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1.发明授权
公开(公告)号：US6150576A
公开(公告)日：2000-11-21
申请号：US272411
申请日：1999-03-19
申请人： Zhaozhong Jiang , Gregory S. Long , Shahid Murtuza , Ayusman Sen , Suzanne E. Schramm , Jeffrey C. Trewella
发明人： Zhaozhong Jiang , Gregory S. Long , Shahid Murtuza , Ayusman Sen , Suzanne E. Schramm , Jeffrey C. Trewella
IPC分类号： C07C2/30 , C07C11/02 , C08F4/64 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/16 , C10M107/02 , C10M107/04 , C10M119/02 , C10M143/02 , C07F9/22
CPC分类号： C10M143/02 , C07C11/02 , C07C2/30 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C10M107/02 , C10M107/04 , C10M119/02 , C07C2527/126 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2531/14 , C07C2531/36 , C07C2531/38 , C08F10/06 , C08F210/16 , C08F2410/01 , C08F2410/04 , C08F4/65925 , C10M2205/00 , C10M2205/003 , C10M2205/02 , C10M2205/0206 , C10M2205/022 , C10M2205/14 , C10N2220/02 , Y02P20/52 , Y10S526/943
摘要： The novel synthetic polyethylene fluids of the present invention are characterized by high viscosity indices (about 94-151 VI), low pour points (about -60 to -10.degree. C.), and a kinematic viscosity of about 6 to 28 cSt KV at 100.degree. C. The product compositions comprise polymers having a molecular weight of from about 300 to 30,000 and a high branching index of 151 to 586 branches per 1000 CH.sub.2 groups, or BI=0.18-0.40, wherein the polymer is substantially free of methyl branches. Highly-branched polyethylene fluids that have less than 5 methyl branches per 1000 CH.sub.2 groups are prepared by polymerizing ethylene in the presence of a catalyst system consisting of [C] and [B], wherein [C] is a catalyst having the empirical formula MX.sub.4 and [B] is a co-catalyst having the empirical formula R.sub.n AlX.sub.3-n, where M is a Group IVB transition metal, X is a halogen anion, R is a C.sub.1 -C.sub.20 alkyl group, and n is 1-2, in the presence of a promoter, wherein the promoter is selected from the group consisting of hydrogen or a Lewis acid such as, for example, FeCl.sub.3, AlCl.sub.3, or mixtures thereof.
摘要翻译： 本发明的新型合成聚乙烯流体的特征在于高粘度指数（约94-151VI），低倾点（约-60至-10℃）和约6至28cSt KV的运动粘度 产物组合物包含分子量为约300至30,000，高支化指数为每1000个CH 2基团为151至586个支链或BI = 0.18-0.40的聚合物，其中聚合物基本上不含甲基支链 。 通过在由[C]和[B]组成的催化剂体系的存在下聚合乙烯来制备每1000个CH 2基团具有少于5个甲基支链的高分支聚乙烯流体，其中[C]是具有经验式MX4的催化剂 和[B]是具有经验式RnAlX 3-n的助催化剂，其中M是ⅣB族过渡金属，X是卤素阴离子，R是C1-C20烷基，n是1-2，在 启动子的存在，其中启动子选自氢或路易斯酸，例如FeCl 3，AlCl 3或其混合物。
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2.发明授权Oxidatively stable esters derived from diamondoids totally hydroxylated at the bridgeheads 失效氧化稳定的酯衍生自在桥头堡全部羟基化的金刚石
公开(公告)号：US5397488A
公开(公告)日：1995-03-14
申请号：US164275
申请日：1993-12-09
IPC分类号： C07C69/00 , C10M105/32 , C10M105/38 , C10M129/72
CPC分类号： C10M105/38 , C10M105/32 , C07C2103/00 , C10M2207/2805 , C10M2207/281 , C10M2207/2815 , C10M2207/282 , C10M2207/283 , C10M2207/2835 , C10M2207/2845 , C10M2207/286 , C10M2207/345
摘要： The invention provides a composition comprising Formula I as shown below and at least one selected from the group consisting of Formulae II, III, IV, and V as shown below: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different, and comprise alkyl groups containing no tertiary carbon and having from about 4 to about 15 carbon atoms. The composition of the invention is useful as a lubricant stock. A method for synthesizing the composition is also disclosed.
摘要翻译： 本发明提供了包含如下所示的式I的组合物和选自由下式II，III，IV和V组成的组中的至少一种：下式表示：式I式 式V其中R 1，R 2，R 3和R 4相同或不同，并且包含不含叔碳原子且具有约4至约15个碳原子的烷基。 本发明的组合物可用作润滑剂原料。 还公开了合成该组合物的方法。
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3.发明授权Conversion of Fischer-Tropsch heavy end products with platinum/boron-zeolite beta catalyst having a low alpha value 失效用低α值的铂/硼沸石β催化剂转化费 - 托重端产物
公开(公告)号：US5362378A
公开(公告)日：1994-11-08
申请号：US992354
申请日：1992-12-17
CPC分类号： B01J29/7007 , B01J29/7415 , B01J2229/20 , B01J2229/36 , C10G2400/10 , Y10S208/95
摘要： The use of high silica to alumina ratio large pore zeolites, in combination with a hydrogenation/dehydrogenation component, to convert Fischer-Tropsch heavy end products which may contain paraffins, olefins and oxygenates into low pour point distillates with high cetane number and extra high VI lube is described. The lube can be dewaxed by a conventional solvent process, by a catalytic process, or by increasing the severity of the hydroisomerization step.
摘要翻译： 使用高二氧化硅与氧化铝比较的大孔沸石与氢化/脱氢组分相结合，将可能含有链烷烃，烯烃和含氧化合物的费 - 托重末端产物转化成具有高十六烷值和超高VI的低倾点馏出物 润滑油被描述。 润滑油可以通过常规溶剂方法，催化方法或通过增加加氢异构化步骤的严重性来脱蜡。
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公开(公告)号：US5210347A
公开(公告)日：1993-05-11
申请号：US764258
申请日：1991-09-23
IPC分类号： C07B61/00 , C07C2/12 , C07C6/04 , C07C9/22 , C10G50/00 , C10G50/02 , C10G69/12 , C10L1/00 , C10L10/08 , C10L10/12 , C10M105/04 , C10N30/02
CPC分类号： C07C9/22 , C07C6/04 , C10G50/02 , C10G69/126 , C07C2521/08 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2529/40 , C07C2529/70 , C07C2531/12 , C07C2531/26 , C07C2531/34
摘要： The 350.degree.-650.degree. F. (177.degree.-343.degree. C.) portion of the product from the oligomerization of light olefin with surface deactivated shape selective medium pore zeolite catalyst particles comprises olefinic hydrocarbons having unique and desirable structures as precursors for high cetane value clean fuels. These oligomers are near linear in structure and contain no aromatics. Following hydrogenation they produce cetane values between 50 and 75. When the near linear olefinic hydrocarbons from surface deactivated zeolite catalyzed oligomerization of light olefins are subjected to ethene metathesis to alpha olefins and oligomerization following the process of Chen et al in U.S. Pat. No. 4,962,249 the overall process reaction product comprises a mixture of a 650.degree. F.+ portion comprising high VI lubricant and a 350.degree.-650.degree. F. portion comprising high cetane clean fuels precursor. Hydrogenation of the 350.degree.-650.degree. F. portion provides an aromatics-free fuel with a cetane value between 50-75 containing less than 0.5 wt % naphthenes. The combined process results in the co-production of high cetane clean fuels and high VI synthetic lubricant.
摘要翻译： 来自轻烯烃与表面失活形状选择性中孔沸石催化剂颗粒的低聚物的350°-650°F（177°-343℃）部分包含具有独特和期望结构的烯烃，作为高十六烷值的前体 价值清洁燃料。 这些低聚物在结构上接近线性并且不含芳族化合物。 在氢化之后，它们产生的十五烷值在50和75之间。当Chen等人在美国专利中的过程中，当来自表面失活的沸石催化的轻质烯烃低聚的近线性烯烃受到乙烯复分解为α-烯烃和低聚。 第4,962,249号总体工艺反应产物包括含有高VI润滑剂的650°F +部分和包含高十六烷值清洁燃料前体的350-650°F部分的混合物。 350°-650°F部分的氢化提供无芳族化合物的燃料，十五烷值在50-75之间，含有小于0.5重量％的环烷烃。 组合的工艺产生了高十六烷值清洁燃料和高VI合成润滑剂的共同生产。
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5.发明授权
公开(公告)号：US6063973A
公开(公告)日：2000-05-16
申请号：US272410
申请日：1999-03-19
申请人： Ayusman Sen , Suzanne E. Schramm , Jeffrey C. Trewella , Zhaozhong Jiang , Gregory S. Long , Shahid Murtuza
发明人： Ayusman Sen , Suzanne E. Schramm , Jeffrey C. Trewella , Zhaozhong Jiang , Gregory S. Long , Shahid Murtuza
IPC分类号： C07C2/30 , C07C11/02 , C08F4/64 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/16 , C10M107/02 , C10M107/04 , C10M119/02 , C10M143/02 , C07F9/22
CPC分类号： C10M143/02 , C07C11/02 , C07C2/30 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C10M107/02 , C10M107/04 , C10M119/02 , C07C2527/126 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2531/14 , C07C2531/36 , C07C2531/38 , C08F10/06 , C08F210/16 , C08F2410/01 , C08F2410/04 , C08F4/65925 , C10M2205/00 , C10M2205/003 , C10M2205/02 , C10M2205/0206 , C10M2205/022 , C10M2205/14 , C10N2220/02 , Y02P20/52 , Y10S526/943
摘要： The novel synthetic polyethylene fluids of the present invention are characterized by high viscosity indices (about 94-151 VI), low pour points (about -60 to -10.degree. C.), and a kinematic viscosity of about 6 to 28 cSt KV at 100.degree. C. The product compositions comprise polymers having a molecular weight of from about 300 to about 30,000 and a branching index of 151 to 586 branches per 1000 CH.sub.2 groups, or BI=0.18-0.40. A process for preparing such novel synthetic polyethylene fluids comprises polymerizing ethylene in the presence of a catalyst system, said catalyst system comprising [A] and [B], wherein [A] is a catalyst having the formula MX.sub.5 and [B] is a co-catalyst having the formula R.sub.n AlX.sub.3-n where M is a Group VB, VIB, or VIII transition metal; X is a halogen anion; R is a C.sub.1 -C.sub.20 alkyl group; and n is 1-2.
摘要翻译： 本发明的新型合成聚乙烯流体的特征在于高粘度指数（约94-151VI），低倾点（约-60至-10℃）和约6至28cSt KV的运动粘度 产物组合物包含分子量为约300至约30,000的支链指数为每1000个CH2基团151至586个支链或BI = 0.18-0.40的聚合物。 制备这种新型合成聚乙烯流体的方法包括在催化剂体系存在下聚合乙烯，所述催化剂体系包含[A]和[B]，其中[A]是具有式MX5和[B]的催化剂， - 具有式R n AlX 3-n的催化剂，其中M是VB，VIB或VIII族过渡金属; X是卤素阴离子; R是C1-C20烷基; n为1-2。
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公开(公告)号：US5057203A
公开(公告)日：1991-10-15
申请号：US519966
申请日：1990-05-07
CPC分类号： C10G35/065 , B01J29/87
摘要： The invention relates to framework gallium containing ultrastable Y having a framework (silica:alumina+gallium oxide) SiO.sub.2 /(Al.sub.2 O.sub.3 +Ga.sub.2 O.sub.3) mole ratio of 18:1 which contains at least 2.2% framework gallium. Moreover, the invention includes use of the framework gallium containing ultrastable Y in hydrocarbon conversion processes, such as reforming, catalytic cracking and aromatization.
摘要翻译： 本发明涉及含有至少含有2.2％骨架镓的骨架（二氧化硅：氧化铝+氧化镓）SiO 2 /（Al 2 O 3 + Ga 2 O 3）摩尔比为18:1的框架镓超稳定Y。 此外，本发明包括在烃转化过程如重整，催化裂化和芳构化中使用含有超稳定Y的骨架镓。
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公开(公告)号：US06365767B1
公开(公告)日：2002-04-02
申请号：US09322880
申请日：1999-08-20
申请人： Clarence D. Chang , Zhaozhong Jiang , Rene B. LaPierre , Suzanne E. Schramm , Hye Kyung Cho Timken
发明人： Clarence D. Chang , Zhaozhong Jiang , Rene B. LaPierre , Suzanne E. Schramm , Hye Kyung Cho Timken
IPC分类号： C07C6996
CPC分类号： C07C68/065 , C07C69/96
摘要： A method is provided for co-producing dialkyl carbonate and alkanediol by reacting alkylene carbonate with alkanol in the presence of a zeolite catalyst which contains alkali metal, alkaline earth metal, or a combination thereof present in excess of a stoichiometric amount.
摘要翻译： 提供了一种通过在含有超过化学计量的碱金属，碱土金属或其组合的沸石催化剂存在下使碳酸亚烷基酯与链烷醇反应来共同生产碳酸二烷基酯和链烷二醇的方法。
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