公开(公告)号：US20140228205A1

公开(公告)日：2014-08-14

申请号：US13948544

申请日：2013-07-23

Applicant: Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

IPC: B01J29/85 ,  B01J29/80 ,  B01J29/82 ,  B01J29/40

CPC classification number: C10G1/10 ,  B01J29/40 ,  B01J29/80 ,  B01J29/82 ,  B01J29/85 ,  B01J35/1019 ,  B01J2029/062 ,  C10G11/18

Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.

Abstract translation: 用于从原料生产烯烃和芳族化合物的催化剂组合物由流化催化裂化（FCC）催化剂和ZSM-5沸石催化剂形成，其中ZSM-5沸石催化剂的量由10wt。 ％以上的FCC催化剂和ZSM-5沸石催化剂的总重量。 催化剂组合物可以用于通过在反应器内引入烃原料和催化剂组合物从原料生产烯烃和芳族化合物的方法，反应器的至少一部分在550℃或更高的反应器温度下 。 将原料和催化剂组合物以6或更大的催化剂 - 进料（C / F）比引入反应器中。

公开(公告)号：US20140228204A1

公开(公告)日：2014-08-14

申请号：US13764886

申请日：2013-02-12

Applicant: Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

IPC: C10G1/10

CPC classification number: C10G1/10 ,  B01J29/40 ,  B01J29/80 ,  B01J29/82 ,  B01J29/85 ,  B01J35/1019 ,  B01J2029/062 ,  C10G11/18

Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.

Abstract translation: 用于从原料生产烯烃和芳族化合物的催化剂组合物由流化催化裂化（FCC）催化剂和ZSM-5沸石催化剂形成，其中ZSM-5沸石催化剂的量由10wt。 ％以上的FCC催化剂和ZSM-5沸石催化剂的总重量。 催化剂组合物可以用于通过在反应器内引入烃原料和催化剂组合物从原料生产烯烃和芳族化合物的方法，反应器的至少一部分在550℃或更高的反应器温度下 。 将原料和催化剂组合物以6或更大的催化剂 - 进料（C / F）比引入反应器中。

公开(公告)号：US20170058214A1

公开(公告)日：2017-03-02

申请号：US15120195

申请日：2014-12-10

Applicant: Arno Johannes Maria OPRINS ,  Ravichander NARAYANASWAMY ,  Vijayanand RAJAGOPALAN ,  Andrew Mark WARD ,  Joris van Willigenburg ,  Raul PELAEZ ,  Egidius Jacoba Maria SCHAERLAECKENS ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Arno Johannes Maria Oprins ,  Ravichander Narayanaswamy ,  Vijayanand Rajagopalan ,  Andrew Mark Ward ,  Joris van Willigenburg ,  Raul Velasco Pelaez ,  Egidius Jacoba Maria Schaerlaeckens

IPC: C10G69/06

CPC classification number: C10G69/06 ,  C10G9/36 ,  C10G45/50 ,  C10G47/18 ,  C10G69/04 ,  C10G2400/20 ,  C10G2400/30

Abstract: The present invention relates to an integrated process to convert crude oil into petrochemical products comprising crude oil distillation, hydrocracking, aromatization and olefins synthesis. Furthermore, the present invention relates to a process installation to convert crude oil into petrochemical products comprising a crude distillation unit, a hydrocracker, an aromatization unit and a unit for olefins synthesis.

Abstract translation: 本发明涉及将原油转化为石油化学产品的综合方法，其包括原油蒸馏，加氢裂化，芳构化和烯烃合成。 此外，本发明涉及将原油转化成石油化学产品的方法，该方法包括粗蒸馏单元，加氢裂化器，芳构化单元和用于烯烃合成的单元。

公开(公告)号：US20160369187A1

公开(公告)日：2016-12-22

申请号：US14901865

申请日：2014-06-30

Applicant: Andrew Mark Ward ,  Ravichander Narayanaswamy ,  Arno Johannes Maria Oprins ,  Vijayanand Rajagopalan ,  Egidius Jacoba Maria Schaerlaeckens ,  Raul Velasco Pelaez ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Andrew Mark Ward ,  Ravichander Narayanaswamy ,  Arno Johannes Maria Oprins ,  Vijayanand Rajagopalan ,  Egidius Jacoba Maria Schaerlaeckens ,  Raul Velasco Pelaez

IPC: C10G69/02

Abstract: The present invention relates to an integrated process to convert crude oil into petrochemical products comprising crude oil distillation, hydrocracking and olefins synthesis, which process comprises subjecting a hydrocracker feed to hydrocracking to produce LPG and BTX and subjecting the LPG produced in the process to olefins synthesis. Furthermore, the present invention relates to a process installation to convert crude oil into petrochemical products comprising: a crude distillation unit comprising an inlet for crude oil and at least one outlet for one or more of naphtha, kerosene and gasoil; a hydrocracker comprising an inlet for a hydrocracker feed, an outlet for LPG and an outlet for BTX; and a unit for olefins synthesis comprising an inlet for LPG produced by the integrated petrochemical process installation and an outlet for olefins. The hydrocracker feed used in the process and the process installation of the present invention comprises one or more of naphtha, kerosene and gasoil produced by crude oil distillation in the process; and refinery unit-derived light-distillate and/or refinery unit-derived middle-distillate produced in the process. The process and process installation of the present invention have an increased production of petrochemicals at the expense of the production of fuels and an improved carbon efficiency in terms of the conversion of crude oils into petrochemicals.

Abstract translation: 本发明涉及将原油转化成包括原油蒸馏，加氢裂化和烯烃合成的石化产品的综合方法，该方法包括使加氢裂化器进料加氢裂化以产生LPG和BTX，并使该方法中产生的LPG进行烯烃合成 。 此外，本发明涉及将原油转化成石油化学产品的工艺装置，其包括：原油蒸馏单元，其包含用于原油的入口和用于石脑油，煤油和油油中的一种或多种的至少一个出口; 加氢裂化器，包括用于加氢裂化器进料的入口，用于LPG的出口和用于BTX的出口; 和用于烯烃合成的单元，其包括由综合石化工艺装置生产的LPG的入口和用于烯烃的出口。 本发明方法和工艺装置中使用的加氢裂化器进料包括在该方法中通过原油蒸馏生产的一种或多种石脑油，煤油和瓦斯油; 以及在该过程中生产的炼油厂单元衍生的轻馏分和/或炼油单元衍生的中间馏分。 本发明的方法和方法安装以石油生产为代价增加石油化学品的生产，并且在原油转化为石油化学品方面提高了碳效率。

公开(公告)号：US09212318B2

公开(公告)日：2015-12-15

申请号：US13948544

申请日：2013-07-23

Applicant: Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

IPC: B01J29/06 ,  B01J29/40 ,  B01J29/08 ,  C10G1/10 ,  B01J29/80 ,  B01J29/82 ,  B01J29/85 ,  B01J35/10 ,  C10G11/18 ,  C10G11/05 ,  C07C1/00 ,  C10G1/00 ,  C10B53/07

CPC classification number: C10G1/10 ,  B01J29/40 ,  B01J29/80 ,  B01J29/82 ,  B01J29/85 ,  B01J35/1019 ,  B01J2029/062 ,  C10G11/18

Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.

Abstract translation: 用于从原料生产烯烃和芳族化合物的催化剂组合物由流化催化裂化（FCC）催化剂和ZSM-5沸石催化剂形成，其中ZSM-5沸石催化剂的量由10wt。 ％以上的FCC催化剂和ZSM-5沸石催化剂的总重量。 催化剂组合物可以用于通过在反应器内引入烃原料和催化剂组合物从原料生产烯烃和芳族化合物的方法，反应器的至少一部分在550℃或更高的反应器温度下 。 将原料和催化剂组合物以6或更大的催化剂 - 进料（C / F）比引入反应器中。

公开(公告)号：US10233395B2

公开(公告)日：2019-03-19

申请号：US15121104

申请日：2014-12-23

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V. ,  Andrew Mark Ward ,  Arno Johannes Maria Oprins ,  Ravichander Narayanaswamy

Inventor： Andrew Mark Ward ,  Arno Johannes Maria Oprins ,  Ravichander Narayanaswamy

IPC: C10G1/10 ,  C10G47/00 ,  C10G47/36 ,  C10G45/00 ,  C10G45/02 ,  C10G65/12 ,  C10G69/06 ,  C10G9/36 ,  C10G69/02 ,  C10G70/00

Abstract: A process for converting mixed waste plastic (MWP) into valuable petrochemicals including feeding MWP to a pyrolysis reactor, converting the MWP into a gaseous stream and a liquid stream, and further processing the gaseous stream into valuable petrochemicals.

公开(公告)号：US20170009151A1

公开(公告)日：2017-01-12

申请号：US15120681

申请日：2014-12-23

Applicant: Christoph DITTRICH ,  Joris VAN WILLIGENBURG ,  Egidius Jacoba Maria SCHAERLAECKENS ,  Andrew Mark WARD ,  Arno Johannes Maria OPRINS ,  Vijayanand RAJAGOPALAN ,  Ravichander NARAYANASWAMY ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V. ,  Raúl VELASCO PELAEZ

Inventor： Christoph DITTRICH ,  Joris VAN WILLIGENBURG ,  Raul VELASCO PELAEZ ,  Egidius Jacoba Maria SCHAERLAECKENS ,  Andrew Mark WARD ,  Arno Johannes Maria OPRINS ,  Vijayanand RAJAGOPALAN ,  Ravichander NARAYANASWAMY

IPC: C10G67/00

CPC classification number: C10G67/00 ,  C10G69/00 ,  C10G69/04 ,  C10G69/06 ,  C10G2400/20 ,  C10G2400/30

Abstract: The present invention relates to a process for converting a hydrocarbon feedstock into olefins and preferably also into BTX, said converting process comprising the following steps of: feeding a hydrocarbon feed-stock to a first hydrocracking unit, feeding the effluent from said first hydrocracking unit to a first separation section, separating said effluent in said first separation section feeding at least one stream to a dehydrogenation unit, and feeding the effluent from said at least one dehydrogenation unit to a second separation section.

Abstract translation: 本发明涉及将烃原料转化为烯烃并优选转化成BTX的方法，所述转化方法包括以下步骤：将烃原料进料至第一加氢裂化装置，将来自所述第一加氢裂化装置的流出物送入 第一分离部分，将所述第一分离部分中的所述流出物分离，将至少一个流进料到脱氢单元，以及将来自所述至少一个脱氢单元的流出物供给到第二分离部分。

公开(公告)号：US08895790B2

公开(公告)日：2014-11-25

申请号：US13764886

申请日：2013-02-12

Applicant: Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

IPC: C10G1/10 ,  C10G1/08 ,  B01J29/40 ,  B01J29/80 ,  B01J29/82 ,  B01J29/85 ,  B01J35/10 ,  C10G11/18 ,  C10G11/00 ,  C10G11/02 ,  C07C4/02 ,  C07C4/06 ,  B01J29/06

CPC classification number: C10G1/10 ,  B01J29/40 ,  B01J29/80 ,  B01J29/82 ,  B01J29/85 ,  B01J35/1019 ,  B01J2029/062 ,  C10G11/18

Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.

Abstract translation: 用于从原料生产烯烃和芳族化合物的催化剂组合物由流化催化裂化（FCC）催化剂和ZSM-5沸石催化剂形成，其中ZSM-5沸石催化剂的量由10wt。 ％以上的FCC催化剂和ZSM-5沸石催化剂的总重量。 催化剂组合物可以用于通过在反应器内引入烃原料和催化剂组合物从原料生产烯烃和芳族化合物的方法，反应器的至少一部分在550℃或更高的反应器温度下 。 将原料和催化剂组合物以6或更大的催化剂 - 进料（C / F）比引入反应器中。

公开(公告)号：US20140228605A1

公开(公告)日：2014-08-14

申请号：US13764923

申请日：2013-02-12

Applicant: Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

Inventor： Ravichander Narayanaswamy ,  Krishna Kumar Ramamurthy ,  P. S. Sreenivasan

IPC: C10G1/10

CPC classification number: C10G1/10 ,  B01J8/0055 ,  B01J8/1836 ,  B01J8/1863 ,  B01J8/26 ,  B01J2208/00044 ,  B01J2208/00061 ,  B01J2219/00198 ,  B01J2219/00218 ,  B01J2219/00231 ,  C10G1/08 ,  C10G1/086 ,  C10G11/187 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30

Abstract: A method of producing olefins and aromatic compounds from a feedstock includes introducing a hydrocarbon feedstock and a catalyst composition that is suitable for converting the feedstock to at least one of olefins and aromatic compounds within a reactor. The reactor has a reactor flow path having a length L between the inlet and outlet. The temperature in the reactor is monitored in at least one location that is at or adjacent to the inlet at a temperature-monitoring distance that is from 0.3 L or less from the inlet. In response to the monitored temperatures one or more parameters are modified. At least a portion of the feedstock is allowed to be converted to at least one of olefins and aromatic compounds within the reactor, which are removed as a product stream.

Abstract translation: 从原料生产烯烃和芳族化合物的方法包括引入烃原料和催化剂组合物，该组合物适于将原料转化为反应器内至少一种烯烃和芳族化合物。 反应器具有在入口和出口之间具有长度L的反应器流动路径。 在距离入口0.3L或更小的温度监测距离处的入口处或邻近处的至少一个位置监测反应器中的温度。 响应于所监测的温度，一个或多个参数被修改。 允许至少一部分原料转化为反应器内的至少一种烯烃和芳族化合物，其作为产物流被除去。

公开(公告)号：US20160369180A1

公开(公告)日：2016-12-22

申请号：US14901873

申请日：2014-06-30

Applicant: Andrew Mark WARD ,  Ravichander NARAYANASWAMY ,  OPRINS Arno, Johannes Maria ,  Vijayanand RAJAGOPALAN ,  Maria Egidius, Jacoba SCHAERLAECKENS ,  Raul VELASCO PELAEZ ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Andrew Mark Ward ,  Ravichander Narayanaswarny ,  Arno Oprins ,  Vijayanand Rajagopalan ,  Egidius Schaerlaeckens ,  Raul Velasco Pelaez

IPC: C10G57/00

CPC classification number: C10G57/00 ,  C10G9/36 ,  C10G21/00 ,  C10G45/00 ,  C10G45/58 ,  C10G47/00 ,  C10G67/0445 ,  C10G69/06 ,  C10G2300/1037 ,  C10G2300/1048 ,  C10G2400/22

Abstract: The present invention relates to an integrated process to convert crude oil into petrochemical products comprising crude oil distillation, dearomatization, ring opening, and olefins synthesis, which process comprises subjecting a hydrocarbon feed to dearomatization to produce a first stream enriched in aromatic hydrocarbons and naphthenic hydrocarbons and a second stream enriched in alkanes; subjecting a stream enriched in aromatic hydrocarbons and naphthenic hydrocarbons to ring opening to produce alkanes; and subjecting refinery unit-derived alkanes produced in the process to olefins synthesis. Furthermore, the present invention relates to a process installation to convert crude oil into petrochemical products comprising a crude distillation unit comprising an inlet for crude oil and at least one outlet for one or more of naphtha, kerosene and gasoil; a dearomatization unit comprising an inlet for a hydrocarbon feed to dearomatization, an outlet for a stream enriched in aromatic hydrocarbons and naphthenic hydrocarbons and a second stream enriched in alkanes; a ring opening unit comprising an inlet for aromatics and naphthenes produced by dearomatization and an outlet for alkanes; a unit for olefins synthesis comprising an inlet for alkanes and an outlet for olefins. The hydrocarbon feed subjected to dearomatization comprises one or more of naphtha, kerosene and gasoil produced by crude oil distillation in the process; and refinery unit-derived light-distillate and/or refinery unit-derived middle-distillate produced in the process. The process and the process installation of the present invention have an increased production of petrochemicals at the expense of the production of fuels and an improved ethylene yield.

Abstract translation: 本发明涉及将原油转化成石油化学产品的综合方法，其包括原油蒸馏，脱芳构化，开环和烯烃合成，该方法包括使烃进料脱芳构化以产生富含芳族烃和环烷烃的第一流 和富含烷烃的第二流; 使富含芳烃和环烷烃的物流开环以产生烷烃; 并将在该方法中生产的炼制单元衍生的烷烃进行烯烃合成。 此外，本发明涉及将原油转化成石油化学产品的方法设备，其包括含有原油入口的粗蒸馏单元和用于石脑油，煤油和油油中的一种或多种的至少一个出口; 脱芳构化单元，其包含用于进行脱芳烃化的烃进料的入口，用于富含芳烃和环烷烃的料流的出口和富含烷烃的第二料流; 开环单元，其包括通过脱芳构化产生的芳族化合物和环烷烃的入口和用于烷烃的出口; 用于烯烃合成的单元包括用于烷烃的入口和用于烯烃的出口。 进行脱芳烃化的烃进料包括在该过程中通过原油蒸馏生产的一种或多种石脑油，煤油和油油; 以及在该过程中生产的炼油厂单元衍生的轻馏分和/或炼油单元衍生的中间馏分。 本发明的方法和方法安装以牺牲燃料生产和提高的乙烯产率为代价增加了石化产品的生产。