公开(公告)号：US5369186A

公开(公告)日：1994-11-29

申请号：US790630

申请日：1991-11-12

Applicant: Maurizio Galimberti ,  Umberto Giannini ,  Romano Mazzocchi ,  Enrico Albizzati ,  Umberto Zucchini

Inventor： Maurizio Galimberti ,  Umberto Giannini ,  Romano Mazzocchi ,  Enrico Albizzati ,  Umberto Zucchini

IPC: C08F8/00 ,  C08F8/12 ,  C08F8/26 ,  C08F10/00 ,  C08F210/00 ,  C08F210/06 ,  C08F210/16 ,  C08F214/16 ,  C08F226/06

CPC classification number: C08F210/00 ,  C08F210/06 ,  C08F210/16

Abstract: Disclosed are polymers and copolymers of CH.sub.2 .dbd.CHR alpha olefins where R is hydrogen or a 1-6 carbon atom alkyl radical, containing in the chain from 0.1 to 40 mole % of monomeric units ##STR1## where X is selected from the group consisting of (CH.sub.2).sub.r CH.sub.2 CH.sub.2 Y ##STR2## where r=0-10, Y is a halogen atom, R.sup.1 is a hydrocarbon radical with 1-18 carbon atoms.

Abstract translation: 公开了CH2 =CHRα烯烃的聚合物和共聚物，其中R是氢或1-6个碳原子的烷基，其中链中含有0.1至40摩尔％的单体单元，其中X选自 （CH2）rCH2CH2Y CH2）rCHCH2（CH2）r + 2OCOR1（CH2）r + 2OR1（CH2）r + 2CH（COOR1）2（CH2）r + 2OH（CH2）r + 2CH2COOH 其中r = ，Y是卤素原子，R1是具有1-18个碳原子的烃基。

公开(公告)号：US5196496A

公开(公告)日：1993-03-23

申请号：US721049

申请日：1991-06-26

Applicant: Maurizio Galimberti ,  Enrico Albizzati ,  Romano Mazzocchi

Inventor： Maurizio Galimberti ,  Enrico Albizzati ,  Romano Mazzocchi

IPC: C08F4/642 ,  C08F4/60 ,  C08F4/659 ,  C08F4/6592 ,  C08F8/00 ,  C08F210/06

CPC classification number: C08F210/06 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/901

Abstract: Essentially syndiotactic crystalline copolymers of propylene with minor proportions of 1-butene, endowed with good mechanical properties, lowered melting point and limited solubility in xylene at 25.degree. C. and the process for their preparation by polymerizing mixtures of propylene with 1-butene, by using catalysts obtained form stereorigid and chiral zirconium and hafnium compounds and from polymethylalumoxane compounds.

公开(公告)号：US5516866A

公开(公告)日：1996-05-14

申请号：US279671

申请日：1994-07-25

Applicant: Luigi Resconi ,  Enrico Albizzati ,  Romano Mazzocchi

Inventor： Luigi Resconi ,  Enrico Albizzati ,  Romano Mazzocchi

IPC: C08F4/645 ,  C08F4/60 ,  C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/06 ,  C08F210/06 ,  C08F210/16 ,  C08F4/642

CPC classification number: C08F210/06 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

Abstract: Novel crystalline copolymers of propylene with minor proportions of ethylene and/or alpha-olefins, endowed with very good mechanical properties, a low melting point and a limited solubility in xylene at 25.degree. C., and the process for preparing them by means of the polymerization of mixtures of propylene with ethylene and/or alpha-olefins of suitable composition, by using catalysts obtained from stereorigid and chiral compounds of zirconium, and methylalumoxanic compounds.

Abstract translation: 丙烯与较少比例的乙烯和/或α-烯烃的新型结晶共聚物具有非常好的机械性能，在25℃下具有低熔点和在二甲苯中的溶解度有限的方法，以及通过 通过使用由立体刚性和锆的手性化合物得到的催化剂和甲基铝氧烷化合物，聚合丙烯与乙烯和/或合适组成的α-烯烃的混合物。

公开(公告)号：US5260389A

公开(公告)日：1993-11-09

申请号：US866927

申请日：1992-04-10

Applicant: Luigi Resconi ,  Romano Mazzocchi ,  Fabrizio Piemontesi

Inventor： Luigi Resconi ,  Romano Mazzocchi ,  Fabrizio Piemontesi

IPC: C08F4/622 ,  C08F4/60 ,  C08F4/6392 ,  C08F4/642 ,  C08F32/00 ,  C08F32/06 ,  C08F136/20 ,  C08F36/20

CPC classification number: C08F136/20 ,  Y10S526/943

Abstract: Highly crystalline high melting 1,5-hexadiene cyclopolymers are prepared by carrying out the polymerization in the presence of a catalyst comprising a specific Zr or Hf metallocene compound and specific alumoxane compounds.

公开(公告)号：US4336360A

公开(公告)日：1982-06-22

申请号：US117789

申请日：1980-02-01

Applicant: Umberto Giannini ,  Antonio Cassata ,  Paolo Longi ,  Romano Mazzocchi

Inventor： Umberto Giannini ,  Antonio Cassata ,  Paolo Longi ,  Romano Mazzocchi

IPC: C08F4/00 ,  B01J27/14 ,  B01J27/24 ,  C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F4/649 ,  C08F4/651 ,  C08F4/654 ,  C08F4/659 ,  C08F10/00 ,  C08F10/04 ,  C08F110/06

CPC classification number: C08F10/00 ,  C08F4/022

Abstract: There is disclosed a process for the stereoregular polymerization of alpha-olefins or mixtures thereof with ethylene, conducted in the presence of highly active and stereospecific new catalysts. The catalysts are obtained from the reaction of a particular Al-alkyl compound which is at least in part in the form of a complex and/or a substitution reaction product with an ester of an oxygenated organic or inorganic acid, with a supported component characterized by having surface area exceeding certain values or showing a particular X-rays spectrum, and obtained by contacting a Ti halogenated compound, preferably in the form of a complex with an electron-donor compound, with a support comprising a Mg or Mn bihalide in an activated condition. In the catalysts the ratio between the Ti compound, expressed in Ti g-atoms, and the g moles of the ester and the electron-donor compound, when present, is lower than 0.3.

Abstract translation: 公开了在高活性和立体特异性新型催化剂存在下进行的α-烯烃或其与乙烯的混合物的立构规整聚合的方法。 催化剂是由至少部分以络合物和/或取代反应产物形式的特定的Al-烷基化合物与含氧有机或无机酸的酯与负载的组分的反应获得的， 其表面积超过某些值或显示特定的X射线光谱，并且通过使配合物与电子给体化合物形式的Ti卤化化合物与包含Mg或Mn二卤化物的载体接触而被活化 条件。 在催化剂中，以Ti原子表示的Ti化合物与酯和电子给体化合物的g摩尔比（当存在时）之比小于0.3。

公开(公告)号：US4187196A

公开(公告)日：1980-02-05

申请号：US955762

申请日：1978-10-30

Applicant: Umberto Giannini ,  Antonio Cassata ,  Paolo Longi ,  Romano Mazzocchi

Inventor： Umberto Giannini ,  Antonio Cassata ,  Paolo Longi ,  Romano Mazzocchi

IPC: C08F4/02 ,  C08F4/64 ,  C08F10/00 ,  C08F10/06

CPC classification number: C08F10/00 ,  C08F4/022 ,  Y10S526/906

Abstract: There is disclosed a process for the stereoregular polymerization of alpha-olefins or mixtures thereof with ethylene, conducted in the presence of highly active and stereospecific new catalysts. The catalysts are obtained from the reaction of a particular Al-alkyl compound which is at least in part in the form of a complex and/or a substitution reaction product with an ester of an oxygenated organic or inorganic acid, with a supported component characterized by having surface area exceeding certain values or showing a particular X-rays spectrum, and obtained by contacting a Ti halogenated compound, preferably in the form of a complex with an electron-donor compound, with a support comprising a Mg or Mn bihalide in an activated condition.In the catalysts the ratio between the Ti compound, expressed in Ti g-atoms, and the g moles of the ester and the electron-doner compound, when present, is lower than 0.3.

Abstract translation: 公开了在高活性和立体特异性新型催化剂存在下进行的α-烯烃或其与乙烯的混合物的立构规整聚合的方法。 催化剂是由至少部分以络合物和/或取代反应产物形式的特定的Al-烷基化合物与含氧有机或无机酸的酯与负载的组分的反应获得的， 其表面积超过某些值或显示特定的X射线光谱，并且通过使配合物与电子给体化合物形式的Ti卤化化合物与包含Mg或Mn二卤化物的载体接触而被活化 条件。 在催化剂中，当Ti原子表示的Ti化合物与酯和电子给体化合物的g摩尔比（当存在时）之比小于0.3。

公开(公告)号：US4107413A

公开(公告)日：1978-08-15

申请号：US779739

申请日：1977-03-21

Applicant: Umberto Giannini ,  Antonio Cassata ,  Paolo Longi ,  Romano Mazzocchi

Inventor： Umberto Giannini ,  Antonio Cassata ,  Paolo Longi ,  Romano Mazzocchi

IPC: C08F4/02 ,  C08F10/00 ,  C08F10/06

CPC classification number: C08F10/00 ,  C08F4/022 ,  Y10S526/906

Abstract: There is disclosed a process for the stereoregular polymerization of alpha olefins or mixtures thereof with ethylene conducted in the presence of highly active and stereospecific new catalysts.The catalysts are obtained from the reaction of a component (A) which is a particular Al-alkyl compound that is at least in part in the form of an addition and/or a substitution reaction product with an electron-donor compound free from ester groups of oxygenated organic and inorganic acids, with a component (B) which is a supported component characterized by having surface area exceeding certain values or by showing a particular X-rays spectrum, and prepared by contacting a halogenated Ti compound, preferably in the form of a complex with an electron-donor compound, with a support comprising a Mg or Mn dihalide in an active state.In the catalysts the ratio between the Ti compound expressed in Ti g-atoms and the g-moles of the electron-donor compounds is lower than 0.3.

Abstract translation: 公开了在高活性和立体特异性新型催化剂存在下，α-烯烃或其与乙烯的混合物的立构规整聚合的方法。

公开(公告)号：US4725631A

公开(公告)日：1988-02-16

申请号：US887815

申请日：1986-07-21

Applicant: Catia Bastioli ,  Giancarlo Romano ,  Romano Mazzocchi

Inventor： Catia Bastioli ,  Giancarlo Romano ,  Romano Mazzocchi

IPC: C08F20/00 ,  A61K6/08 ,  A61K6/083 ,  C07C43/225 ,  C07C43/23 ,  C07C69/54 ,  C07C69/653 ,  C08F20/10 ,  C08F20/30 ,  C08F120/30 ,  A61K6/00 ,  A61F2/00

CPC classification number: A61K6/083 ,  C08F20/30

Abstract: Acrylic diesters of bisphenol-alkyl-ether of formula: ##STR1## in which R.sub.1 and R.sub.2 may be a halogen or a C.sub.1 -C.sub.7 alkyl radical optionally halogen-substituted, and R.sub.3 may be hydrogen, halogen, or a C.sub.1 -C.sub.7 alkyl radical optionally halogen-substituted. Polymers obtained from the acrylic diesters of bisphenol-alkyl-ether of formula (1) and dental composites containing said acrylic diesters.

Abstract translation: 双酚 - 烷基醚的丙烯酸二酯，其分子式为：其中R 1和R 2可以是卤素或任选被卤素取代的C 1 -C 7烷基，R 3可以是氢，卤素或 任选被卤素取代的C 1 -C 7烷基。 由式（1）的双酚 - 烷基醚的丙烯酸二酯获得的聚合物和含有丙烯酸二酯的牙科复合物。

公开(公告)号：US4614727A

公开(公告)日：1986-09-30

申请号：US701530

申请日：1985-02-14

Applicant: Paolo Longi ,  Umberto Giannini ,  Romano Mazzocchi

Inventor： Paolo Longi ,  Umberto Giannini ,  Romano Mazzocchi

IPC: C08F4/64 ,  C08F10/02

CPC classification number: C08F10/02 ,  Y10S526/906

Abstract: Polymerization catalysts, more particularly catalysts for the polymerization of ethylene and mixtures thereof with other monomers copolymerizable therewith, are disclosed. The catalysts are prepared by mixing (A) an organometallic compound or hydride of a metal belonging to Groups I, II or III of the Mendelyeev Periodic Table, with (B) the reaction product of (1) a titanium compound of the type (NR.sub.4).sub.p Ti.sub.m X.sub.(n.m)+p, in which R.sub.4 is hydrogen and/or hydrocarbon radicals, X.sub.n.m represents halogen atoms or, in part, OR' groups in which R' is an organic radical; n represents the Ti valence, and m and p are the whole numbers 1, 2 or 3; and (2) a carrier comprising an anhydrous magnesium halide.

Abstract translation: 公开了聚合催化剂，更特别的是用于乙烯聚合的催化剂及其与可与其共聚的其它单体的混合物。 催化剂通过将（A）属于门多利夫周期表第I，II或III族的金属的有机金属化合物或氢化物与（B）（1）钛化合物（NR4）的反应产物 ）pTimX（nm）+ p，其中R4是氢和/或烃基，Xn.m表示卤素原子，或部分地是其中R'是有机基团的OR'基团; n表示Ti价，m和p为整数1,2或3; 和（2）包含无水卤化镁的载体。

公开(公告)号：US4226963A

公开(公告)日：1980-10-07

申请号：US959604

申请日：1978-11-13

Applicant: Umberto Giannini ,  Antonio Cassata ,  Paolo Longi ,  Romano Mazzocchi

Inventor： Umberto Giannini ,  Antonio Cassata ,  Paolo Longi ,  Romano Mazzocchi

IPC: C08F4/02 ,  C08F10/00 ,  C08F10/06

CPC classification number: C08F10/00 ,  C08F4/022 ,  Y10S526/902 ,  Y10S526/906

Abstract: There is disclosed a process for the stereoregular polymerization of alpha olefins or mixtures thereof with ethylene conducted in the presence of highly active and stereospecific new catalysts. The catalysts are obtained from the reaction of a particular Al-alkyl compound which is at least in part in the form of a complex and/or a substitution reaction product with an electron-donor compound free from ester groups of oxygenated organic and inorganic acids, with a supported component characterized by having surface area exceeding certain values or by showing a particular X-rays spectrum and which is obtained by contacting a halogenated Ti compound, preferably in the form of a complex with an electron-donor compound, with a support comprising a Mg or Mn dihalide in an active state. In the catalysts the ratio between the Ti compound expressed in Ti g-atoms and the g-moles of the electron donor compounds is lower than 0.3.

Abstract translation: 公开了在高活性和立体特异性新型催化剂存在下，α-烯烃或其与乙烯的混合物的立构规整聚合方法。 催化剂是由至少部分为配合物和/或取代反应产物形式的特定的Al-烷基化合物与不含氧化的有机和无机酸的酯基的电子给体化合物的反应获得的， 其特征在于具有超过某些值的表面积或通过显示特定的X射线光谱，并且其通过使配合物形式的卤化Ti化合物与电子给体化合物接触而获得，所述载体包含 处于活性状态的Mg或Mn二卤化物。 在催化剂中，Ti原子表示的Ti化合物与电子给体化合物的g-摩尔比为0.3以下。