摘要:
This invention provides a fluorine-containing copolymer having a repeat unit derived from at least one fluorinated olefin and a repeat unit derived from at least one polycyclic ethylenically unsaturated monomer having pendant hydroxyl or esterified hydroxyl groups, and optionally other repeat units, typically derived from an acrylate. These polymers have high transparency at short wavelengths such as 193 nm and 157 nm, and provide good plasma etch resistance and adhesive properties. Also provided are photoresist compositions and substrates coated therewith.
摘要:
This invention provides novel fluorine containing polymers which comprise at least one fluorinated olefin, at least one polycyclic ethylenically unsaturated monomer with a fused 4-membered carbocyclic ring and, optionally, other components. The polymers are useful for photoimaging compositions and, in particular, photoresist compositions (positive-working and/or negative-working) for imaging in the production of semiconductor devices. The polymers are especially useful in photoresist compositions having high UV transparency (particularly at short wavelengths, e.g., 157 nm) which are useful as base resins in resists and potentially in many other applications.
摘要:
The present invention provides novel fluorine-containing copolymers which comprise at least one fluorinated olefin, at least one polycyclic ethylenically unsaturated monomer with a fused 4-membered heterocyclic ring and, optionally, other components. The copolymers are useful for photoimaging compositions and, in particular, photoresist compositions (positive-working and/or negative-working) for imaging in the production of semiconductor devices. The copolymers are especially useful in photoresist compositions having high UV transparency (particularly at short wavelengths, e.g., 157 nm) which are useful as base resins in resists and potentially in many other applications.
摘要:
This invention provides an efficient method for synthesizing trithiocarbonate RAFT agents, RSC(S)SR′, that can be used in the living polymerization of methacrylates and other olefinic monomers. This invention also provides an efficient method of synthesizing bis(alkylsulfanylthiocarbonyl) disulfides that are useful as intermediates in the synthesis of trithiocarbonate RAFT agents.
摘要:
The invention pertains to low polydispersity acrylic polymers useful for photoimaging and photoresist compositions, and to the photoimaging processes which use these compositions. The low polydispersity polymers of this invention are prepared using controlled radical polymerization (CRP) techniques, such as RAFT (reversible addition fragmentation chain transfer) polymerization.
摘要:
This invention provides a method for removing certain sulfur-containing groups from polymers, especially those made via RAFT polymerization processes.
摘要:
This invention provides an efficient method for synthesizing trithiocarbonates, RSC(S)SR′ that can be used, for example, as RAFT agents in the living polymerization of styrenics, acrylates, and other olefinic monomers.
摘要:
The invention provides a polymer having (a) at least one repeat unit derived from an ethylenically unsaturated compound having at least one fluorine atom covalently attached to an ethylenically unsaturated carbon atom; and (b) at least one repeat unit derived from an ethylenically unsaturated cyclic compound of structure: (I) wherein n is 0, 1, or 2; and R2 to R4 are independently H; C1-C10 alkyl or alkoxy, optionally substituted by halogen or ether oxygens; or C6-C20 aryl. These polymers can be used in making photoresist compositions and coated substrates.
摘要翻译:本发明提供了一种聚合物,其具有(a)至少一种衍生自具有至少一个与烯属不饱和碳原子共价连接的氟原子的烯属不饱和化合物的重复单元; 和(b)衍生自以下结构的烯属不饱和环状化合物的至少一个重复单元:(I)其中n为0,1或2; R 2和R 4独立地是H; C 1 -C 10烷基或烷氧基,任选被卤素或醚氧取代; 或C 6 -C 20芳基。 这些聚合物可用于制备光致抗蚀剂组合物和涂覆的基材。
摘要:
The invention is directed to creamy alcoholic beverages comprising wine and/or spirits and creamer, wherein the creamer is emulsified within the wine and/or spirit and the creamy alcoholic beverage is storage stable at a temperature of about 20° C. to about 25° C. for at least one year. Optionally, the creamy alcoholic beverage may include pectin and does not excessively foam. The wine may be treated to substantially remove or deactivate proteolytic enzymes within the wine using at least one of heat treatment, column adsorption, clay adsorption, tangential filtration, or ultra-filtration.