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    Method for the oligomerization of alpha-olefins
    1.
    发明授权
    Method for the oligomerization of alpha-olefins 失效
    α-烯烃低聚方法

    公开(公告)号：US4594469A

    公开(公告)日：1986-06-10

    申请号：US530336

    申请日：1983-09-08

    申请人： Frederick C. Loveless ,  Aspet V. Merijanian ,  David J. Smudin ,  Walter Nudenberg

    发明人： Frederick C. Loveless ,  Aspet V. Merijanian ,  David J. Smudin ,  Walter Nudenberg

    IPC分类号： B01J31/00 ,  B01J31/14 ,  C07B61/00 ,  C07C1/00 ,  C07C2/30 ,  C07C11/02 ,  C07C67/00

    CPC分类号： C07C2/30 ,  C07C2527/06 ,  C07C2531/02 ,  C07C2531/14

    摘要： A process for oligomerizing alpha-olefins comprising contacting in a reactor zone under reaction conditions: (a) alpha-olefins having at least three carbon atoms; (b) an alkyl aluminum bromine or iodine compound having the formula R.sub.3 Al.sub.2 X.sub.3 or R.sub.n AlX.sub.3-n, wherein n is 1 or 2; R is an hydrocarbyl group and X is a reactive halogen selected from bromine and iodine; and (c) a cocatalyst which is (i) bromine, (ii) iodine, (iii) hydrocarbyl bromide having at least one halogen group reactive with said aluminum compound or (iv) hydrocarbyl iodide having at least one halogen group reactive with said aluminum compound.

    摘要翻译： 包括使α-烯烃低聚的方法，包括在反应条件下在反应器区中接触：（a）具有至少三个碳原子的α-烯烃; （b）具有式R3Al2X3或RnAlX3-n的烷基铝溴或碘化合物，其中n为1或2; R是烃基，X是选自溴和碘的反应性卤素; 和（c）助催化剂，其为（i）溴，（ii）碘，（iii）具有至少一个与所述铝化合物反应的卤素基团的烃基溴，或（iv）具有至少一个与所述铝反应的卤素基团的烃基碘 复合。

    Polymerization catalyst promoter
    6.
    发明授权
    Polymerization catalyst promoter 失效
    聚合催化剂促进剂

    公开(公告)号：US5786504A

    公开(公告)日：1998-07-28

    申请号：US649736

    申请日：1996-05-15

    申请人： Walter Nudenberg ,  Catherine Ann McGeary ,  Xu Wu Feng ,  Francis Xavier O'Shea

    发明人： Walter Nudenberg ,  Catherine Ann McGeary ,  Xu Wu Feng ,  Francis Xavier O'Shea

    IPC分类号： C07C69/65 ,  C08F4/68 ,  C08F10/00 ,  C08F10/02 ,  C08F210/16 ,  C08F210/18 ,  C07C69/62 ,  C07C327/00

    CPC分类号： C07C69/65 ,  C08F210/16 ,  C08F210/18

    摘要： Compounds of the formula: ##STR1## wherein n is 1, 2, 3, or 4; X.sup.1 and X.sup.2 are each, independently, chlorine or bromine; A is O or S; R.sup.1 is hydrogen or C.sub.1 -C.sub.16 alkyl; R.sup.2 is C.sub.1 -C.sub.16 alkyl, C.sub.6 -C.sub.16 aryl, C.sub.1 -C.sub.4 alkylidene, or CH.sub.2 OR.sup.5 ; R.sup.3 is hydrogen, chlorine, bromine, or OR.sup.6 ; R.sup.4 is C.sub.1 -C.sub.16 alkyl, C.sub.7 -C.sub.16 aralkyl, C.sub.2 -C.sub.16 alkenyl, or C.sub.6 -C.sub.18 aryl; R.sup.5 is hydrogen, C.sub.1 -C.sub.16 alkyl, C.sub.7 -C.sub.16 aralkyl, C.sub.2 -C.sub.16 alkenyl, or C.sub.6 -C.sub.18 aryl; and R.sup.6 is hydrogen or C.sub.1 -C.sub.16 alkyl. These compounds by themselves and in combination with certain halo-but-2-enoic acids and esters are useful as catalyst promoters in ethylene polymerization processes.

    摘要翻译： 下式的化合物：其中n为1,2,3或4; X1和X2各自独立地为氯或溴; A是O或S; R1是氢或C1-C16烷基; R2是C1-C16烷基，C6-C16芳基，C1-C4亚烷基或CH2OR5; R3是氢，氯，溴或OR6; R4是C1-C16烷基，C7-C16芳烷基，C2-C16烯基或C6-C18芳基; R5是氢，C1-C16烷基，C7-C16芳烷基，C2-C16烯基或C6-C18芳基; 并且R 6是氢或C 1 -C 16烷基。 这些化合物本身并与某些卤代丁-2-烯酸和酯组合可用作乙烯聚合方法中的催化剂促进剂。