas ,  Harald Kaspar ,  Tilman C. Zipplies ,  Helmut Traunspurger

IPC: C08F214/22 ,  C08F214/28

CPC classification number: C08F214/222 ,  C08F214/22 ,  C08F214/282 ,  C08F259/08 ,  C08F214/26 ,  C08F216/125 ,  C08F216/1408

Abstract: Curable fluoropolymer containing repeating units derived from VDF and TFE and at least one other fluorinated co-monomer and further containing —CF2CH2I end groups and branching sites derived from one or more perfluorinated bisolefinic ether(s) used as modifier(s), wherein the one or more perfluorinated bisolefinic ether(s) used as modifier(s) correspond to the general formula: CF2═CF—(CF2)n—O—(R1)—O—(CF2)mCF═CF2 wherein n and m are independent from each other either 1 or 0 and wherein R1 represents a perfluorinated linear or branched, cyclic or acyclic aliphatic or aromatic hydrocarbon residue that may be interrupted by one or more oxygen atoms and comprises up to 30 carbon atoms. Further provided are methods of making the curable fluoropolymers and for making an article containing the curable polymers.

公开(公告)号：US20170226337A1

公开(公告)日：2017-08-10

申请号：US15503109

申请日：2015-08-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Lisa P. Chen ,  Klaus Hintzer ,  Harald Kaspar ,  Kai H. Lochhaas ,  Mark W. Muggli ,  Jens Schrooten ,  Allen M. Sohlo ,  Helmut Traunspurger ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08L27/18 ,  B32B27/28 ,  B32B27/08 ,  B32B27/30 ,  B32B27/32 ,  C08F214/26 ,  B32B27/20

CPC classification number: C08F214/26 ,  B32B27/08 ,  B32B27/20 ,  B32B27/304 ,  B32B27/308 ,  B32B27/322 ,  B32B2262/10 ,  B32B2264/102 ,  B32B2307/202 ,  B32B2307/7242 ,  B32B2597/00 ,  B32B2605/08 ,  C08F214/262

Abstract: Described herein is a composition comprising a fluorothermoplastic polymer, wherein the fluorothermoplastic polymer is derived from: (a) 60-85 mol % tetrafluoroethene; (b) 2-12 mol % hexafluoropropene; (c) 10-30 mol % vinylidene fluoride; (d) 0.2 to 5 mol % of a bromine-containing monomer. Such compositions can be used in multilayer constructions in, for example, fuel hose applications.

公开(公告)号：US09714307B2

公开(公告)日：2017-07-25

申请号：US14646451

申请日：2013-11-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Herbert Koenigsmann ,  Helmut Traunspurger ,  Tilman C. Zipplies

IPC: C08L27/18 ,  C08F214/26 ,  C08F214/18

CPC classification number: C08F214/262 ,  C08F214/184 ,  C08L27/18 ,  C08L2201/54

Abstract: A method of making a partially fluorinated polymer dispersions and resulting aqueous mixtures. The method comprising polymerizing one or more fluorinated monomers in an aqueous emulsion polymerization in the presence of a polymerizable fluorinated emulsifier to form a fluorinated polymer. The polymerizable fluorinated emulsifier has the formula X2C═CX(CF2)m(CH2)n[O—(CX2)p]q-[O—(CX2)r]s—[O—(CX2—CX2)]t—[(O)w—(CX2)u]v-[CH2]z—Y.

公开(公告)号：US20240113301A1

公开(公告)日：2024-04-04

申请号：US18462577

申请日：2023-09-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Michael H. Mitchell ,  Michael C. Dadalas ,  Mark W. Muggli ,  Helmut Traunspurger ,  André Streiter ,  Kevin W. Eberman ,  Brandon A. Bartling

IPC: H01M4/62

CPC classification number: H01M4/625 ,  H01M4/623

Abstract: Methods of preparing a dry powder blend co-coagulating conductive carbon black particles and fibrillizable polytetrafluoroethylene particles from an aqueous dispersion and drying the co-coagulate are described. Dry powders prepared by such methods and electrodes prepared from such powders are also described.

公开(公告)号：US20190070599A1

公开(公告)日：2019-03-07

申请号：US16081808

申请日：2017-03-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Tilman C. Zipplies ,  Klaus Hintzer ,  Helmut Traunspurger ,  Karl D. Weilandt

IPC: B01J41/05 ,  B01J47/02 ,  C07C51/47

Abstract: Provided are methods for removing a perfluorinated alkanoic acid from solutions containing the perfluorinated alkanoic acid and a fluorinated alkoxy acid. These methods include contacting the first solution with an anion-exchange resin to produce a second solution and a resultant anion-exchange resin having perfluorinated alkanoic acid adsorbed thereto, wherein the perfluorinated alkanoic acid is present in the first solution at a first concentration and is present in the second solution at a second concentration which is lower than the first concentration, and separating the second solution from the resultant anion-exchange resin.

公开(公告)号：US20160122522A1

公开(公告)日：2016-05-05

申请号：US14992223

申请日：2016-01-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Herbert Koenigsmann ,  Helmut Traunspurger ,  Tilman C. Zipplies

IPC: C08L27/18

CPC classification number: C08L27/18 ,  C08F214/262

Abstract: A method of making a highly fluorinated polymers and resulting aqueous mixtures. The method comprising polymerizing one or more perfluorinated monomers in an aqueous emulsion polymerization in the presence of a polymerizable fluorinated emulsifier to form a perfluorinated polymer. The polymerizable fluorinated emulsifier has the formula X2C═CX(CF2)m(CH2)n[O—(CX2)p]q—[O—(CX2)r]s−[O—(CX2—CX2)]t—[(O)w—(CX2)u]v—[CH2]z—Y. The method also provides for isolating the highly fluorinated polymer and post-fluorinating the isolated highly fluorinated polymer.

Abstract translation: 制备高度氟化聚合物和所得含水混合物的方法。 该方法包括在可聚合的氟化乳化剂的存在下在水乳液聚合中聚合一种或多种全氟化单体以形成全氟化聚合物。 可聚合的氟化乳化剂具有式X2C≡CX（CF2）m（CH2）n [O-（CX2）p] q- [O-（CX2）r] s- [O-（CX2-CX2）] t- [ （O）w - （CX2）u] v- [CH2] z-Y。 该方法还提供了分离高度氟化的聚合物和后氟化分离的高度氟化的聚合物。

公开(公告)号：US09260553B2

公开(公告)日：2016-02-16

申请号：US14646980

申请日：2013-11-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Klaus Hintzer ,  Harald Kaspar ,  Herbert Koenigsmann ,  Helmut Traunspurger ,  Tilman C. Zipplies

IPC: C08F214/26

CPC classification number: C08L27/18 ,  C08F214/262

Abstract: A method of making a highly fluorinated polymers and resulting aqueous mixtures. The method comprising polymerizing one or more perfluorinated monomers in an aqueous emulsion polymerization in the presence of a polymerizable fluorinated emulsifier to form a perfluorinated polymer. The polymerizable fluorinated emulsifier has the formula X2C═CX(CF2)m(CH2)n[O—(CX2)p]q—[O—(CX2)r]s—[O—(CX2—CX2)]t—[(O)w—(CX2)u]v—[CH2]z—Y. The method also provides for isolating the highly fluorinated polymer and post-fluorinating the isolated highly fluorinated polymer.

Abstract translation: 制备高度氟化聚合物和所得含水混合物的方法。 该方法包括在可聚合的氟化乳化剂的存在下在水乳液聚合中聚合一种或多种全氟化单体以形成全氟化聚合物。 可聚合的氟化乳化剂具有式X2C≡CX（CF2）m（CH2）n [O-（CX2）p] q- [O-（CX2）r] s- [O-（CX2-CX2）] t- [ （O）w - （CX2）u] v- [CH2] z-Y。 该方法还提供了分离高度氟化的聚合物和后氟化分离的高度氟化的聚合物。

公开(公告)号：US10744497B2

公开(公告)日：2020-08-18

申请号：US16081808

申请日：2017-03-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Tilman C. Zipplies ,  Klaus Hintzer ,  Helmut Traunspurger ,  Karl D. Weilandt

IPC: C08F6/16 ,  B01J41/05 ,  C07C51/47 ,  B01J20/26 ,  C07C51/08 ,  C02F1/42 ,  B01J47/02 ,  C02F101/36 ,  C07C55/32 ,  C07C59/135

Abstract: Provided are methods for removing a perfluorinated alkanoic acid from solutions containing the perfluorinated alkanoic acid and a fluorinated alkoxy acid. These methods include contacting the first solution with an anion-exchange resin to produce a second solution and a resultant anion-exchange resin having perfluorinated alkanoic acid adsorbed thereto, wherein the perfluorinated alkanoic acid is present in the first solution at a first concentration and is present in the second solution at a second concentration which is lower than the first concentration, and separating the second solution from the resultant anion-exchange resin.

公开(公告)号：US10087322B2

公开(公告)日：2018-10-02

申请号：US15503109

申请日：2015-08-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Lisa P. Chen ,  Klaus Hintzer ,  Harald Kaspar ,  Kai H. Lochhaas ,  Mark W. Muggli ,  Jens Schrooten ,  Allen M. Sohlo ,  Helmut Traunspurger ,  Karl D. Weilandt ,  Tilman C. Zipplies

IPC: C08F214/16 ,  C08F214/22 ,  C08F214/26 ,  C08F214/28 ,  C08L27/18 ,  B32B27/28 ,  B32B27/20 ,  B32B27/30 ,  B32B27/32 ,  B32B27/08

Abstract: Described herein is a composition comprising a fluorothermoplastic polymer, wherein the fluorothermoplastic polymer is derived from: (a) 60-85 mol % tetrafluoroethene; (b) 2-12 mol % hexafluoropropene; (c) 10-30 mol % vinylidene fluoride; (d) 0.2 to 5 mol % of a bromine-containing monomer. Such compositions can be used in multilayer constructions in, for example, fuel hose applications.