公开(公告)号：US09027421B2

公开(公告)日：2015-05-12

申请号：US13518348

申请日：2010-12-21

Applicant: Udo Gellert

Inventor： Udo Gellert

IPC: G01N1/38 ,  B05B5/00 ,  G01N30/04 ,  G01N30/12 ,  G01N30/24 ,  G01N30/72

CPC classification number: B05B5/00 ,  G01N30/04 ,  G01N30/12 ,  G01N30/24 ,  G01N30/72 ,  G01N30/7246

Abstract: A liquid-metering device comprising a droplet generator including a reservoir and, connected to the latter, a displacement space which is modifiable by an electromechanical transducer and which has an outlet opening and, upon excitation of the transducer, shoots a liquid droplet from a cold area into a heatable area through or counter to a gas stream generated by a gas source. To make the device suitable for automatic and quasi-continuous liquid metering in process analysis, a heatable evaporation chamber is provided through which the liquid to be metered flows via valves, and, between the evaporation chamber and the reservoir, a condensate chamber is connected via further valves. The condensate chamber and the reservoir are connected via additional valves and a pressure regulator to the gas source.

Abstract translation: 一种液体计量装置，其包括液滴发生器，其包括储存器，并且与液体发生器连接，所述位移空间可由机电换能器修改，并且具有出口开口，并且在所述换能器激发时，从冷发射液滴 区域通过或与气源产生的气流反向成可加热区域。 为了使该装置适用于过程分析中的自动和准连续液体计量，提供可加热蒸发室，待计量的液体通过该蒸发室经由阀流动，并且在蒸发室和储存器之间，冷凝室通过 进一步的阀门。 冷凝室和储存器通过附加阀和压力调节器连接到气源。

公开(公告)号：US20130175356A1

公开(公告)日：2013-07-11

申请号：US13518348

申请日：2010-12-21

Applicant: Udo Gellert

Inventor： Udo Gellert

IPC: B05B5/00

CPC classification number: B05B5/00 ,  G01N30/04 ,  G01N30/12 ,  G01N30/24 ,  G01N30/72 ,  G01N30/7246

Abstract: A liquid-metering device comprising a droplet generator including a reservoir and, connected to the latter, a displacement space which is modifiable by an electromechanical transducer and which has an outlet opening and, upon excitation of the transducer, shoots a liquid droplet from a cold area into a heatable area through or counter to a gas stream generated by a gas source. To make the device suitable for automatic and quasi-continuous liquid metering in process analysis, a heatable evaporation chamber is provided through which the liquid to be metered flows via valves, and, between the evaporation chamber and the reservoir, a condensate chamber is connected via further valves. The condensate chamber and the reservoir are connected via additional valves and a pressure regulator to the gas source.

Abstract translation: 一种液体计量装置，其包括液滴发生器，其包括储存器，并且与液体发生器连接，所述位移空间可由机电换能器修改，并且具有出口开口，并且在所述换能器激发时，从冷发射液滴 区域通过或与气源产生的气流反向成可加热区域。 为了使该装置适用于过程分析中的自动和准连续液体计量，提供可加热蒸发室，待计量的液体通过该蒸发室经由阀流动，并且在蒸发室和储存器之间，冷凝室通过 进一步的阀门。 冷凝室和储存器通过附加阀和压力调节器连接到气源。

公开(公告)号：US20120226445A1

公开(公告)日：2012-09-06

申请号：US13390885

申请日：2010-08-06

Applicant: Udo Gellert

Inventor： Udo Gellert

IPC: G06F19/00

CPC classification number: G01N30/8641 ,  G01N30/8631 ,  G01N30/8637 ,  G01N2030/862

Abstract: A method for improving the chromatographic detection limit for an analyte including a) producing a chromatogram with a peak of the analyte, b) calculating a regression straight line for a baseline from measured values of a section without a peak in the chromatogram, c) calculating a regression function from measured values of the peak of the analyte, d) subtracting the regression function from the chromatogram, e) calculating a regression polynomial for the baseline from the values of the chromatogram which have been changed in step d), calculating a further regression function from the measured values of the peak in the produced chromatogram, g) calculating a peak area between the regression polynomial and the further regression function, h) repetition of step d) with the further regression function instead of the regression function and of steps e), f) and g), until the calculated peak area changes by less than a predetermined amount.

Abstract translation: 一种用于改进分析物的色谱检测极限的方法，包括a）产生具有分析物峰的色谱图，b）从色谱图中没有峰的部分的测量值计算基线的回归直线，c）计算 来自分析物峰的测量值的回归函数，d）从色谱图中减去回归函数，e）从步骤d）中已经改变的色谱图的值计算基线的回归多项式，计算另外的 回归函数从产生色谱图中的峰值的测量值，g）计算回归多项式与进一步回归函数之间的峰面积，h）重复步骤d）与进一步的回归函数而不是回归函数和步骤 e），f）和g），直到计算的峰面积改变小于预定量。

公开(公告)号：US09116160B2

公开(公告)日：2015-08-25

申请号：US13511925

申请日：2010-11-25

Applicant: Udo Gellert ,  Frank Probst

Inventor： Udo Gellert ,  Frank Probst

IPC: G01N30/66 ,  G01R27/26 ,  G01N30/86 ,  G01N30/04 ,  G01N30/88

CPC classification number: G01N30/8631 ,  G01N30/04 ,  G01N30/66 ,  G01N2030/8859 ,  G01R27/2629

Abstract: The invention relates to a gas sample to be analyzed, wherein said sample is guided by means of a carrier gas through a separator unit having a downstream thermal conductivity detector providing a chromatogram having peaks for different analytes as a measurement signal. When using a thermal conductivity detector having a heated gold thread coated with a parylene F, hydrogen is used as a carrier gas, and a peak for the analyte hydrogen sulfide is generated by differentiating the chromatogram at the location of said analyte. The invention permits unlimited use of hydrogen as a carrier gas, even if the analyte is oxygen.

Abstract translation: 本发明涉及要分析的气体样品，其中所述样品通过载气通过具有下游热导率检测器的分离器单元引导，所述分离器单元提供具有作为测量信号的不同分析物峰值的色谱图。 当使用涂有聚对二甲苯F的加热金线的热导率检测器时，使用氢气作为载气，并且通过对所述分析物的位置处的色谱进行微分分析产生分析物硫化氢的峰。 本发明允许氢气作为载气的无限制使用，即使分析物是氧气。

公开(公告)号：US08240334B2

公开(公告)日：2012-08-14

申请号：US12310929

申请日：2007-09-13

Applicant: Udo Gellert

Inventor： Udo Gellert

IPC: G01N30/24 ,  G05D7/00

CPC classification number: G01N30/20 ,  G01N30/40 ,  G01N2030/207 ,  Y10T137/2544 ,  Y10T137/87249

Abstract: An arrangement for metering a gaseous sample in a carrier gas stream has a sample gas path and a carrier gas path, both paths being connected to a carrier gas source. By introducing different pressures into the sample gas path and the carrier gas path, a metered amount is extracted from a sample slug and diverted into the carrier gas stream via a connection gas path through the carrier gas path. The sample gas path has two flow resistances in front of and behind a branch point of a connection gas path. One resistance lies between the carrier gas source and a metering unit and a gas volume of the sample gas path between the branch point of the connection gas path and the other flow resistance is dimensioned such that the sample slug only reaches the second resistance after extraction and diversion of the metered amount.

Abstract translation: 用于计量载气流中的气体样品的布置具有样品气体路径和载气路径，两条路径连接到载气源。 通过将不同的压力引入到样品气体路径和载气路径中，从样品块中提取计量的量并经由载气通道的连接气体路径转移到载气流中。 样品气体路径在连接气体路径的分支点的前方和后方具有两个流动阻力。 一个电阻位于载气源和计量单元之间，并且在连接气体路径的分支点和另一个流动阻力之间的样品气体路径的气体体积的尺寸设定为使得样品块在提取后仅达到第二阻力， 转入计量金额。

公开(公告)号：US09201050B2

公开(公告)日：2015-12-01

申请号：US13390885

申请日：2010-08-06

Applicant: Udo Gellert

Inventor： Udo Gellert

IPC: G01N30/00 ,  G01N30/86

CPC classification number: G01N30/8641 ,  G01N30/8631 ,  G01N30/8637 ,  G01N2030/862

Abstract: A method for improving the chromatographic detection limit for an analyte including a) producing a chromatogram with a peak of the analyte, b) calculating a regression straight line for a baseline from measured values of a section without a peak in the chromatogram, c) calculating a regression function from measured values of the peak of the analyte, d) subtracting the regression function from the chromatogram, e) calculating a regression polynomial for the baseline from the values of the chromatogram which have been changed in step d), f) calculating a further regression function from the measured values of the peak in the produced chromatogram, g) calculating a peak area between the regression polynomial and the further regression function, h) repetition of step d) with the further regression function instead of the regression function and of steps e), f) and g), until the calculated peak area changes by less than a predetermined amount.

Abstract translation: 一种用于改进分析物的色谱检测极限的方法，包括a）产生具有分析物峰的色谱图，b）从色谱图中没有峰的部分的测量值计算基线的回归直线，c）计算 从分析物峰的测量值得到的回归函数，d）从色谱图中减去回归函数，e）从步骤d）中已经改变的色谱图的值计算基线的回归多项式，f）计算 从生成的色谱图中的峰值的测量值进一步的回归函数，g）计算回归多项式和进一步回归函数之间的峰面积，h）步骤d）的重复与进一步的回归函数而不是回归函数， 的步骤e），f）和g），直到计算的峰面积改变小于预定量。

公开(公告)号：US20150219578A1

公开(公告)日：2015-08-06

申请号：US14604954

申请日：2015-01-26

Applicant: UDO GELLERT

Inventor： UDO GELLERT

IPC: G01N27/18

CPC classification number: G01N27/18 ,  G01N30/66

Abstract: A thermal conductivity detector includes at least four detector components that are arranged in receptacles of a thermal conduction block in a circle around a center axis of the thermal conduction block. The thermal conduction block comprises a central portion along the axis, the cross-axial dimensions of the central portion being less than the diameter of the circle. There are at least four equal peripheral portions that are connected solely to the central portion and are separated from each other, each of the peripheral portions carrying one of the detector components.

Abstract translation: 热传导检测器包括至少四个检测器部件，其被布置在围绕热传导块的中心轴的圆周中的导热块的插座中。 导热块包括沿轴线的中心部分，中心部分的横向轴向尺寸小于圆的直径。 至少有四个相等的外围部分仅与中心部分连接并且彼此分开，每个周边部分承载检测器部件之一。

公开(公告)号：US20130133403A1

公开(公告)日：2013-05-30

申请号：US13511925

申请日：2010-11-25

Applicant: Udo Gellert ,  Frank Probst

Inventor： Udo Gellert ,  Frank Probst

IPC: G01N30/86 ,  G01N30/04

CPC classification number: G01N30/8631 ,  G01N30/04 ,  G01N30/66 ,  G01N2030/8859 ,  G01R27/2629

Abstract: The invention relates to a gas sample to be analyzed, wherein said sample is guided by means of a carrier gas through a separator unit having a downstream thermal conductivity detector providing a chromatogram having peaks for different analytes as a measurement signal. When using a thermal conductivity detector having a heated gold thread coated with a parylene F, hydrogen is used as a carrier gas, and a peak for the analyte hydrogen sulfide is generated by differentiating the chromatogram at the location of said analyte. The invention permits unlimited use of hydrogen as a carrier gas, even if the analyte is oxygen.

Abstract translation: 本发明涉及要分析的气体样品，其中所述样品通过载气通过具有下游热导率检测器的分离器单元引导，所述分离器单元提供具有作为测量信号的不同分析物峰值的色谱图。 当使用涂有聚对二甲苯F的加热金线的热导率检测器时，使用氢气作为载气，并且通过对所述分析物的位置处的色谱进行微分分析产生分析物硫化氢的峰。 本发明允许氢气作为载气的无限制使用，即使分析物是氧气。

公开(公告)号：US08426215B2

公开(公告)日：2013-04-23

申请号：US10950395

申请日：2004-09-28

Applicant: Friedhelm Mueller ,  Udo Gellert

Inventor： Friedhelm Mueller ,  Udo Gellert

IPC: G01N30/02

CPC classification number: G01N30/461 ,  G01N30/40 ,  G01N30/465 ,  G01N30/66 ,  G01N30/78 ,  Y10T436/21

Abstract: A gas chromatograph for analyzing natural gas, with a first separation column (6). A first detector (7) is provided following the first separation column, the first separation column and the first detector operable to separate or detect propane and higher hydrocarbons. A second separation column (8) and a second detector (9) following it are provided to separate or detect carbon dioxide and ethane. A third separation column (10) and a third detector (11) following it are provided to separate or detect nitrogen and methane. A controllable changeover device (12) is provided between the second separation column (8) and the third separation column (10) to discharge eluates following methane. The first, second and third separation columns (6, 8, 10) and the first, second and third detectors (7, 9, 11) are connected in series. At least the first and the second detectors (7, 9) are operable to detect a mixture of substances flowing through them in a non-destructive manner.

Abstract translation: 用于分析天然气的气相色谱仪，具有第一分离柱（6）。 在第一分离柱之后提供第一检测器（7），第一分离柱和第一检测器可操作以分离或检测丙烷和高级烃。 提供第二分离塔（8）和跟随其后的第二检测器（9）以分离或检测二氧化碳和乙烷。 提供第三分离塔（10）和随后的第三检测器（11）以分离或检测氮和甲烷。 在第二分离塔（8）和第三分离塔（10）之间设置可控切换装置（12），以排出甲烷后的洗脱液。 第一，第二和第三分离柱（6,8,10）和第一，第二和第三检测器（7,9,11）串联连接。 至少第一和第二检测器（7,9）可操作以检测以非破坏性方式流过它们的物质的混合物。

公开(公告)号：US20050123452A1

公开(公告)日：2005-06-09

申请号：US10950395

申请日：2004-09-28

Applicant: Friedhelm Mueller ,  Udo Gellert

Inventor： Friedhelm Mueller ,  Udo Gellert

IPC: G01N30/40 ,  G01N30/46 ,  G01N30/66 ,  G01N30/78 ,  G01N30/02

CPC classification number: G01N30/461 ,  G01N30/40 ,  G01N30/465 ,  G01N30/66 ,  G01N30/78 ,  Y10T436/21

Abstract: A gas chromatograph for analyzing natural gas, with a first separation column (6). A first detector (7) is provided following the first separation column, the first separation column and the first detector operable to separate or detect propane and higher hydrocarbons. A second separation column (8) and a second detector (9) following it are provided to separate or detect carbon dioxide and ethane. A third separation column (10) and a third detector (11) following it are provided to separate or detect nitrogen and methane. A controllable changeover device (12) is provided between the second separation column (8) and the third separation column (10) to discharge eluates following methane. The first, second and third separation columns (6, 8, 10) and the first, second and third detectors (7, 9, 11) are connected in series. At least the first and the second detectors (7, 9) are operable to detect a mixture of substances flowing through them in a non-destructive manner.

Abstract translation: 用于分析天然气的气相色谱仪，具有第一分离柱（6）。 在第一分离柱之后提供第一检测器（7），第一分离柱和第一检测器可操作以分离或检测丙烷和高级烃。 提供第二分离塔（8）和跟随其后的第二检测器（9）以分离或检测二氧化碳和乙烷。 提供第三分离塔（10）和随后的第三检测器（11）以分离或检测氮和甲烷。 在第二分离塔（8）和第三分离塔（10）之间设置可控切换装置（12），以排出甲烷后的洗脱液。 第一，第二和第三分离柱（6,8,10）和第一，第二和第三检测器（7,9,11）串联连接。 至少第一和第二检测器（7,9）可操作以检测以非破坏性方式流过它们的物质的混合物。