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公开(公告)号：US5310861A
公开(公告)日：1994-05-10
申请号：US904192
申请日：1992-06-19
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
Abstract: Aramids, which in the drawn state have high tensile strengths tensile elongations, and tensile moduli, are made from units derived from p-phenylenediamine, terephthalic acid, a substituted terephthalic acid, and 4,4'-bibenzoic acid or 2,6-naphthalene dicarboxylic acid. The aramids are useful for ropes and composites.
Abstract translation: 在拉伸状态下具有拉伸强度拉伸伸长率和拉伸模量的芳族聚酰胺由来自对苯二胺，对苯二甲酸，取代对苯二甲酸和4,4'-二苯甲酸或2,6-萘的单元制成 二羧酸。 芳族聚酰胺可用于绳索和复合材料。
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2.发明授权Tough, high strength fibers of copolyesters prepared from isophthalic acid; 4,4'-oxydibenzoic acid; and hydroquinone diacetate 失效广泛的由强酸制备的共聚物的高强度纤维; 4,4'-氧代苯甲酸 和氢氯酸二钠
公开(公告)号：US5175236A
公开(公告)日：1992-12-29
申请号：US683052
申请日：1991-04-10
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
IPC: D01F6/62 , C08G63/191 , D01F6/84
CPC classification number: D01F6/84
Abstract: Tough, high strength fibers of copolyesters from hydroquinone, isophthalic acid and 4,4'-oxydibenzoic acid in defined proportions.
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公开(公告)号：US4383105A
公开(公告)日：1983-05-10
申请号：US334891
申请日：1981-12-28
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
CPC classification number: C08G73/16
Abstract: High modulus filaments are melt-spun from polyimide-esters derived from I 6-hydroxy-2-naphthoic acid, a diphenol and 4-carboxy-N-(p-carboxyphenyl)-phthalimide; II 6-hydroxy-2-naphthoic acid, an aromatic dicarboxylic acid 4-hydroxy-N-(p-hydroxyphenyl)phthalimide; or III 6-hydroxy-2-naphthoic acid, 4-hydroxybenzoic acid and 4-carboxy-N-(p-hydroxyphenyl)phthalimide. The polyimide esters are optically anisotropic in the melt. As-spun filaments from these polymers can be heat treated while free from tension to increase their tenacity.
Abstract translation: 来自I 6-羟基-2-萘甲酸，二酚和4-羧基-N-（对羧基苯基） - 邻苯二甲酰亚胺的聚酰亚胺酯熔融纺丝高模量长丝; II 6-羟基-2-萘甲酸，芳族二羧酸4-羟基-N-（对羟基苯基）邻苯二甲酰亚胺; 或III- 6-羟基-2-萘甲酸，4-羟基苯甲酸和4-羧基-N-（对羟基苯基）邻苯二甲酰亚胺。 聚酰亚胺酯在熔体中是光学各向异性的。 来自这些聚合物的纺丝长丝可以在没有张力的情况下进行热处理以增加它们的韧性。
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公开(公告)号：US4335232A
公开(公告)日：1982-06-15
申请号：US281200
申请日：1981-07-07
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
CPC classification number: C08G63/605 , C08G63/682
Abstract: Fiber-forming aromatic polyester consisting essentially of 1,4-dioxyphenylene units, lower alkyl or halo-1,4-dioxyphenylene units, terephthaloyl units and 3-carbonyl-4'-oxybenzophenone or 4-carbonyl-4'-oxybenzophenone units or chloro- and/or methyl substituted homologs of these.
Abstract translation: 基本上由1,4-二氧代亚苯基单元，低级烷基或卤代-1,4-二氧代亚苯基单元组成的成纤芳香族聚酯，对苯二甲酰单元和3-羰基-4'-氧二苯甲酮或4-羰基-4'-氧二苯甲酮单元或氯 - 和/或甲基取代的同系物。
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5.发明授权Aromatic polyester which forms optically anisotropic melts and filaments thereof 失效形成光学各向异性熔体的芳族聚酯及其长丝
公开(公告)号：US4269965A
公开(公告)日：1981-05-26
申请号：US76799
申请日：1979-09-17
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
IPC: C08G63/00 , C07C45/46 , C07C45/67 , C07C49/83 , C07C49/84 , C08G63/06 , C08G63/60 , C08G63/672 , C08G63/68 , C08G63/682 , D01F6/84 , D01F6/86
CPC classification number: D01F6/86 , C07C45/46 , C07C45/673 , C07C49/83 , C07C49/84 , C08G63/605 , C08G63/672 , C08G63/682 , D01F6/84
Abstract: An aromatic polyester consisting essentially of (1) p-oxybenzoyl units or the 3-methyl- or 3-chloro-derivatives thereof; (2) 3,4'-dioxydiphenylether or 3,4'-dioxybenzophenone units or the 3'-methyl- or 3'-chloro- derivatives thereof or terephthaloyldi (3-methyl-4-oxybenzene) units; and (3) terephthaloyl units and filaments thereof.
Abstract translation: 基本上由（1）对羟基苯甲酰基单元或其3-甲基或3-氯代衍生物组成的芳族聚酯; （2）3,4'-二氧二苯醚或3,4'-二氧二苯甲酮单元或其3'-甲基或3'-氯 - 衍生物或对苯二甲酰二（3-甲基-4-氧苯）单元; 和（3）对苯二甲酰单元及其长丝。
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Patent Agency Ranking6.发明授权Polyesters derived from 3,4'-dihydroxy-benzophenones or 3-hydroxy-4'-(4-hydroxyphenyl-)benzophenone and certain aromatic dicarboxylic acids and filaments thereof 失效衍生自3,4'-二羟基 - 二苯甲酮或3-羟基-4' - （4-羟基苯基）二苯甲酮和某些芳族二羧酸及其长丝的聚酯
公开(公告)号：US4245082A
公开(公告)日：1981-01-13
申请号：US54448
申请日：1979-07-09
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
Abstract: High modulus filaments are melt-spun from polyesters which are derived from 3,4'-dihydroxybenzophenones or 3-hydroxy-4'-(4-hydroxyphenyl-)benzophenone and terephthalic, 2,6-naphthalene dicarboxylic, or bibenzoic acid. The polyesters are optically anisotropic in the melt. As-spun filaments from these polyesters can be heat treated while free from tension to increase their tenacity.
Abstract translation: 高模量长丝由衍生自3,4'-二羟基二苯甲酮或3-羟基-4' - （4-羟基苯基）二苯甲酮和对苯二甲酸，2,6-萘二羧酸或双苯甲酸的聚酯熔融纺丝。 聚酯在熔体中是光学各向异性的。 来自这些聚酯的纺丝长丝可以在没有张力的情况下进行热处理以增加它们的韧性。
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公开(公告)号：US5543492A
公开(公告)日：1996-08-06
申请号：US399330
申请日：1995-03-06
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
Abstract: Aramid polymers with small amounts of alkyl- and/or alkoxy-substitution on their aromatic diamine and/or aromatic diacid monomeric units are disclosed. Such aramid polymers show improved properties compared to similar aramids without the substitution. The aramids described herein are useful for films or fibers, for example, as employed in the manufacture of packaging, ropes, filter bags, or composites. The invention also includes a process for making such polymers, involving subjecting fibers or films made from such aramid polymers to heat treatment under tension.
Abstract translation: 公开了在其芳族二胺和/或芳族二酸单体单元上具有少量烷基和/或烷氧基取代的芳族聚酰胺聚合物。 与没有取代的类似芳族聚酰胺相比，这种芳族聚酰胺聚合物显示出改进的性能。 本文所述的芳族聚酰胺可用于膜或纤维，例如用于制造包装，绳索，过滤袋或复合材料中的纤维。 本发明还包括一种制备这种聚合物的方法，包括使由这种芳族聚酰胺聚合物制成的纤维或薄膜在张力下进行热处理。
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公开(公告)号：US5292856A
公开(公告)日：1994-03-08
申请号：US44013
申请日：1993-04-08
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
CPC classification number: C08G69/32 , C08G69/12 , C08G69/265
Abstract: High molecular weight polyamides having benzidine linkages are prepared using certain substituted benzidine monomers.
Abstract translation: 使用某些取代的联苯胺单体制备具有联苯胺键的高分子量聚酰胺。
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公开(公告)号：US5288835A
公开(公告)日：1994-02-22
申请号：US65300
申请日：1993-05-21
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
CPC classification number: C08G63/672 , C08G73/16
Abstract: Isotropic polyesters containing a repeat unit derived from 4,4'-bis(3-hydroxyphenoxy)biphenyl, and especially poly(imide-esters) containing that diol, trimellitic anhydride and at least one diamine and/or aminocarboxylic acid. Such polyesters have a good combination of physical and melt properties, making them easy to shape and them useful for mechanical parts and fibers.
Abstract translation: 包含衍生自4,4'-双（3-羟基苯氧基）联苯的重复单元，特别是含有该二醇，偏苯三酸酐和至少一种二胺和/或氨基羧酸的聚（酰亚胺 - 酯）的各向同性聚酯。 这种聚酯具有良好的物理和熔融性质的组合，使得它们易于成型，并且它们可用于机械部件和纤维。
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10.发明授权Spin dopes from poly[2,2'-bis(trifluoromethyl)benzidine terephthalamide] and from poly[2,2'-bis(1,1,2,2-tetrafluoroethoxy benzidine terephthalamide] 失效来自聚[2,2'-双（三氟甲基）联苯胺对苯二甲酰胺]和聚[2,2'-双（1,1,2,2-四氟乙氧基联苯胺对苯二甲酰胺）
公开(公告)号：US5219898A
公开(公告)日：1993-06-15
申请号：US868689
申请日：1992-04-15
Applicant: Robert S. Irwin
Inventor： Robert S. Irwin
IPC: D01F6/60
CPC classification number: D01F6/605
Abstract: Anisotropic solutions are prepared from poly[2,2'-bis(trifluoromethyl)benzidine terephthalamide] or poly[2,2'-bis(1,1,2,2-tetrafluoroethoxy)benzidine terephthalamide] in amide solvents containing certain chlorides in specified amount. Crystalline fibers are prepared from the polymers.
Abstract translation: 各向异性溶液由含有特定氯化物的酰胺溶剂中的聚[2,2'-双（三氟甲基）联苯胺对苯二甲酰胺]或聚[2,2'-双（1,1,2,2-四氟乙氧基）联苯胺对苯二胺] 量。 从聚合物制备结晶纤维。
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