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公开(公告)号：US20180244891A1
公开(公告)日：2018-08-30
申请号：US15966098
申请日：2018-04-30
发明人： Steven R. Allen , Vlodek Gabara , Joseph Lenning Lowery , Steven Raymond Lustig , Christopher William Newton , David J. Rodini , Andrew J. Sitter
CPC分类号： C08K3/30 , C08K2003/309 , D01D10/06 , D01F6/74 , D01F6/805 , D01F11/08 , Y10T428/249921
摘要： The present invention concerns fiber made from a polymer comprising imidazole groups, fiber further having: i) a halide anion, the halide anion being present in an amount of 0.05 to 20.1 weight percent, based on weight of fiber; and ii) sulfur, wherein the sulfur is present in the fiber in an amount of 0.05 to 3 weight percent; the fiber exhibiting hydrochloric acid evolution as identified by TGA-IR between 277.13° C. to 448.19° C.
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2.发明授权Process for preparing yarn derived from aramid copolymer fiber having low residual sulfur 有权用于制备具有低残留硫的芳族聚酰胺共聚物纤维得到的纱线的方法公开(公告)号：US09315923B2
公开(公告)日：2016-04-19
申请号：US14371444
申请日：2012-01-11
申请人： Steven R. Allen , Vlodek Gabara , Joseph Lenning Lowery , Steven Raymond Lustig , Christopher William Newton , David J. Rodini , Andrew J. Sitter
发明人： Steven R. Allen , Vlodek Gabara , Joseph Lenning Lowery , Steven Raymond Lustig , Christopher William Newton , David J. Rodini , Andrew J. Sitter
摘要： The present invention concerns processes for producing a yarn comprising polymer comprising imidazole groups, the process having the following steps: (a) spinning a solution of polymer in sulfuric acid to give rise to a plurality of dope filaments; (b) coagulating the plurality of dope filaments into a multi-filament as-spun yarn; and (c) washing the as-spun multi-filament yarn with an aqueous acid comprising a halide or an aqueous salt comprising a halide or combination thereof.
摘要翻译： 本发明涉及生产包含咪唑基团的聚合物的纱线的方法，该方法具有以下步骤：（a）将聚合物溶液在硫酸中纺丝以产生多个涂料丝; （b）将多根纺丝原丝凝结成纺丝纱; 和（c）用包含卤化物或包含卤化物或其组合的盐水的含水酸洗涤初纺复丝纱线。
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公开(公告)号：US20150354093A1
公开(公告)日：2015-12-10
申请号：US14758165
申请日：2013-12-19
发明人： Tae Hak PARK , Bum Hoon LEE , Jae Young LEE , Young Cheol PARK , Kyeong Hwan RHO
摘要： The present invention provides a method for manufacturing para-aramid fibers, which includes: spinning a polymeric solution containing aramid polymer in an organic solvent through a spinneret into an inert gas to partially remove the organic solvent contained in the spun fiber; contacting the spun fiber with conditioning solution, so as to maintain residual water in fiber in a range of 10 to 15%; and subjecting the treated fiber to drawing, washing and heating in a dry-spinning manner. The present invention may greatly reduce energy consumption and costs for recovery of the solvent, as compared to a conventional manufacturing method of aramid fiber in a wet-spinning manner. Further, the present invention may solve conventional problems such as corrosion of apparatus, deterioration of working environments, or the like, since a concentrated sulfuric acid solvent is not used in a spinning process. Still further, the present invention may conduct drawing and heating after maintaining the residual water in fiber in a range of 10 to 15% before drawing, thereby remarkably improving the strength and elastic modulus of the fiber.
摘要翻译： 本发明提供对位芳族聚酰胺纤维的制造方法，其包括：将含有芳族聚酰胺聚合物的有机溶剂中的聚合物溶液通过喷丝头纺丝成惰性气体，以部分除去纺丝纤维中所含的有机溶剂; 使纺丝纤维与调理溶液接触，以保持纤维中的残留水在10〜15％的范围内。 对经处理的纤维进行拉伸，洗涤和干纺加热。 与传统的芳族聚酰胺纤维的湿法纺丝方法相比，本发明可以大大降低能量消耗和回收溶剂的成本。 此外，由于在纺丝工序中不使用浓硫酸溶剂，本发明可以解决设备腐蚀，工作环境劣化等常规问题。 此外，本发明可以在拉伸前将纤维中的残留水保持在10〜15％的范围内进行拉伸加热，从而显着提高纤维的强度和弹性模量。
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公开(公告)号：US20150299905A1
公开(公告)日：2015-10-22
申请号：US14648769
申请日：2013-12-27
申请人： TEIJIN LIMITED
发明人： Hiroki SHIMADA , Hajime IZAWA
IPC分类号： D01F6/80
CPC分类号： D01F6/805 , D03D1/0035 , D03D1/0041 , D03D1/007 , D03D15/12 , D10B2331/021 , D10B2401/04 , D10B2401/22
摘要： Provided is a heat-resistant fabric made of a meta-type wholly aromatic polyamide fiber, characterized in that the abrasion resistance of the heat-resistant fabric in accordance with the JIS L1096 8.19.1 A-1 method (universal type method (plane method), abrasion tester press load: 4.45 N (0.454 kf), paper: #600) is 200 rubs or more, the tear strength of the heat-resistant fabric in accordance with the JIS L1096 8.17.4 D method (pendulum method) is 20 N or more, and the retention of the abrasion resistance and the retention of the tear strength after 100 washes in accordance with JIS L0844 No. A-1 are each 90% or more relative to before washing. As a result, the provided heat-resistant fabric can be dyed to a color chosen from a wide range of color options and is capable of maintaining high mechanical characteristics over time/age even after repeated uses or washes, etc.
摘要翻译： 提供一种由间位型全芳族聚酰胺纤维制成的耐热织物，其特征在于耐热织物的耐磨性按照JIS L1096 8.19.1A-1方法（通用型方法（平面法 ），磨损试验机的压力载荷：4.45N（0.454kf），纸：＃600）为200摩尔以上，耐热织物的抗撕裂强度按照JIS L1096 8.17.4D法（摆式法）为 20N以上，并且根据JIS L0844 No.A-1，100次洗涤后的耐磨性和保持撕裂强度的保持率相对于洗涤前为90％以上。 结果，所提供的耐热织物可以被染色成从宽范围的颜色选择中选择的颜色，并且即使在重复使用或洗涤等之后也能够保持高的时间/年龄的机械特性。
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公开(公告)号：US08671524B2
公开(公告)日：2014-03-18
申请号：US13349611
申请日：2012-01-13
IPC分类号： D01B9/00
摘要： The present invention concerns processes for reducing water in never-dried fiber comprising copolymer derived from the copolymerization of para-phenylenediamine, 5(6)-amino-2-(p-aminophenyl)benzimidazole; and terephthaloyl dichloride, the process having the following steps in a continuous process, (a) a step of drying a never-dried fiber having at least 0.1% sulfur at less than 150° C. until the moisture content of the fiber is less than 60 weight percent; and (b) a step of further drying the fiber above 150° C. while the moisture content of the fiber is no more than 60 weight percent; and the fiber being further heated to at least 350° C. in either an additional continuous or separate step.
摘要翻译： 本发明涉及减少未干燥纤维中水分的方法，包括由对苯二胺，5（6） - 氨基-2-（对氨基苯基）苯并咪唑的共聚得到的共聚物; 和对苯二甲酰氯，该方法在连续方法中具有以下步骤，（a）在小于150℃下干燥具有至少0.1％硫的未干燥纤维，直到纤维的水分含量低于 60％ 和（b）当纤维的水分含量不超过60重量％时，纤维进一步干燥150℃以上的步骤; 并且在额外的连续或分开的步骤中将纤维进一步加热至至少350℃。
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公开(公告)号：US20130015603A1
公开(公告)日：2013-01-17
申请号：US13349597
申请日：2012-01-13
IPC分类号： B29C71/02
摘要： The present invention concerns processes for reducing water in never-dried fiber comprising copolymer derived from the copolymerization of para-phenylenediamine, 5(6)-amino-2-(p-aminophenyl)benzimidazole; and terephthaloyl dichloride, the process comprising the steps of: (a) heating the never-dried fiber to a temperature of at least 20° C. but less than 100° C. until the moisture content of the fiber is 20 weight percent or less of the fiber; and (b) further heating the fiber to a temperature of at least 350° C.
摘要翻译： 本发明涉及减少未干燥纤维中水分的方法，包括由对苯二胺，5（6） - 氨基-2-（对氨基苯基）苯并咪唑的共聚得到的共聚物; 和对苯二甲酰氯，该方法包括以下步骤：（a）将未干燥的纤维加热至至少20℃但小于100℃的温度，直到纤维的水分含量为20重量％以下 的纤维; 和（b）将纤维进一步加热到至少350℃的温度
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7.发明申请POLYAMIDE BLOCK COPOLYMER, ARTICLE INCLUDING SAME, AND DISPLAY DEVICE INCLUDING THE ARTICLE 有权聚酰胺嵌段共聚物，包括它的文章和包括文章的显示装置公开(公告)号：US20120296037A1
公开(公告)日：2012-11-22
申请号：US13364062
申请日：2012-02-01
IPC分类号： C08G81/00 , C09J177/00 , C09D177/00
CPC分类号： C08G69/32 , C08G69/265 , C08G69/28 , C08G69/42 , C08G81/00 , C08J5/18 , C08J2377/10 , C08L77/10 , C09D177/10 , C09J177/10 , D01F6/805
摘要： A polyamide block copolymer that includes a first segment including a repeating unit represented by Chemical Formula 1, a repeating unit represented by Chemical Formula 2, or a combination thereof; and a second segment including a repeating unit represented by Chemical Formula 3. The variables R1 to R15, and n1 to n8 are defined herein.
摘要翻译： 一种聚酰胺嵌段共聚物，其包含包含由化学式1表示的重复单元的第一区段，由化学式2表示的重复单元或其组合; 和包含由化学式3表示的重复单元的第二区段。变量R1至R15和n1至n8在本文中定义。
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8.发明申请FLAME RETARDANT COMPOSITION, FLAME-RETARDANT RESIN COMPOSITION AND MOLDED PRODUCT AND FIBER MADE OF FLAME-RETARDANT RESIN COMPOSITION 失效阻燃剂组合物，阻燃树脂组合物和模塑产品以及阻燃树脂组合物的纤维制品公开(公告)号：US20100331467A1
公开(公告)日：2010-12-30
申请号：US12873707
申请日：2010-09-01
申请人： Shoichi Wakatake , Kazuhiko Kosuge
发明人： Shoichi Wakatake , Kazuhiko Kosuge
IPC分类号： C08K3/12
摘要： To provide a halogen-free flame retardant composition containing no antimony, phosphorus and phosphorus compounds at all, a non-halogen flame-retardant resin composition of environmental type ideal for disaster prevention made of the flame retardant composition, which causes little carbon monoxide (CO) during combustion while having high flame retardance, and molded products, electric wires, cables, fiber or fiber post-processed products made of the resin composition. The flame retardant composition comprises a mixture of (A) a resin having an average particle diameter of not more than 1000 μm selected from wholly aromatic polyamide, polyimide, polyamideimide, a copolymer of the wholly aromatic polyamide, the polyimide or the polyamideimide or a mixture of the above mentioned polymers and (B) a metal hydrate. The flame-retardant resin composition contains 50 to 200 parts by mass of the flame retardant composition to 100 parts by mass of a thermoplastic resin or a thermosetting resin.
摘要翻译： 为了提供一种不含锑，磷和磷化合物的无卤阻燃剂组合物，由阻燃剂组合物制成的非常适用于防灾的环境型非卤素阻燃树脂组合物，其几乎不产生一氧化碳（CO ），同时具有高阻燃性，以及由树脂组合物制成的成型产品，电线，电缆，纤维或纤维后处理产品。 阻燃剂组合物包含（A）选自全芳香族聚酰胺，聚酰亚胺，聚酰胺酰亚胺，全芳香族聚酰胺，聚酰亚胺或聚酰胺酰亚胺的共聚物或混合物的平均粒径为1000μm以下的树脂的混合物 的上述聚合物和（B）金属水合物。 该阻燃性树脂组合物含有50〜200质量份阻燃组合物与100质量份热塑性树脂或热固性树脂。
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公开(公告)号：US20090127735A1
公开(公告)日：2009-05-21
申请号：US12092390
申请日：2006-11-01
CPC分类号： C08G69/32 , C08G69/26 , C08G73/22 , C08J3/05 , C08J2377/06 , C08L77/10 , C08L79/08 , C08L2205/02 , D01F6/60 , D01F6/605 , D01F6/74 , D01F6/805 , C08L2666/20
摘要： The object of this invention is to provide a dope that has excellent formability and can be formed into a fiber, a film, pulp-shaped particles and the like by a wet method. The object of this invention is also to provide a process for the production of a fiber excellent in heat resistance, strength and elastic modulus.This invention provides a dope and a process for the production of a fiber from the dope, the dope comprising a polyamide and a basic solvent, the polyamide containing a recurring unit of the following formula (I), wherein Ar1 represents at least one substituent selected from the group consisting of and having an inherent viscosity of 1.0 or more, the dope has a polyamide concentration of over 10% by weight but not more than 25% by weight and exhibits optical anisotropy at 50° C.
摘要翻译： 本发明的目的是提供一种具有优异成型性的涂料，并可通过湿法形成纤维，薄膜，纸浆状颗粒等。 本发明的目的还在于提供一种制造耐热性，强度和弹性模量优异的纤维的方法。 本发明提供了一种用于从纺丝原液生产纤维的涂料和方法，所述涂料包含聚酰胺和碱性溶剂，所述聚酰胺含有下式（I）的重复单元，其中Ar 1表示至少一个选自 由特性粘度为1.0以上的聚合物组成的聚酰胺浓度为10重量％以上且25重量％以下，在50℃下显示光学各向异性
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10.发明申请公开(公告)号：US20080085978A1
公开(公告)日：2008-04-10
申请号：US11663980
申请日：2005-10-20
申请人： Bernardus Koenders
发明人： Bernardus Koenders
CPC分类号： C08J3/05 , B29C47/6068 , B29C47/6075 , C08J2377/10 , D01D1/02 , D01F6/805 , Y10T428/1369 , Y10T428/2913 , Y10T428/2969
摘要： Described is a method for dissolving PPTA or copolymers thereof in sulfuric acid using a twin screw extruder having transporting, mixing, and kneading elements with an entering zone, an intermediate zone, a mixing zone, a negative transport zone, a degassing zone, and a pressure build-up zone. The method includes transporting PPTA or copolymer thereof into the entering zone at a transport capacity low enough as to prevent sulfuric acid entering the entering zone; introducing sulfuric acid in the entering or intermediate zone; essentially fully filling the mixing zone to allow sufficient time to mix and dissolve PPTA or copolymer thereof in the sulfuric acid to obtain a PPTA or copolymer-sulfuric acid solution; creating after the mixing zone a negative transport zone to obtain a product lock between the mixing zone and the degassing zone; creating a thin film of the PPTA or copolymer-sulfuric acid solution in the degassing zone to degas the solution; and entering the solution into the output pressure build-up zone to partially fill this zone and to leave the twin screw extruder.
摘要翻译： 描述了使用具有输送区域，中间区域，混合区域，负运送区域，脱气区域和输送区域的输送，混合和捏合元件的双螺杆挤出机将PPTA或其共聚物溶解在硫酸中的方法。 压力积聚区。 该方法包括以足够低的运输能力将PPTA或其共聚物输送到进入区域中，以防止硫酸进入进入区域; 在进入或中间区域引入硫酸; 基本上完全填充混合区以允许足够的时间将PPTA或其共聚物混合并溶解在硫酸中以获得PPTA或共聚物 - 硫酸溶液; 在混合区之后产生负运送区，以在混合区和脱气区之间获得产品锁; 在脱气区中形成PPTA或共聚物 - 硫酸溶液的薄膜，使溶液脱气; 并将溶液进入输出压力累积区以部分填充该区域并离开双螺杆挤出机。
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