公开(公告)号：US08367166B2

公开(公告)日：2013-02-05

申请号：US12608682

申请日：2009-10-29

申请人： Jeremy E. Dahl ,  J. Michael Moldowan ,  Michael A. Kelly ,  Robert M. Carlson

发明人： Jeremy E. Dahl ,  J. Michael Moldowan ,  Michael A. Kelly ,  Robert M. Carlson

IPC分类号： C07C13/28 ,  C23C16/00

CPC分类号： C07C13/64 ,  C07C2603/90 ,  C23C16/0272 ,  C23C16/27 ,  C23C16/271

摘要： In some embodiments, the present invention is directed to methods for synthesizing higher diamondoids, wherein said methods involve augmenting existing diamondoid molecules through the bonding of carbon atoms to such existing diamondoid species with intramolecular cross-linking so as to form larger diamondoids containing face-fused diamond-crystal (adamantane) cages with carbon frameworks superimposable on the cubic-diamond crystal lattice.

摘要翻译： 在一些实施方案中，本发明涉及用于合成较高类金刚石的方法，其中所述方法包括通过碳原子与现有的金刚石类物质与分子内交联键合来增加现有的类金刚石分子，从而形成更大的含有面熔融 具有碳框架的金刚石晶体（金刚烷）笼可重叠在立方晶系晶格上。

公开(公告)号：US07884256B2

公开(公告)日：2011-02-08

申请号：US11013638

申请日：2004-12-17

申请人： Shenggao Liu ,  Robert M. Carlson ,  Jeremy E. Dahl

发明人： Shenggao Liu ,  Robert M. Carlson ,  Jeremy E. Dahl

IPC分类号： C07C13/00

CPC分类号： B82Y30/00 ,  B82Y10/00 ,  C07C4/00 ,  C07C7/04 ,  C07C7/12 ,  C07C7/135 ,  C07C13/64 ,  C07C17/10 ,  C07C17/16 ,  C07C17/383 ,  C07C17/395 ,  C07C23/20 ,  C07C29/124 ,  C07C29/143 ,  C07C29/149 ,  C07C29/48 ,  C07C31/137 ,  C07C31/278 ,  C07C37/20 ,  C07C39/17 ,  C07C41/16 ,  C07C43/188 ,  C07C45/28 ,  C07C47/347 ,  C07C49/423 ,  C07C51/353 ,  C07C67/08 ,  C07C67/14 ,  C07C69/08 ,  C07C69/38 ,  C07C69/54 ,  C07C69/604 ,  C07C205/05 ,  C07C211/38 ,  C07C211/50 ,  C07C217/90 ,  C07C233/58 ,  C07C2603/54 ,  C07C2603/90 ,  C08G61/00 ,  C08G61/02 ,  C08G83/00 ,  C08L65/00 ,  C07C69/608 ,  C07C61/125

摘要： Higher diamondoid derivatives capable of taking part in polymerization reactions are disclosed as well as intermediates to these derivatives, polymers formed from these derivatives and methods for preparing the polymers.

摘要翻译： 公开了能够参与聚合反应的高级金刚石衍生物以及这些衍生物的中间体，由这些衍生物形成的聚合物和制备聚合物的方法。

公开(公告)号：US07795468B2

公开(公告)日：2010-09-14

申请号：US10313804

申请日：2002-12-06

申请人： Shenggao Liu ,  Robert M. Carlson ,  Jeremy E. Dahl ,  Waqar R. Qureshi

发明人： Shenggao Liu ,  Robert M. Carlson ,  Jeremy E. Dahl ,  Waqar R. Qureshi

IPC分类号： C07C61/12 ,  C07C61/28 ,  C07D221/22 ,  C07C275/26 ,  C07C235/26 ,  C07C211/16

CPC分类号： B82Y30/00 ,  B82Y10/00 ,  C07C4/00 ,  C07C7/04 ,  C07C7/12 ,  C07C7/135 ,  C07C13/64 ,  C07C17/10 ,  C07C17/16 ,  C07C17/383 ,  C07C17/395 ,  C07C23/20 ,  C07C39/17 ,  C07C43/188 ,  C07C47/347 ,  C07C49/423 ,  C07C69/753 ,  C07C205/05 ,  C07C211/38 ,  C07C211/50 ,  C07C217/90 ,  C07C233/58 ,  C07C2603/54 ,  C07C2603/90 ,  C08G61/00 ,  C08G61/02 ,  C08G83/00 ,  C08L65/00

摘要： This invention is directed to functionalized higher diamondoids having at least one functional group. Preferably these derivatives have the following Formula I: wherein D is a higher diamondoid nucleus and wherein R1, R2, R3, R4, R5 and R6 are independently selected from a group consisting of hydrogen and functional groups, provided that there is at least one functional group on the derivative. The functionalized higher diamondoid compounds may also be of the formula D—L—(D)n wherein D is a higher diamondoid nucleus and L is a linking group and n is 1 or more. The functionalized higher diamondoid compounds additionally may be of the formula R38—D—D—R39 wherein D is a higher diamondoid nucleus and R38 and R39 are substituents.

摘要翻译： 本发明涉及具有至少一个官能团的官能化的更高级的金刚石。 优选地，这些衍生物具有以下式I：其中D是较高的金刚石核，并且其中R 1，R 2，R 3，R 4，R 5和R 6独立地选自氢和官能团，条件是存在至少一个官能 组合导数。 官能化的高级金刚石化合物也可以是式D-L-（D）n，其中D是较高的金刚石核，L是连接基团，n是1或更多。 官能化的高级金刚石化合物另外可以是式R38-D-D-R39，其中D是较高的金刚石核，R38和R39是取代基。

公开(公告)号：US20100112214A1

公开(公告)日：2010-05-06

申请号：US12608682

申请日：2009-10-29

申请人： Jeremy E. Dahl ,  J. Michael Moldowan ,  Michael A. Kelly ,  Robert M. Carlson

发明人： Jeremy E. Dahl ,  J. Michael Moldowan ,  Michael A. Kelly ,  Robert M. Carlson

IPC分类号： C07C13/28 ,  C23C16/00

CPC分类号： C07C13/64 ,  C07C2603/90 ,  C23C16/0272 ,  C23C16/27 ,  C23C16/271

摘要： In some embodiments, the present invention is directed to methods for synthesizing higher diamondoids, wherein said methods involve augmenting existing diamondoid molecules through the bonding of carbon atoms to such existing diamondoid species with intramolecular cross-linking so as to form larger diamondoids containing face-fused diamond-crystal (adamantane) cages with carbon frameworks superimposable on the cubic-diamond crystal lattice.

摘要翻译： 在一些实施方案中，本发明涉及用于合成较高类金刚石的方法，其中所述方法包括通过碳原子与现有的金刚石类物质与分子内交联键合来增加现有的类金刚石分子，从而形成更大的含有面熔融 具有碳框架的金刚石晶体（金刚烷）笼可重叠在立方晶系晶格上。

公开(公告)号：US07649056B2

公开(公告)日：2010-01-19

申请号：US11335916

申请日：2006-01-18

申请人： Shenggao Liu ,  Robert M. Carlson ,  Jeremy E. Dahl

发明人： Shenggao Liu ,  Robert M. Carlson ,  Jeremy E. Dahl

IPC分类号： C08F20/00

CPC分类号： C07C49/617 ,  C07C23/20 ,  C07C49/423 ,  C07C49/613 ,  C07C61/29 ,  C07D221/22 ,  C07D311/96 ,  C07D313/06 ,  C07D335/04 ,  C07D471/10 ,  C07F9/65683

摘要： This invention is related to heteroatom containing diamondoids (i.e., “heterodiamondoids”) which are compounds having a diamondoid nucleus in which one or more of the diamondoid nucleus carbons has been substitutionally replaced with a noncarbon atom. These heteroatom substituents impart desirable properties to the diamondoid. In addition, the heterodiamondoids are functionalized affording compounds carrying one or more functional groups covalently pendant therefrom. This invention is further related to polymerizable functionalized heterodiamondoids. In a preferred aspect of this invention the diamondoid nuclei are triamantane and higher diamondoid nuclei. In another preferred aspect, the heteroatoms are selected to give rise to diamondoid materials which can serve as n- and p-type materials in electronic devices can serve as optically active materials.

摘要翻译： 本发明涉及含有杂原子的类金刚石（即“异二亚类”），它们是具有金刚石核的化合物，其中一个或多个金刚石核碳被替代为非碳原子。 这些杂原子取代基赋予金刚石所需的性质。 此外，异二亚甲基二羧酸被官能化，从而提供携带一个或多个共价悬挂的官能团的化合物。 本发明进一步涉及可聚合的官能化异二聚体。 在本发明的优选方面，金刚石核是三金刚烷和更高的金刚石核。 在另一个优选的方面，选择这些杂原子以产生可用作电子器件中的n-型和p-型材料的类金刚石材料，可用作光学活性材料。

公开(公告)号：US20090176035A1

公开(公告)日：2009-07-09

申请号：US12113256

申请日：2008-05-01

申请人： Andrew W. Tudhope ,  William J. Boardman ,  Steven F. Sciamanna ,  Thomas B. Casserly ,  Robert M. Carlson

发明人： Andrew W. Tudhope ,  William J. Boardman ,  Steven F. Sciamanna ,  Thomas B. Casserly ,  Robert M. Carlson

IPC分类号： B05D3/04

CPC分类号： C23C16/045 ,  C23C16/26 ,  C23C16/50 ,  C23C16/503 ,  C23C16/509 ,  C23C16/52

摘要： The invention relates to a method for forming high sp3 content amorphous carbon coatings deposited by plasma enhanced chemical vapor deposition on internal surfaces and employing the “hollow-cathode” technique. This method allows adjustment of tribological properties, such as hardness, Young's modulus, wear resistance and coefficient of friction as well as optical properties, such as refractive index. In addition the resulting coatings are uniform and have high corrosion resistance. By controlling pressure, type of diamondoid precursor and bias voltage, the new method prevents the diamondoid precursor from fully breaking upon impact with the substrate. The diamondoid retains sp3 bonds which yields a high sp3 content film at higher pressure. This enables a faster deposition rate than would be possible without the use of a diamondoid precursor.

摘要翻译： 本发明涉及一种用于形成通过等离子体增强化学气相沉积在内表面上并采用“中空阴极”技术沉积的高含量无定形碳涂层的方法。 该方法允许调节摩擦学性能，例如硬度，杨氏模量，耐磨性和摩擦系数以及光学性质如折射率。 此外，所得涂层是均匀的并且具有高耐腐蚀性。 通过控制压力，类金刚石前体和偏置电压，新方法可防止金刚石类前体在与基材碰撞时完全破裂。 金刚石保留sp3键，其在较高压力下产生高的sp3含量的膜。 这使得能够在不使用金刚石前体的情况下实现比可能更快的沉积速率。

公开(公告)号：US20090075203A1

公开(公告)日：2009-03-19

申请号：US12200703

申请日：2008-08-28

申请人： Shenggao Liu ,  Jeremy E. Dahl ,  Robert M. Carlson

发明人： Shenggao Liu ,  Jeremy E. Dahl ,  Robert M. Carlson

IPC分类号： G03F7/004 ,  C08G61/00

CPC分类号： C07C69/54 ,  C07C35/44 ,  C07C2603/86 ,  C07C2603/90 ,  G03F7/0397 ,  Y10S430/111

摘要： Novel positive-working photoresist compositions are disclosed. The monomers of the base resin of the resist contain diamondoid-containing pendant groups higher than adamantane in the polymantane series; for example, diamantane, triamantane, tetramantane, pentamantane, hexamantane, etc. The diamondoid-containing pendant group may have hydrophilic-enhancing substituents such as a hydroxyl group, and may contain a lactone group. Advantages of the present compositions include enhanced resolution, sensitivity, and adhesion to the substrate.

摘要翻译： 公开了新型正性光致抗蚀剂组合物。 抗蚀剂的基体树脂的单体在聚曼烷系列中含有高于金刚烷的含金刚石的侧基; 例如，金刚烷，四金刚烷，五金刚烷，六
金刚等。含金刚石的侧基可以具有亲水性增强取代基，例如羟基，可含有内酯基。 本发明组合物的优点包括提高分辨率，灵敏度和对基材的粘合性。

公开(公告)号：US20080300317A1

公开(公告)日：2008-12-04

申请号：US12125416

申请日：2008-05-22

申请人： Chu-Yi Yu ,  Deyuan Kong ,  Frederick W. Lam ,  Steven F. Sciamanna ,  Earl Shelton ,  Shenggao Liu ,  Robert M. Carlson

发明人： Chu-Yi Yu ,  Deyuan Kong ,  Frederick W. Lam ,  Steven F. Sciamanna ,  Earl Shelton ,  Shenggao Liu ,  Robert M. Carlson

IPC分类号： A61K31/047 ,  A61K31/045 ,  A61K31/137 ,  A61P31/16

CPC分类号： A61K31/045 ,  A61K31/13 ,  A61K31/16 ,  A61K31/19 ,  C07C211/19 ,  C07C2603/90 ,  Y02A50/385 ,  Y02A50/393 ,  Y02A50/463

摘要： This invention relates to diamondoid derivatives which exhibit therapeutic activity. Specifically, the diamondoid derivatives herein exhibit therapeutic effects in the treatment of viral disorders. Also provided are methods of treatment, prevention and inhibition of viral disorders in a subject in need.

摘要翻译： 本发明涉及显示出治疗活性的类金刚石衍生物。 具体地，本文中的类金刚石衍生物在治疗病毒性疾病中表现出治疗效果。 还提供了在需要的受试者中治疗，预防和抑制病毒性疾病的方法。

公开(公告)号：US07306671B2

公开(公告)日：2007-12-11

申请号：US10784915

申请日：2004-02-24

申请人： Jeremy E. Dahl ,  Robert M. Carlson ,  Shenggao Liu

发明人： Jeremy E. Dahl ,  Robert M. Carlson ,  Shenggao Liu

IPC分类号： C30B29/02

CPC分类号： H01J1/3048 ,  B82Y10/00 ,  B82Y30/00 ,  C07C4/00 ,  C07C7/04 ,  C07C7/12 ,  C07C7/135 ,  C07C13/64 ,  C07C17/10 ,  C07C17/16 ,  C07C17/383 ,  C07C17/395 ,  C07C23/20 ,  C07C39/17 ,  C07C47/347 ,  C07C49/423 ,  C07C205/05 ,  C07C211/50 ,  C07C2603/54 ,  C07C2603/90 ,  C08G61/00 ,  C08G61/02 ,  C08G83/00 ,  C08L65/00 ,  H01J2201/30457 ,  H01L23/3732 ,  H01L24/45 ,  H01L24/48 ,  H01L2224/451 ,  H01L2224/45124 ,  H01L2224/45144 ,  H01L2224/48247 ,  H01L2924/00014 ,  H01L2924/01012 ,  H01L2924/01019 ,  H01L2924/0102 ,  H01L2924/01078 ,  H01L2924/01079 ,  H01L2924/12042 ,  H01L2924/14 ,  H01L2924/181 ,  H01L2924/19041 ,  H01L2924/00 ,  H01L2224/05599 ,  H01L2924/00012

摘要： Novel uses of diamondoid-containing materials in the field of microelectronics are disclosed. Embodiments include, but are not limited to, thermally conductive films in integrated circuit packaging, low-k dielectric layers in integrated circuit multilevel interconnects, thermally conductive adhesive films, thermally conductive films in thermoelectric cooling devices, passivation films for integrated circuit devices (ICs), and field emission cathodes. The diamondoids employed in the present invention may be selected from lower diamondoids, as well as the newly provided higher diamondoids, including substituted and unsubstituted diamondoids. The higher diamondoids include tetramantane, peritamantane, hexamantane, heptamantane, octamantane, nonamantane, decamantane, and undecamantane. The diamondoid-containing material may be fabricated as a diamondoid-containing polymer, a diamondoid-containing sintered ceramic, a diamondoid ceramic composite, a CVD diamondoid film, a self-assembled diamondoid film, and a diamondoid-fullerene composite.

摘要翻译： 公开了在微电子学领域中含有金刚石的材料的新用途。 实施例包括但不限于集成电路封装中的导热膜，集成电路多层互连中的低k电介质层，导热粘合剂膜，热电冷却器件中的导热膜，用于集成电路器件（IC）的钝化膜 和场致发射阴极。 本发明中使用的类金刚石可以选自下面的金刚石，以及新提供的更高的金刚石，包括取代和未取代的金刚石。 较高的金刚石包括四聚烷，四金刚烷，六金刚烷，七金刚烷，八甲烷，非金刚烷，十烷和十一烷。 含金刚石的材料可以制造为含有金刚石的聚合物，含金刚石的烧结陶瓷，金刚石陶瓷复合材料，CVD金刚石膜，自组装的金刚石膜和类金刚石 - 富勒烯复合材料。

公开(公告)号：US07273598B2

公开(公告)日：2007-09-25

申请号：US10892080

申请日：2004-07-14

申请人： Jeremy E. Dahl ,  Robert M. Carlson ,  Shenggao Liu

发明人： Jeremy E. Dahl ,  Robert M. Carlson ,  Shenggao Liu

IPC分类号： C30B29/04

CPC分类号： C07C4/00 ,  B82Y10/00 ,  B82Y30/00 ,  C07C7/04 ,  C07C7/12 ,  C07C7/135 ,  C07C13/64 ,  C07C17/10 ,  C07C17/16 ,  C07C17/383 ,  C07C17/395 ,  C07C23/20 ,  C07C39/17 ,  C07C47/347 ,  C07C49/423 ,  C07C205/05 ,  C07C211/50 ,  C07C2603/54 ,  C07C2603/90 ,  C08G61/00 ,  C08G61/02 ,  C08G83/00 ,  C08L65/00 ,  H01J1/3048 ,  H01J2201/30457 ,  H01L23/3732 ,  H01L23/4334 ,  H01L23/49513 ,  H01L24/45 ,  H01L24/48 ,  H01L24/73 ,  H01L24/83 ,  H01L35/22 ,  H01L2224/32245 ,  H01L2224/451 ,  H01L2224/45124 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2224/83 ,  H01L2924/00014 ,  H01L2924/01012 ,  H01L2924/01019 ,  H01L2924/0102 ,  H01L2924/01029 ,  H01L2924/01078 ,  H01L2924/01079 ,  H01L2924/12042 ,  H01L2924/14 ,  H01L2924/15787 ,  H01L2924/181 ,  H01L2924/19041 ,  H01L2924/3512 ,  H01L2924/00 ,  H01L2924/00012 ,  H01L2224/05599

摘要： Novel uses of diamondoid-containing materials in the field of microelectronics are disclosed. Embodiments include, but are not limited to, passivation films for integrated circuit devices (ICs). The diamondoids employed in the present invention may be selected from lower diamondoids, as well as the newly provided higher diamondoids, including substituted and unsubstituted diamondoids. The higher diamondoids include tetramantane, pentamantane, hexamantane, heptamantane, octamantane, nonamantane, decamantane, and undecamantane. The diamondoid-containing material may be fabricated as a diamondoid-containing polymer, a diamondoid-containing sintered ceramic, a diamondoid ceramic composite, a CVD diamondoid film, a self-assembled diamondoid film, and a diamondoid-fullerene composite.

摘要翻译： 公开了在微电子学领域中含有金刚石的材料的新用途。 实施例包括但不限于用于集成电路器件（IC）的钝化膜。 本发明中使用的类金刚石可以选自下面的金刚石，以及新提供的更高的金刚石，包括取代和未取代的金刚石。 较高的类金刚石包括四聚烷，五金刚，六金刚，七金刚烷，八甲烷，非金刚烷，十烷金和十一烷。 含金刚石的材料可以制造为含有金刚石的聚合物，含金刚石的烧结陶瓷，金刚石陶瓷复合材料，CVD金刚石膜，自组装的金刚石膜和类金刚石 - 富勒烯复合材料。